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2.
A seven-step synthesis ofS-(+)-hydroprene (S-1) in 20 % overall yield starting fromS-(+)-3,7-dimethyl-1,6-octadiene (2) of 55+-10 % optical purity is described. The introduction of an optical enhancement step in the synthetic sequence at the stage ofS-(–)-3,7-dimethyl-1-octanol (9) raises the optical purity ofS-1 from 50 % to 80 %.For part 13, see. ref.1
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 342–348, February, 1993. 相似文献
3.
Felix Burkhardt Carl G. Schirmeister Christian Wesemann Massimo Nutini Stefano Pieralli Erik H. Licht Marc Metzger Frederik Wenz Rolf Mülhaupt Benedikt C. Spies 《Molecules (Basel, Switzerland)》2020,25(24)
A polyolefin with certified biocompatibility according to USP class VI was used by our group as feedstock for filament-based 3D printing to meet the highest medical standards in order to print personal protective equipment for our university hospital during the ongoing pandemic. Besides the chemical resistance and durability, as well as the ability to withstand steam sterilization, this polypropylene (PP) copolymer is characterized by its high purity, as achieved by highly efficient and selective catalytic polymerization. As the PP copolymer is suited to be printed with all common printers in fused filament fabrication (FFF), it offers an eco-friendly cost–benefit ratio, even for large-scale production. In addition, a digital workflow was established focusing on common desktop FFF printers in the medical sector. It comprises the simulation-based optimization of personalized print objects, considering the inherent material properties such as warping tendency, through to validation of the process chain by 3D scanning, sterilization, and biocompatibility analysis of the printed part. This combination of digital data processing and 3D printing with a sustainable and medically certified material showed great promise in establishing decentralized additive manufacturing in everyday hospital life to meet peaks in demand, supply bottlenecks, and enhanced personalized patient treatment. 相似文献
4.
《Journal of Coordination Chemistry》2012,65(18):3316-3328
The reactions As2O3, Se and 1,10-phenanthroline (phen) with NiCl2 and ZnCl2 in water at 140°C for 5 days afforded selenidoarsenates [Ni(phen)3]2[As8Se14] (1) and [Zn(phen)3]2[As8Se14] (2), respectively. The reactions with CoCl2 and NiCl2 in CH3OH aqueous solution produced polyselenidoarsenates [Co(phen)3][As2Se6] (3) and [Ni(phen)3][As2Se6] (4). All transition metal ions are octahedrally coordinated by six nitrogen atoms and all arsenics are trigonal pyramidally coordinated by three seleniums. In 1 and 2, eight [AsSe3]3? trigonal pyramids joined via edge-sharing to form [As8Se14]4? with condensation grade of 0.571. [As8Se14]4? contains two As3Se3 and one As6Se6 heterocycles. The formations of the selenidoarsenate anion [As8Se14]4? in 1 and 2 and polyselenidoarsenate [As2Se6]2? in 3 and 4 show solvent effect on condensation of trigonal bipyramidal [AsSe3]3? units under solvothermal conditions. 相似文献
5.
This paper examines the combined effects of a transverse magnetic field and variable viscosity on unsteady flow of a reactive third‐grade electrically conducting fluid and heat transfer in a channel with convective cooling at the surface. It is assumed that the fluid has small electrical conductivity and the electromagnetic force produced is very small. The coupled nonlinear partial differential equations governing the problem are derived and solved numerically using a semi‐implicit finite‐difference scheme. Both numerical and graphical results are presented and physical aspects of the problem are discussed with respect to various parameters embedded in the system. It is in general noted that those parameters that increase/decrase one flow quantity (velocity or temperature) also lead to the increase/decrease respectively of the other quantity. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
6.
本研究旨在分析脑胶质瘤患者的磁共振弥散张量成像(DTI)参数与病变组织血管内皮生长因子(VEGF)和基质金属蛋白酶-9(MMP-9)表达的相关性,以及DTI参数对脑胶质瘤进行分级诊断的价值.根据病理分级将102例脑胶质瘤患者分为低级别组(47例)和高级别组(55例),均行MRI和DTI检查,定量测定表观弥散系数(ADC... 相似文献
7.
陈黎明 《中国无机分析化学》2012,2(2):61-64
利用高分辨电感耦合等离子体质谱法测定半导体级高纯氢氟酸中的痕量金属杂质,用膜去溶进样系统直接进样检测,无需前处理、快速,避免了在样品前处理时的污染问题。高分辨电感耦合等离子体质谱法可以消除多分子离子干扰,降低检出限,提高定量准确性。方法的检出限为0.09~37.07ng/L,加标回收率为92.3%~116.8%。方法简单,结果可靠,适用于高纯氢氟酸中痕量元素的快速测定。 相似文献
8.
浙江磐安尖山地区旅游资源丰富,有待开发的旅游资源主要包括火山岩峡谷、多级瀑潭组合、高山飞瀑、皇城湖、破火山口、玄武岩台地、生态旅游资源,工业旅游资源、人文史迹和宗教寺庙等10个方面。可划分成皇城湖、夹溪、胡宅和鞍顶山4个景区,尖山地区的旅游资源要统筹规划,全方位、高标准开发,提高科学文化品位,并且纳入周边大旅游圈中。 相似文献
9.
丁宣浩 《数学年刊A辑(中文版)》2013,34(1):81-86
截断调和Bergman空间b_n~2=L_a~2{w,w~2,…,w~n}~v是Hilbert空间L~2的闭子空间.研究了单位圆盘上的截断调和Bergman空间上的Toeplitz算子的乘积问题,完整地刻画了具有有界调和符号的两个Toeplitz算子的有限秩与紧的半换位子或换位子. 相似文献
10.