Microwave spectrum of N2D4, 14N quadrupole coupling constants,and the barrier to inversion of the amino group

The microwave spectrum of N₂D₄ has been observed and analyzed. Based on five low-J rotational transitions the effective rotational constants are: A = 74712.9 ± 1.9 MHz, B = 18500.42 ± 0.46 MHz, and C = 18439.91 ± 0.46 MHz. The quadrupole coupling constants of the ¹⁴N nuclei are X_aa = 4.23 ± 0.04 MHz, X_bb = 1.98 ± 0.05 MHz, and X_cc = ?2.25 ± 0.05 MHz. Using the observed ground state inversion splittings for N₂D₄ and N₂H₄ the barrier to inversion of a single amino group is computed to be 5.00 kcal mol^?1.     

The coulometric titration of bromate with cuprous copper

A coulometric procedure has been developed by which 18 to 240 μg quantities of bromate may be determined to within 0.3 μg. The bromate is allowed to react with bromide in an acid solution and electrolytically generated cuprous copper is used for the titration. A dual platinum electrode indicator system is used in an amperometric end-point procedure     

I.I. Rabi: The Two Cultures and the Universal Culture of Science

I set forth and discuss I.I. Rabis views on the nature of science and society, focusing specifically on Rabis views on science and government, science and education, and science and religion. I also explore the influence of Rabi and C.P. Snow on each other. In the 1960s, Rabi set forth his mature and boldest positions, advocating science as the center of education and science as the replacement for religion. His positions culminate in science as the universal culture. I highlight Rabi not only as a scientist and public servant, but also as a public intellectual actively engaged with and connected to major issues of his time.Michael A. Day is Professor of Physics at Lebanon Valley College. He holds doctorates in both physics and philosophy.     

Intra-elemental photoelectron line intensities and their significance to quantitative analysis

Intraelemental relative photoelectron line intensities for 20 pure elements obtained under ultrahigh vacuum (5·10^?9 torr) and high resolution with cleaned surfaces are presented. Theoretical and experimental aspects of relative photoelectron line intensities as well as other characteristics of significance to quantitative analysis are discussed. Experimental data are related to theoretical results and compared with other recent work.     

Automated development of analytical chemical methods : The determination of senun calcium by the cresolphthalein complexone method

The cresolphthalein complexone method for serum calcium determination was investigated by means of a modified Technicon Autoanalyzer II under computer control. Simplex optimization of reagent concentrations, followed by response-surface mapping in the region of the optimum produced a method yielding 8.5% greater calcium sensitivity and 15% lower baseline absorbance than the standard method, with comparable insensitivity to interferences, and only a very slight sacrifice in linearity; a comprehensive operational understanding of the chemical system was also obtained.     

Synthesis of ring modified prostaglandins

The total syntheses of the ring modified prostaglandins 8–12, 16, 18, 20, and 22 are described.     

In Appreciation

Leslie Foldy’s diminutive stature and modest demeanor gave little clue to the powerful intellect responsible for several significant advances in theoretical physics.Two were particularly important. His 1945 theory of the multiple scattering of waves laid out the fundamentals that most modern theories have followed (and sometimes rediscovered), while his work with Siegfried Wouthuysen on the nonrelativistic limit of the Dirac equation opened the way to a wealth of valuable insights. In this article we recall some of the milestones along Foldy’s path through a life in physics. Some of the anecdotes we report here were related to one of the authors (PLT) just before an event in 2000 celebrating Foldy’s 80th birthday, while others were told to us over the course of the nearly forty years during which we were colleagues. Still others were uncovered during the course of WJF’s research for his book, Physics at a Research University: Case Western Reserve 1830–1990 (Cleveland: Case Western Reserve University, 2006). Other details were provided by Foldy’s widow, Roma. Philip L. Taylor is the Perkins Professor of Physics and Professor of Macromolecular Science and Engineering at Case Western Reserve University. William J. Fickinger is Professor Emeritus of Physics at Case Western Reserve University.     

A novel dimerisation of 3-benzoyl 4-phenylisocrotonic acid

The acid catalized self condensation of 3-benzoyl-4-pbenylisocrotonicacid is described.