Methacryloxyethyl phosphate‐grafted expanded polytetrafluoroethylene membranes for biomedical applications

Expanded polytetrafluoroethylene (ePTFE) membranes were modified by graft copolymerization with methacryloxyethyl phosphate (MOEP) in methanol and 2‐butanone (methyl ethyl ketone (MEK)) at ambient temperature using gamma irradiation. The effect of dose rate (0.46 and 4.6 kGy h^?1), monomer concentration (1–40 %) and solvent were studied and the modified membranes were characterized by weight increase, X‐ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). XPS was used to determine the % degree of surface coverage using the C? F (ePTFE membrane) and the C? C (MOEP graft copolymer) peaks. Grafting yield, as well as surface coverage, were found to increase with increasing monomer concentration and were significantly higher for samples grafted in MEK than in methanol solution. SEM images showed distinctly different surface morphologies for the membranes grafted in methanol (smooth) and MEK (globular), hence indicating phase separation of the homopolymer in MEK. We propose that in our system, the non‐solvent properties of MEK for the homopolymer play a more important role than solvent chain transfer reactions in determining grafting outcomes. Copyright © 2005 Society of Chemical Industry     

在湿陷性黄土地区对混凝土夯扩桩的检测

对夯扩桩在豫西湿陷性黄土地区的应用和可行性分析与检测。     

Crystallization of poly(3‐hydroxybutyrate) by exfoliated graphite nanoplatelets

Poly(3‐hydroxybutyrate) (PHB) has been shown to be efficiently nucleated by exfoliated graphite nanoplatelets (xGnP). The nucleating effect of xGnP was investigated using differential scanning calorimetry, optical microscopy and atomic force microscopy. Nonisothermal crystallization of PHB from the melt required lower activation energies for PHB containing 1 wt % and 3 wt % xGnP (?214 and ?102 kJ/mol respectively) than for pure PHB (?60 kJ/mol). A kinetic study of the PHB/xGnP crystallization employing a modified form of the Avrami equation revealed that the presence of xGnP increased the PHB crystallization temperature, as well as the crystallization rates, and generated smaller and more numerous spherulites. Optical microscopy and atomic force microscopy confirmed the incorporation of xGnP into the lamellar structure of the PHB spherulites and provided insight into the influence of xGnP on spherulite size and lamellae thickness. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

聚乙烯/石墨阻燃复合材料的研究

研究了石墨、可膨胀石墨、膨胀石墨 /聚乙烯复合材料的阻燃性能。结果表明 ,石墨具有一定的阻燃作用 ,可膨胀石墨具有良好的阻燃效果。但可膨胀石墨填充的复合材料力学性能较差     

细鳞片石墨化学氧化法制备可膨胀石墨技术问题探讨

采用分步氧化法制备了80目细鳞片可膨胀石墨。通过L9（3^4）正交试验确定了最佳工艺条件。在液固比-5：1，C：KMnO4=1：0．12，Ⅰ H2SO4：Ⅱ H2SO4=4：1，H2SO4：H2O2=12：1（均为质量比g／g）条件下获得膨胀容积为290mL／g。对制备过程中液固比、硫酸浓度、双氧水的加入方式、可膨胀石墨烘手温度、原料粒度等因素对膨胀容积的影响以及可膨胀石墨的稳定性的改善方法进行了探讨。     

膨胀石墨的饱和吸附量与微观结构的关系

采用不同的方法测定膨胀石墨对不同油质的饱和吸附量,来探讨膨胀石墨的结构与饱和吸附量的关系.由扫描电镜可知,膨胀石墨具有较大的比表面积,其孔结构是以中、大孔为主;蠕虫石墨的表面结构与其内部结构不同,其内部为典型的片层结构.通过观察石墨内部孔结构特征变化,可以分析膨胀石墨对油的去除效率以及影响因素.     

Mechanism of Fume Suppression and Performance on Asphalt of Expanded Graphite for Pavement under High Temperature Condition

Fume suppression mechanisms and the effect of expanded graphite on the performance of asphalt were studied by applying infrared spectroscopy(FT-IR), X-ray diffraction(XRD), scanning electron microscopy(SEM) and comprehensive thermal analysis(TG, DSC). The experimental results confirm that asphalt which is mixed with expandable graphite will expand in the process of hot mix, and the expanded graphite layer will swell by the light component in the asphalt. The light component in the asphalt and PAHs adsorption on expanded graphite surface or part of the plug in the expanded graphite layer between plates made nucleation crystallization growth. And the Van der Waals force and the bonding of the lattice can effectively restrain the asphalt fume release. Meanwhile, the expanding agent with oxidative can spread into the asphalt, leading to asphalt oxygenated and plastic abate, while the ductility decreases. Expanded graphite, SBS modifier and environment- friendly plasticizers are used to composite modified asphalt. According to asphalt fume release experiment, normal test of asphalt performance, Brookfield viscosity test, RTFOT test and asphalt mixture tests(high temperature stability, low temperature stability, water stability), it has been proven that the modified asphalt's performance is better than that of matrix asphalt and equivalent to that of SBS modified asphalt. Furthermore, it has good fume suppression effect.     

PC机基于EPP接口的实验硬件扩展总线

辅助学生在微机原理与接口控制学习中建立从原理到应用的认识是微机接口实验应达到的首要目的。现有的实验系统,大多通过上位PC机与实验箱上的代理或目标处理器通信实现对实验电路的控制,其控制方式是间接的,不直观,且增加额外成本和环节,在实际工程应用中也很少使用。EPP直接接口的微机原理实验系统去除以往实验系统上的处理器,采用简单数字电路实现基于PC机EPP并口的标准总线扩展并连接实验电路,使控制访问更为直接,也更易与实际微机控制应用相结合。通过扩展总线接口还能连接学生自己设计的实验电路,有利于开放性实验的设计与实现。基于这一思想设计构造的实验系统经实际教学验证,效果良好。     

小角度检查仪检定不确定度分析

详细分析了检定小角度检查仪的不确定度来源及相应标准不确定度分量和自由度,在此基础上计算出合成不确定度和有效自由度,最后给出在置信概率为99%时的扩展不确定度,使得量值传递更加可靠。     

基于退化激励信号的含有迟滞的三明治系统辨识

含有迟滞的三明治系统不仅具有非光滑、多值映射等特性, 而且迟滞环节的输入输出信号还是不能直接测量的, 常规方法难以进行有效的辨识. 本文提出了一种基于退化激励信号的两步辨识方案: 第一步, 设计一个特殊的退化激励信号将迟滞环节退化为一条静态曲线, 从而可以将两端的线性动态环节辨识出来, 解决中间信号不可测的问题; 第二步, 利用已辨识的线性模型重构迟滞环节的输入输出信号, 再采用“扩展输入空间法”建立迟滞环节的神经网络模型. 最后, 在压电超精密运动系统的实验结果表明所提出的建模方法取得了令人满意的结果.