An effective rhodium catalyst system on the synthesis of acetic acid from methyl formate

Rh/Lil/SnR₄ is an effective catalyst system for the conversion of methyl formate to acetic acid under carbon monoxide pressure. The effects of solvent and initial CO partial pressure on the turnover rate of the reaction were investigated. The possibility of replacing some of the iodide promoters by tin compounds has been probed.     

复杂条件下发挥锚杆支护作用的相关技术

介绍了在特殊地质和开采条件下,发挥锚杆支护作用的几种相关技术。     

40Cr钢复合热处理强韧化

用光学及电子显微镜(SEM.TEM)观察不同热处理的40Cr 钢的冲击及断裂韧性断口、及金相组织,阐明其间相互关系;断口结构可反映断裂特征,组织情况;细化晶粒提高强度、塑性和冲击韧性,但却减少脆断的特性距离 l 因而降低 K_(1c)模;减少碳(杂质)偏聚而使其呈较均匀地分布,从而减少可诱发塑坑的较粗大的碳(杂质)化合物的析出,即增加塑坑的间距 di 以及增加塑断组成物。从而都可增加断裂临界应变 ef,都可以提高 K_(1c)40Cr 复合热处理既靠先超高温淬、回火以减少碳(杂质)偏聚,改善其分布,以反增加位错马氏体从而提高 K_(1c),也靠后淬、回火细化晶粒而提高强度、塑性和冲击韧性,各自发挥长处达到强韧化。     

Bright Blue Light—emitting Diodes Based on a Novel Fluorescent Dye Containing Heterocyclic Groups

Novel molecular material ,1-benzothiazoly-3-pheny1-pyrazoline (BTPP) was found to function as bright blue light emitting dye in organic electroluminescent device, and its optical and electric characteristics were investigated. This heterovyclic compound exhibited good characteristics of blue photoluminescence and electroluminescence,which had the emission peak at 450nm .The single layer light-emitting devices using BTPP as light -emitting material dispersed in poly(N-vinylcarbazole)(PVK) and double layer ones using PBD as hole block layer above the light-emitting layer were fabricated using conventional spin-casting and vaccum vapour deposition methods. The introduction of PBD has enhanced electron injection and luminance efficiency, compared with the single layer LEDs.     

一种有机化合物名称编码与亚结构检索方法

本文以 IUPAC 为基础,考虑有机化合物母体和取代基的关联,采用库中已有的化合物名称进行亚结构检索,这种检索方法,由于由化合物名称所劈裂的编码数量较少,所以索引文件小,检索速度较快。另外,这种方法是侧重在化学上有意义的母体和宫能团,它可以和碎片编码亚结构检索方法互相补充。     

Composite group vector space method for estimating melting and boiling point of pure organic compound

Composition Group Vector Space (CGVS) method for estimating melting and boiling point T _m , T _b of organic compound has been proposed, and the principle of this method has been elucidated. The models for estimating T _m , T _b have been established and the numerical values of relative parameters have been presented. The average percentage deviations of T _m , T _b estimation are 7.53 and 1.58, respectively, which show that the present method demonstrates significant improvement in applicability to predict the above properties, compared to conventional group methods.     

数控机床交流伺服系统的复合控制研究

针对常规P-P与PPI控制存在的问题，提出了在数控机床交流伺服系统中，采用带速度和加速度作为前馈控制，模糊自校正PID控制作为位置反馈控制的复合控制器，实验证明可以显著提高控制系统的控制精度，大大降低跟踪误差，具有较强的鲁棒性。     

由拱管组成的复合管段固定支架受力计算

根据工程设计的实践，介绍了由拱管和波纹补偿器所组成的复合管段的固定支架受力计算方法和注意事项。     

A multipurpose audio watermarking algorithm with synchronization and encryption

We propose a new multipurpose audio watermarking scheme in which two complementary watermarks are used.For audio copyright protection,the watermark data with copyright information or signature are first encrypted by Arnold transformation.Then the watermark data are inserted in the low frequency largest significant discrete cosine transform(DCT) coefficients to obtain robustness performance.For audio authentication,a chaotic signal is inserted in the high frequency insignificant DCT coefficients to detect tampered regions.Furthermore,the synchronization code is embedded in the audio statistical characteristics to resist desynchronization attacks.Experimental results show that our proposed method can not only obtain satisfactory detection and tampered location,but also achieve imperceptibility and robustness to common signal processing attacks,such as cropping,shifting,and time scale modification(TSM).Comparison results show that our method outperforms some existing methods.     

多通管塑挤胀形工艺的力学分析

讨论了以聚氨酯橡胶棒为胀形介质，采用塑挤胀形复合工艺把无缝管坯一次成形为多通管成品的加工方法，分析了多通管塑挤胀形过程，提出了“应变样条”分析法，进而分析了典型剖面上应力应变状态，讨论了成形力间应具备的合理的数值关系，以使变形区处于最有利于变形的超高的静水压力和合适的偏应力状态，获得尽可能长的支管。