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1.
2.
Supported metal catalysts, particularly noble metals supported on SiO2, have attracted considerable attention due to the importance of the silica–metal interface in heterogeneous catalysis and in electronic device fabrication. Several important issues, e.g., the stability of the metal–oxide interface at working temperatures and pressures, are not well-understood. In this review, the present status of our understanding of the metal–silica interface is reviewed. Recent results of model studies in our laboratories on Pd/SiO2/Mo(1 1 2) using LEED, AES and STM are reported. In this work, epitaxial, ultrathin, well-ordered SiO2 films were grown on a Mo(1 1 2) substrate to circumvent complications that frequently arise from the silica–silicon interface present in silica thin films grown on silicon. 相似文献
3.
荧光显示管直丝氧化物阴极有效逸出功的计算 总被引:1,自引:1,他引:0
阴极的逸出功是表征阴极发射能力的物理量,求定荧光显示管直丝氧化物阴极有效逸出功时,因其零场发射电流密度难于准确取值,温度无法直接测量,显得困难,须予解决,为此提出了一种计算阴极有产逸出功的办法,对某显示管的发射欠佳和“低温高效”的两种氧化物阴极的有效逸出功进行计算,有效逸出功率是靠测量相关物理量再同计算得出,精度不很高,文中所用办法也不例外,但所得结果能反映阴极发射能力,所需仪器少,是实用方法。 相似文献
4.
Oxide films were deposited on different substrates by laser molecular beam epitaxy. Reflection high-energy electron diffraction was performed to in situ investigate the change of growth mode and the lattice relaxation during the growth. An asymmetrical phenomenon was found in the two kinds of strain states, compressive stress and tensile stress of heterostructures with different lattice mismatch. In the case of BaTiO3/SrTiO3 (2.2%), 2D layer-by-layer growth mode without lattice relaxation can be maintained for a longer period for BTO films on STO with compressive stress, comparing to STO films on BTO with tensile stress. When MgO films were deposited on SrTiO3 with a large mismatch of 7.8%, compressive stress leads to rapid lattice relaxation with a very thin wet layer, and 3D strained island were observed. As a comparison, SrTiO3 films on MgO with tensile stress were configured. No RHEED patterns can be observed duo to a large tensile stress. 相似文献
5.
Ram Bilas 《Bulletin of Materials Science》1993,16(2):109-116
X-ray diffraction, electron paramagnetic resonance, microwave absorption and resistivity measurements were carried out on
YBa2−x
Bi
x
Cu3O7 (0≤x≤0·5) superconductors in order to study the effect of bismuth on the structural and superconducting properties. A decrease
in sintering temperature increased the amount of impurity phase. Transition from an orthorhombic (superconducting) phase to
tetragonal structure produced no significant change in EPR zero-field signal at liquid nitrogen temperature (LNT). The non-resonance
signal height decreased on higher concentration of bismuth. Sintered YBa2−x
Bi
x
Cu3O7 superconductor had a strong EPR zero-field signal at LNT. We have evaluated particle size from XRD and EPR studies. The average
particle size was about 0·4μm. 相似文献
6.
7.
A silicide coating was prepared on Ti3SiC2-based ceramic by pack cementation to improve the oxidation resistance of Ti3SiC2, which is a technologically important material for high temperature applications. The microstructure, phase composition and
oxidation resistance of the coated sample were investigated. The results demonstrated that the silicide coating was mainly
composed of TiSi2 and SiC. A single layer of a mixture of SiO2 and TiO2 was formed on the surface of the coated sample during isothermal oxidation at 1100 °C and 1200 °C for 20h. Compared to Ti3SiC2, the parabolic rate constant of silicide coated Ti3SiC2 decreased by 2~3 orders of magnitude. Furthermore, the coated sample showed much better cyclic oxidation resistance than
Ti3SiC2 during the cyclic oxidation at 1100 °C for 400 times. However, during the preparation of the coating, a number of fine cracks
formed in the outer layer of the coating. When these cracks penetrated the whole coating during the cyclic oxidation, the
oxidation rate was accelerated, which degraded the oxidation resistance.
Electronic Publication 相似文献
8.
The corrosion of low carbon steel in natural sea-water is characterized by the formation and growth of compact and thick layers composed of oxides, insoluble salts and organic materials. These layers are the result of corrosion processes induced by local environmental conditions, water oxygen supply; ionic species; bacteria and organic matter. The exchange of various species (ions, molecules, gas) between sea-water and the rust layers or the metal depends both on the kinetics of the Faradaic reactions of the entities with either the oxides or the metal, as well as on their transport properties through the different strata of the rust layers. In this work, an impedance study was carried out using the 4-electrodes cell arrangement with corrosion products picked up on steel sheet piling immersed for 25 years and analyzed as free standing membranes. This new approach is a good way to reach the specific transport and transfer properties of the oxide without being blurred by the metal influence. The physical model developed in this work was based on a transmission line, and accurately described the experimental diagrams. The electronic resistivity of the oxide layer, its porosity, the mean pore size and the reaction kinetics parameters could be determined from the fittings. 相似文献
9.
Metal oxide semiconductors are today the most promising materials for photoelectrochemical production of hydrogen by the method of the photoelectrolysis of water as the problems of the stability of photoelectrodes are basically solved only for such materials. The aim of this short review paper is the presentation of results in this field obtained both worldwide and by the authors of this paper. The factors determining the efficiency of photoelectrolysis and possible ways to increase the photocatalytic activity of semiconductor photoelectrodes are analyzed. It is shown that the development of new photoelectrodes made of solid solutions and more complicated multicomponent compositions are most promising. Possibilities to use porous and nanocrystalline oxide photoelectrodes in photoelectrochemistry are also discussed. Photoelectrolysis setups for the photoelectrochemical conversion of solar energy into hydrogen are briefly described. 相似文献
10.
穿孔顶头表面氧化膜浅析 总被引:3,自引:0,他引:3
分析了穿孔顶头表面氧化膜的形成过程、性质、作用、界面行为,以及对顶头使用寿命的影响。指出了提高该氧化膜耐久性的途径。 相似文献