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The feasibility of a new alloy design concept utilizing the principle of ‘tungsten bronze effect’ is critically evaluated for the development of metallic bipolar plates for proton exchange membrane fuel cell (PEMFC). An austenitic stainless steel (ASS) is modified with W and La to improve the stability of the passive film in an acidic environment as well as to reduce the contact resistance by the tungsten bronze effect. The experimental ASS containing W and La was evaluated in a simulated PEMFC environment of H3PO4 and H2SO4 solutions at 80 °C, and the electrical property was evaluated by performing a contact resistance test. The test results show that the ASS modified with W and La has good passive film stability for corrosion resistance and low contact resistance. The X-ray photoelectron spectroscopy (XPS) analysis clearly suggests the possibility of the tungsten bronze effect from the change in valency state of W6+ to W5+ in the passive film formed on the modified ASS. The feasibility of a new alloy design concept utilizing the ‘tungsten bronze effect’ is well demonstrated; however, more study is highly required for the development of metallic bipolar plates of PEMFC. 相似文献
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Effect of heat treatment on microstructure and properties of hot-extruded nickel-aluminum bronze 总被引:1,自引:0,他引:1
The effect of heat treatment on the microstructure and properties of a hot-extruded nickel-aluminum bronze was investigated. Experimental materials were heat treated through different processes, including quenching, normalizing, aging and annealing, and their microstructure, corrosion resistance and mechanical properties were characterized. It is found that quenching causes all β phase transformed into β phase, however, normalizing causes β phase transformed into β α and κ phases. When the quenched sample is aged, fine phase is precipitated from the as-quenched microstructure of β' phase. Annealing causes the transformation of β into a and κ phases. The results of mechanical property tests show that quenching, normalizing and aging improve the tensile strength and hardness of the experimental material, with a corresponding fall in elongation. Annealing raises the elongation but reduces the tensile strength and hardness. Furthermore, corrosion resistance of nickel-aluminum bronze ranks from worse to better in the following order: aged, quenched, normalized, hot-extruded and annealed. However, with the exposure time of corrosion test increasing, the difference of average corrosion rate between those nickel-aluminum bronzes tums small. 相似文献
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Influence of heat treatment on tribological behaviors of novel wrought aluminum bronze 总被引:4,自引:1,他引:4
1 INTRODUCTIONAluminumbronzepossessesexcellentphysical,mechanicalandtribologicalproperties .Itisavailableformakingwear resistingan 相似文献
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A composite catalyst Nafion-Pt-HxMoO3 was prepared on a glassy carbon by cyclic voltammetry methods in sulfuric acid solution containing Na2MoO4, H2PtCl6 and Naton, and its activity for the methanol oxidation was studied with Pt-HxMoO3 as comparison. It is found that the electrocatalytic activity and the stability of Pt-HxMoO3 are improved by the Nation. The activity of Pt-HxMoO3 reaches its maximum when the content of Nation in the preparation solution is 0.012%(mass fraction). In this case the oxidation peak current of methanol on Nation-Pt-HxMoO3 is 1.76 times larger than that on Pt-HxMoO3 and keeps unchanged when the potential is set at 0.3 V (vs Hg-Hg2SO4) for 5 000 s in 1 mol/LCH3OH+0.5 mol/L U2SO4 solution. The results from energy dispersive spectroscopy show that the content of Nation in the composite is 0.57%. The results from scanning electron spectroscopy show that the composite of Nafion-Pt-HxMoO has a gain size of about 90 nm and distributes more uniformly than Pt-HxMoO3. 相似文献
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1 INTRODUCTIONAluminumbronzeisanimportantengineeringmateri alduetoitsexcellentphysical ,mechanical,anti corro sionandwearresistingproperties .Ourresearchgroupde velopedaspecialtypeofhighstrength ,wear resistinga luminumbronze(KK ) ,whichisexceptionallygoodfor… 相似文献
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介绍低锡青铜镀层电解退除工艺及应用情况,并对影响因素和退镀机理进行探讨。工艺成分简单,溶液稳定,使用寿命长,底层不易腐蚀,退镀溶液可直接加入镀液使用。 相似文献
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