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1.
Dehydrogenation of Light Alkanes Over Rhenium Catalysts on Conventional and Mesoporous MFI Supports 总被引:1,自引:0,他引:1
Anne Krogh Rovik Anke Hagen Iver Schmidt Søren Dahl Ib Chorkendorff Claus Hviid Christensen 《Catalysis Letters》2006,109(3-4):153-156
Recently, Re/HZSM-5 (Si/Al = 15) was shown to be an efficient catalyst for ethane dehydrogenation and aromatization at 823 K
and atmospheric pressure. In this reaction, the major initial products were benzene, toluene and xylene (BTX), but increasing
amounts of ethene were produced with time on stream due to deactivation of the catalyst. We show that by use of rhenium impregnated
MFI supports with very few or no acidic sites (Si/Al > 500), highly selective ethane dehydrogenation catalysts are obtained
with ethene selectivities of 98%. By use of mesoporous MFI supports (Si/Al >500) the lifetime of the catalyst appears to be
slightly improved compared to conventional MFI crystals. The beneficial effect of a mesoporous MFI support is convincingly
demonstrated in propane dehydrogenation, where both conversion and selectivities on the mesoporous MFI (Si/Al > 500) impregnated
with Re are significantly higher than on Re supported on a comparable conventional MFI support. 相似文献
2.
Zobi F Spingler B Alberto R 《Chembiochem : a European journal of chemical biology》2005,6(8):1397-1405
We have synthesized and fully characterized four new complexes comprising the fac-[Re(CO)3]+ moiety and the ligands NH3, L-proline (Pro), or N,N-dimethylglycine (dmGly). The reaction of [Re(H2O)3(CO)3]+ with the two amino acids gives trinuclear complexes of general formula [Re(L)(CO)3]3 (where L = amino acid). We have studied the in vitro behavior of these compounds with guanine and DNA in order to understand whether the cytotoxicity exhibited by certain rhenium complexes based on the fac-[Re(CO)3]+ core is due to the formation of nucleobase complexes and inter- or intrastrand links between DNA bases. We have performed model studies with guanine and studied the structural effects induced by different rhenium(I) tricarbonyl complexes on PhiX174 plasmid DNA by electrophoretic methods. Our results show that rhenium complexes with two available coordination sites interact with plasmid DNA to form a stable adduct that is likely to involve two bases. 相似文献
3.
采用经高能球磨的超细93W-4.9Ni-2.1Fe预合金粉末,并添加少量的Re,经压制,烧结制取试样。研究Re对93W-4.9Ni-2.1Fe合金性能和微观组织的影响。用机械式拉力试验机测量试样拉伸强度,用扫描电镜观察试样拉伸断1:3的形貌,用金相显微镜对试样显微组织进行测试分析。结果表明:当添加0%-0.8%Re(质量分数,下同)时,随着Re添加量的增加,合金的相对密度稳定在99.43%~99.49%,烧结样品延伸率从不加Re时的26.47%降至0.8%Re时的14.71%,合金的抗拉强度由不加Re时的1025MPa增加到0.8%Re时的1142MPa,合金拉伸断口收缩率由不加Re时的20.45%降至0.8%Re时的10.91%;随着Re含量的增加,合金中W晶粒的穿晶解理断裂的比例增加,而粘结相延性断裂的比例减少;随着Re含量的增加,合金中W晶粒尺寸明显减小,由不加Re时的40μm-45μm减小到添加0.8%Re时的20μm-25μm。 相似文献
4.
Fangfang Cui Xiaobo Li Qingliang Feng Jianbo Yin Lin Zhou Dongyan Liu Kaiqiang Liu Xuexia He Xing Liang Shengzhong Liu Zhibin Lei Zonghuai Liu Hailin Peng Jin Zhang Jing Kong Hua Xu 《Nano Research》2017,10(8):2732-2742
The anisotropic two-dimensional (2D) layered material rhenium disulfide (ReSe2) has attracted considerable attention because of its unusual properties and promising applications in electronic and optoelectronic devices.However,because of its low lattice symmetry and interlayer decoupling,anisotropic growth and out-of-plane growth occur easily,yielding thick flakes,dendritic structure,or flower-like structure.In this study,we demonstrated a bottom-up method for the controlled and scalable synthesis of ReSe2 by van der Waals epitaxy.To achieve controllable growth,a micro-reactor with a confined reaction space was constructed by stacking two mica substrates in the chemical vapor deposition system.Within the confined reaction space,the nucleation density and growth rate of ReSe2 were significantly reduced,favoring the large-area synthesis of ReSe2 with a uniform monolayer thickness.The morphological evolution of ReSe2 with growth temperature indicated that the anisotropic growth was suppressed at a low growth temperature (<600 ℃).Field-effect transistors employing the grown ReSe2 exhibited p-type conduction with a current ON/OFF ratio up to 10s and a hole carrier mobility of 0.98 cm2/(V.s).Furthermore,the ReSe2 device exhibited an outstanding photoresponse to near-infrared light,with responsivity up to 8.4 and 5.1 A/W for 850-and 940-nm light,respectively.This work not only promotes the large-scale application of ReSe2 in high-performance electronic devices but also clarifies the growth mechanism of low-lattice symmetry 2D materials. 相似文献
5.
6.
采用CVD方法制备了Ir/Re复合材料。研究了Ir层中Ir晶粒的形貌和生长特点,计算得到Ir晶粒生长动力学方程:(x2-x02)/t=4.31×103exp(-2.65eV/kT)(μm2·s-1)。研究了CVD过程中Re层表面晶粒生长和V,W型浸蚀纹的关系。对靠近Ir层的细晶粒区和Re层中部的柱状晶粒区中Re晶粒的再结晶长大进行了研究,计算得到柱状晶区中Re晶粒的生长动力学方程:(x2-x02)/t=2.55×103exp(-1.52eV/kT)(μm2·s-1),研究了Ir/Re扩散、Re扩散对细晶区中Re晶粒生长动力学的影响。 相似文献
7.
特殊场合下的温度测量技术 总被引:1,自引:0,他引:1
对于测量条件恶劣,不能用常规传感器实现的特殊场合,如高温强腐蚀性介质、真空、高温熔体及核辐射条件下的温度测量,必须开发特种专用传感器。本文阐述了钨铼热电偶等特种温度传感器的特点、性能及应用,并着重探讨了当前测温领域热点问题。铝液、铜液及熔盐等高温溶体连续测温;高温渗碳、真空粉末治金烧结炉(气)等强还原性气氛下的温度测量:流化床等流动粉体等高温强磨损条件下的温度测量技术等。实践证明,新开发的特殊场合下专用温度传感器,不仅与国际接轨,替代进口产品,而且还可以打入国际市场。 相似文献
8.
以一种定向合金为基础成分,加入不同含量的Re,采用定向凝固工艺浇注性能试棒,通过SEM研究了含Re合金的微观组织特征及Re在不同相中的分布情况,比较了不同Re含量的室温拉伸和高温持久性能。研究结果表明:通过加入Re可以有效提高合金的室温拉伸屈服强度和高温持久寿命,但室温和高温塑性有所降低。加入Re后合金的铸态组织变化不大:γ γ′共晶相数量随Re含量的增加而略有增多,并且尺寸变小。Re主要分布于γ基体中,在强化相γ′中的分布很少,并通过在γ基体中阻碍位错运动有效提高合金的高温强度。 相似文献
9.
10.