Occurrence and characterisation of the hydrogen-evolving enzyme in Frankia sp.

An increase in hydrogen evolution from the hydrogen-evolving enzyme in the actinomycete Frankia was recorded in the presence of nickel. Immunogold localisation analysis of the intracellular distribution of hydrogenase proteins indicated that they were evenly distributed in the membranes and cytosol of both hyphae and vesicles. In addition, molecular characterisation of the hydrogen-evolving enzyme at the proteomic level, using two-dimensional gel electrophoresis combined with mass spectrometry, confirmed that the Frankia hydrogen-evolving enzyme is similar to the cyanobacterial bidirectional hydrogenase of Anabena siamensis.     

乙烯齐聚催化剂研究进展

乙烯齐聚是合成直链低碳α-烯烃最先进的方法，直链低碳α-烯烃可用于生产低密度聚乙烯和高密度聚乙烯等多种精细化学品。本文综述了乙烯齐聚催化体系的研究进展，重点介绍了镍、锆、钛催化剂的组成以及反应时间、反应温度、溶剂、助催化剂等因素对乙烯齐聚活性和选择性的影响，并讨论了典型镍的催化机理。     

Effect of calcination conditions on phase formation and particle size of nickel niobate powders synthesized by solid-state reaction

The solid-state mixed oxide method via a rapid vibro-milling technique is explored in the preparation of single-phase nickel niobate (NiNb₂O₆) powders. The formation of the NiNb₂O₆ phase in the calcined powders has been investigated as a function of calcination conditions by TG-DTA and XRD techniques. Morphology, particle size and chemical composition have been determined via a combination of SEM and EDX techniques. It has been found that the minor phases of unreacted NiO and Nb₂O₅ precursors and the Ni₄Nb₂O₉ phase tend to form together with the columbite NiNb₂O₆ phase, depending on calcination conditions. More importantly, it is seen that optimization of calcination conditions can lead to a single-phase NiNb₂O₆ in an orthorhombic phase.     

电镀企业火警和爆鸣事故实例

列举了作者经历的18种火警和爆呜事故，为电镀企业敲响警钟，安全重于泰山。     

羰基镍粉末生产中羰基镍测定的发展状况与应用

阐述了国内外羰基镍测定的各种方法以及在工业与环境保护等领域的应用状。     

高可靠镀Ni／Au工艺及其在微波PTFE电路上的应用

介绍了高可靠电镀Ｎｉ／Ａｕ工艺在ＰＴＦＥ微波印制电路上的应用，并分析了氨基磺酸盐镀软镍和亚硫酸盐镀软金工艺的影响因素及提高Ｎｉ／Ａｕ镀层之间附着力的措施。通过实验及应用证明了与直接镀金工艺相比，在软基材ＰＴＦＥ敷铜箔板上镀Ｎｉ／Ａｕ工艺能大大提高微波电路的可焊性，高温稳定性和长期可靠性，并且用其所制作的微波器件的高频性能也优于直接镀金工业。     

Graphite formation on Ni film by chemical vapor deposition

Thin film formation of graphite by chemical vapor deposition using 2-methyl-1,2′-naphthyl ketone as a starting material was carried out on Ni film substrates. On Ni films directly deposited on quartz glass, the graphite films were obtained when the Ni film thickness was above 1 000 Å and above 5 000 Å at 700 °C and 1 000 °C, respectively. Depositions on thinner Ni film substrates comprise amorphous carbon (a-C) or graphite tubes which was owing to the thermal coagulation of the Ni film into droplets. On the other hand, graphite film was obtained on the Ni film with thickness 10 Å when a-C was inserted between the Ni film and the quartz glass. The coagulation of the Ni film is considered to be avoided by inserting a-C layer.     

“镍”催化酰氯和有机锡试剂交叉偶联反应的研究

镍络合物催化酰氯与有机锡试剂交叉偶联合成有机酮的反应,其反应选择性强,反应彻底,转化率高,工艺简单。在有机锡过量的情况下,对不同催化剂的催化活性和包括投料比,反应温度,反应时间,反应溶剂等反应条件进行了考察。     

缓冲剂在电镀工业中的应用

着重叙述了缓冲剂原理及应用。详细阐述了在电镀工艺中如何选用缓冲剂以及将电镀中的缓冲剂与化学中的缓冲剂的应用加以区别。