全文获取类型
收费全文 | 3081篇 |
免费 | 261篇 |
国内免费 | 51篇 |
学科分类
工业技术 | 3393篇 |
出版年
2024年 | 42篇 |
2023年 | 46篇 |
2022年 | 74篇 |
2021年 | 91篇 |
2020年 | 98篇 |
2019年 | 86篇 |
2018年 | 65篇 |
2017年 | 115篇 |
2016年 | 104篇 |
2015年 | 98篇 |
2014年 | 96篇 |
2013年 | 176篇 |
2012年 | 166篇 |
2011年 | 175篇 |
2010年 | 125篇 |
2009年 | 119篇 |
2008年 | 140篇 |
2007年 | 179篇 |
2006年 | 197篇 |
2005年 | 156篇 |
2004年 | 139篇 |
2003年 | 153篇 |
2002年 | 122篇 |
2001年 | 112篇 |
2000年 | 95篇 |
1999年 | 86篇 |
1998年 | 74篇 |
1997年 | 62篇 |
1996年 | 34篇 |
1995年 | 27篇 |
1994年 | 30篇 |
1993年 | 23篇 |
1992年 | 20篇 |
1991年 | 19篇 |
1990年 | 11篇 |
1989年 | 12篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 2篇 |
1985年 | 6篇 |
1984年 | 8篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有3393条查询结果,搜索用时 15 毫秒
1.
A series of novel thermoplastic elastomers, based on poly(dimethylsiloxane) (PDMS) as the soft segment and poly(butylene terephthalate) (PBT) as the hard segment, were synthesized by catalyzed two‐step, melt transesterification reactions of dimethyl terephthalate and methyl esters of carboxypropyl‐terminated poly(dimethylsiloxane)s (M?n = 550–2170 g mol?1) with 1,4‐butanediol. The lengths of both the hard and soft segments were varied while the weight ratio of the hard to soft segments in the reaction mixture was maintained constant (57/43). The molecular structure, composition and molecular weights of the poly(ester–siloxane)s were examined by 1H NMR spectroscopy. The effectiveness of the incorporation of the methyl‐ester‐terminated poly(dimethylsiloxane)s into the copolymer chains was verified by chloroform extraction. The effect of the segment length on the transition temperatures (Tm and Tg) and the thermal and thermo‐oxidative degradation stability, as well as the degree of crystallinity and hardness properties of the synthesized TPESs, were studied. Copyright © 2003 Society of Chemical Industry 相似文献
2.
NBR/PP热塑性弹性体研究进展 总被引:12,自引:0,他引:12
阐述了NBR/PP共混热塑性弹性体动态硫化胶的国内外研究进展、微观相态结构、性能、应用及展望。 相似文献
3.
This paper presents the current understanding of the flame retardant mechanism of Casico?. The study includes the flame retardant effect of each individual component: ethylene–acrylate copolymer, chalk and silicone elastomer, as well as the formation of an intumescent structure during heating. The flame retardant properties were investigated by cone calorimetry and oxygen index tests. To obtain insight into the flame retardant mechanism, heat treatment under different conditions has also been performed. The results indicate that the flame retardant mechanism of Casico is complex and is related to a number of reactions, e.g. ester pyrolysis of acrylate groups, formation of carbon dioxide by reaction between carboxylic acid and chalk, ionomer formation and formation of an intumescent structure stabilized by a protecting char. Special emphasis is given to the formation of the intumescent structure and its molecular structure as evaluated from 13C MAS‐NMR and 29Si MAS‐NMR, ESCA and XRD analysis. After treatment at 500°C the intumescent structure consists mainly of silicon oxides and calcium carbonate and after treatment at 1000°C the intumescent structure consists of calcium silicate, calcium oxide and calcium hydroxide. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
4.
Two thermoplastic and two thermosetting fibrereinforced plastic composites were subjected to dynamic tests over a wide range of temperature, covering both cryogenic and hot environments. The thermal behaviour of each composite, as indicated by its dynamic mechanical properties, was assessed individually, and was compared collectively with that of the other composites. 相似文献
5.
概述了SIS热塑性弹性体的合成方法以及国内外SIS生产和应用情况。综述了SIS在胶黏剂应用上的特点以及以茂金属为催化剂的SIS新低压加氢工艺的进展和国内SIS发展现状,提出了大力开发C5资源促进我国SIS产业发展的建议。 相似文献
6.
7.
Xingshuo Zhang Ruotao Feng Junhao Wang Wenqi Wang Jing Hua Zhaobo Wang 《大分子材料与工程》2021,306(6):2000745
Highly efficient oil-water separation shows urgent demand in industrial applications, especially in oil-spill accidents and organic solvent separation. Herein, a novel method is proposed for continuous oil-water separation by a pressure response through valve, which is loaded in a flexible convolute superhydrophobic/superoleophilic film based on low-density polyethylene (LDPE)/ethylene-propylene-diene terpolymer (EPDM) thermoplastic vulcanizate (TPV). The superhydrophobic/superoleophilic LDPE/EPDM TPV film (with contact angles of oil and water are 0° and 161.9°± 2.2°) is prepared only via a molding process where sandpaper is used as the template. The superhydrophobic/superoleophilic property of the TPV film shows robust performance in the activity endurance test. More importantly, the flexible LDPE/EPDM TPV film can be easily rolled up and loaded in through valve, which is the pressure response channel in oil-water separation. The typical separation pressure of oil and water is 3.01 and 6.17 kPa, which means the oil can be completely separated from the oil-water mixture under proper pressure in the pressure response through valve. 相似文献
8.
9.
PP/mPE/无机填料三元复合材料的形态结构和力学性能 总被引:6,自引:1,他引:6
采用刚性无机填料对茂金属聚乙烯(mPE)弹性体增韧聚丙烯(PP)二元共混体系进行增强,从而制得PP/mPE无机填料三元复合材料。分别探讨了CaCO3用量对复合材料拉伸性能和低温冲击性能影响,并考察了不同填料的增强效果。实验结果表明,由于弹性体的存在,无机填料的增强作用减弱;共混物的低温冲击强度也因填料的加入而大幅度下降,但经过表面处理的高岭土体系的冲击强度反而提高。SEM断裂形貌显示,未经表面处理的填料和基体的界面结合较弱,而改性高岭土则以层状结构分散于基体中,并呈现牢固的界面结合。 相似文献
10.
根据国外动态硫化技术的发地趋势,结合国内科研情况.对TPV推广应用的可能性进行了分析,并对今后的发展提出了建议。国内TPV的主要应用市场是轿车及电线电缆行业。顶计2000年,轿车行业对TPE的需求量达3250t/a。国内EPDM/PPTPV工厂成本不超过1.7万元/t.售价将远低于Santoprene。 相似文献