Mg0.5NixZn0.5-xFe2O4 spinel as a sustainable magnetic nano-photocatalyst with dopant driven band shifting and reduced recombination for visible and solar degradation of Reactive Blue-19

Focussing on visible light active ferrites for high performance removal of noxious pollutants, we report the synthesis of Mg_0.5Ni_xZn_0.5-xFe₂O₄ (x = 0.1, 0.2, 0.3, 0.4, & 0.5) ferrite nanoparticle for degradation of reactive blue-19 (RB-19). Lattice parameters calculated using intense X-ray diffraction (XRD) peaks and Nelson-Riley plots (N-R plot) are in well agreement with each other. The sample Mg_0.5Ni_0.4Zn_0.1Fe₂O₄ (M5N4) exhibits best performance with 99.5% RB-19 degradation in 90 min under visible light. Photoluminescence (PL) results confirm that recombination of charge carriers is highly reduced in the photocatalyst. Scavenging experiments suggest that O₂⁻ radicals were the dominant species responsible for photocatalytic performance. The photocatalytic mechanism was explained in terms of dopant driven shifting of conduction bands and valence bands (calculated by Mott-Schottky plots). The thermodynamic probability of radical generation along with role of redox cycles of metal ions has been discussed in the mechanism. The dye degradation was ascertained by detection of intermediates via mass spectrometry analysis and a possible degradation route was also predicted. The findings in this work provide intriguing opportunities to modify the electronic band structure of spinel ferrites for visible and solar light photocatalytic activity for environmental detoxification.     

Study of metal assisted anisotropic chemical etching of silicon for high aspect ratio in crystalline silicon solar cells

Textured surface is commonly used to enhance the efficiency of silicon solar cells by reducing the overall reflectance and improving the light scattering. In this study, a comparison between isotropic and anisotropic etching methods was investigated. The deep funnel shaped structures with high aspect ratio are proposed for better light trapping with low reflectance in crystalline silicon solar cells. The anisotropic metal assisted chemical etching (MACE) was used to form the funnel shaped structures with various aspect ratios. The funnel shaped structures showed an average reflectance of 14.75% while it was 15.77% for the pillar shaped structures. The average reflectance was further reduced to 9.49% using deep funnel shaped structures with an aspect ratio of 1:1.18. The deep funnel shaped structures with high aspect ratios can be employed for high performance of crystalline silicon solar cells.     

套保稠油油田火烧油层可行性分析

从火烧油层的筛选标准、实际地质条件及室内物理模拟实验入手，对该油田火烧可行性进行了分析。分析结果认为，套保油田进行火烧总体上是可行的，在实际火烧时应避开底水的影响，火烧区域应选在构造高部位或仅烧其主力层。     

水煤浆燃烧技术及其发展

分析了水煤浆雾化燃烧的技术状况、应用方向和存在问题，介绍了水煤浆流化—悬浮高效洁净燃烧新技术及其优点，结合实践应用情况，分析了发展水煤浆流化—悬浮燃烧技术的意义和应用前景。     

Preparation and properties of nano-sized SnO2 powder

1　INTRODUCTIONSnO2isoneofthemainmaterialsusedingassensor.Becauseofthehumidityandgassensingfunction,itattractsmoreandmoreattentions.Butthepresentproblemishowtoimprovethestabilityandsensibilityofgassensor.Researchershavetakenmanymeasurestoresolvethisproble…     

超细Fe3O4粒子表面包覆酞菁钴性质研究

本文研究了合成载氧体的金属有机化学液相淀积法制造工艺，所得产物经ＴＥＭ、ＸＰＳ、Ｍｏｓｓ－ｂａｕｅｒ谱和Ｂ－Ｈ仪等手段，研究了它的结构和磁性能。实验表明，酞青钴以薄层形式包覆在Ｆｅ＿３Ｏ＿４的表面，封闭了Ｆｅ＿３Ｏ＿４的表面孔洞，稳定了Ｆｅ＿３Ｏ＿４的物相，增强了磁性能。     

孤岛油田西区聚合物驱开发研究

孤岛油田西区注聚区1997年3月投入注聚后，高渗层得到有效封堵，吸水剖面得到明显改善。注聚期间，通过实施注聚区外围水井降水或停注、油井放大生产压差和调整注聚井注入速度等开发措施，扩大了聚合物波及体积，聚合物驱取得了明显效果。     

高速往复式内燃机平衡轴低质量设计分析

分析了扇形和偏心圆两种平衡轴设计的要求以及平衡重低质量的设计原则。扇形平衡重半径及宽度应尽量大、夹角应尽量小。偏心圆平衡重的偏心圆半径应尽可能大 ,轴承半径应尽可能小。同样质量的扇形平衡重产生的平衡力比偏心圆平衡重要大。     

FW调剖技术及应用

应用FW调剖技术有针对性地对 119口非钻停井区注水井采取了 4种精细调剖方案 ,对比了化学浅调剖应用前后注水井层间矛盾的缓解 ,纵向上吸水剖面的改善 ,注水量和吸水指数的变化及渗流能力的变化。结果表明 ,注水井化学浅调剖后 ,井区的连通油井明显受效 ,获得较高的增油量 ,水驱的开发效果得到改善。化学浅调剖可以有效地封堵高渗透层 ,扩大低渗透层注入水的波及体积 ,减缓注水井层间矛盾 ,实现了对注水井吸水剖面的有效调整 ,这对深化注水结构调整、挖掘各类油层潜力、提高储量动用程度有显著的效果。     

添加剂组成对通用内燃机油性能的影响

通过相关模拟试验，分析研究了添加剂组成对通用内燃机油的抗磨性能，抗氧化性能以及清净分散性能的影响。