全文获取类型
收费全文 | 53980篇 |
免费 | 6477篇 |
国内免费 | 5746篇 |
学科分类
工业技术 | 66203篇 |
出版年
2024年 | 254篇 |
2023年 | 755篇 |
2022年 | 1637篇 |
2021年 | 2039篇 |
2020年 | 2004篇 |
2019年 | 1689篇 |
2018年 | 1740篇 |
2017年 | 2002篇 |
2016年 | 2141篇 |
2015年 | 2121篇 |
2014年 | 3213篇 |
2013年 | 3414篇 |
2012年 | 4574篇 |
2011年 | 4364篇 |
2010年 | 3283篇 |
2009年 | 3420篇 |
2008年 | 2797篇 |
2007年 | 3605篇 |
2006年 | 3453篇 |
2005年 | 3020篇 |
2004年 | 2559篇 |
2003年 | 2125篇 |
2002年 | 1679篇 |
2001年 | 1412篇 |
2000年 | 1274篇 |
1999年 | 1094篇 |
1998年 | 837篇 |
1997年 | 764篇 |
1996年 | 564篇 |
1995年 | 491篇 |
1994年 | 459篇 |
1993年 | 324篇 |
1992年 | 255篇 |
1991年 | 176篇 |
1990年 | 122篇 |
1989年 | 90篇 |
1988年 | 86篇 |
1987年 | 70篇 |
1986年 | 61篇 |
1985年 | 42篇 |
1984年 | 30篇 |
1983年 | 24篇 |
1982年 | 21篇 |
1981年 | 15篇 |
1980年 | 20篇 |
1979年 | 14篇 |
1974年 | 6篇 |
1959年 | 8篇 |
1955年 | 3篇 |
1951年 | 26篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Prediction of methane adsorption content in continental coal-bearing shale reservoir using SLD model
Shale gas, as an important unconventional resource, has drawn global attention. It is mainly composed of adsorption gas and free gas. Adsorption gas content could play an important guiding role on both the selection of favorable perspective area and the exploration and exploitation of shale gas resources. In order to accurately measure adsorption gas content, a new approach was established to predict the adsorption isotherm of methane on shale. Based on the simplified local-density (SLD) method, both the adsorption isotherms of illite, illite/smectite mixed-layer, cholorite and type III kerogen and the total shale rock could be well fitted. The fitting results show good coincidences with the true experimental test data, which proves the method is reasonable and dependable and the prediction results are effective and credible. In addition, the good simulation results show that the SLD parameters can reflect the pore structure characteristics and corresponding adsorption characteristics of the shale samples, which can be used for the quantitative characterization of shale pore system. 相似文献
2.
湘中海相浅层湘冷1井酸压工艺研究及应用 总被引:2,自引:0,他引:2
湘冷1井具有气层埋藏浅(400m-500m)、纵向上裂隙发育的特点,属低孔、低渗的含泥质灰岩致密储层。大量室内实验和研究采用“前置液酸压+闭合酸化”工艺技术,并优选了相应降阻酸和闭合酸配方。通过酸压实现了该井工业油气流的突破,取得了明显的增产效果,为新区海相浅层气的开发探索出了一套成熟的改造增产措施。 相似文献
3.
应用静态吸附、动态吸附、程序升温脱附和程序升温还原等实验方法,考察了噻吩在Ni基非晶态合金上的吸附和脱附行为。常温下,噻吩分子首先吸附在清洁的Ni表面,并立刻被活化,发生氢解反应,C-S键断裂,释放出烃类部分,S留在Ni原子上。噻吩可以在Ni基非晶态合金表面发生强度不同的化学吸附。弱化学吸附的噻吩可以脱附;强化学吸附的噻吩不会脱附,而在高温下发生氢解反应。 相似文献
4.
5.
A locomotive cabin adsorption air‐conditioner has been equipped in #DF4B‐2369 locomotive; and has been successfully run for 2 years. It is powered by waste heat from the exhaust of the diesel engine. The influence on heat transfer is described by the equivalent heat transfer coefficient or thermal resistance of components inside the adsorber. The variation of adsorption capacity is expressed by a non‐equilibrium adsorption function. The dynamic heat transfer process of adsorption air‐conditioning system is treated with the lumped parameter method. Some typical running experimental results are present. The diesel engine rotating speed and locomotive speed influenced on the refrigeration system are discussed. The maximum mean refrigeration power is regarded as an objective function. Based on experiments and theoretical analysis, the running characteristics of the air‐conditioning system are optimized. Some techniques of performance improvement are suggested as well. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
6.
中原油田岩石可钻性与声波时差关系研究 总被引:3,自引:0,他引:3
选取中原油田的大量岩心,采用常规岩石力学测试方法测定了岩石的可钻性、声波测试方法测定了岩石和岩屑声波时差,通过对测得的岩石可钻性级值和声波时差进行回归拟合,得出了中原油田岩石可钻性与声波时差的关系式。现场应用表明,该关系式较好地反映了中原油田地层岩石可钻性与声波时差的关系,可以在优选钻头时作为参考或直接应用。 相似文献
7.
H. Yamamoto N. Heyamoto T. Matsui N. Murayama J. Shibata 《International Journal of Thermophysics》2003,24(5):1385-1394
Polyvinylalcohol (PVA) polymer gel is a temperature sensitive polymeric gel, with a critical transition temperature (with H2O) of 310 K. At higher than 310 K, this temperature sensitive polymer gel shrinks because of discharging water, whereas at lower temperatures, the gel swelled because of absorbing water. The reversibility of the gel's volume change was confirmed by temperature swing. The adsorption behavior of an organic compound onto the PVA polymer gel in water was tested at various temperatures. The amount of adsorbed organic compound increased remarkably at temperatures higher than about 310 K. Then, it was confirmed that the organic compound in PVA polymer gel could be reversibly adsorbed and desorbed by a temperature change between 293 and 323 K. The mechanism of adsorption of the organic compound onto the PVA polymer gel could be explained by hydration and dehydration of polymer gel. 相似文献
8.
9.
This paper investigates the catalytic ignition of the H2/O2/CO2 mixture on platinum in a stagnation flow at atmospheric pressure experimentally and numerically. We measure the ignition temperatures of the gas mixtures flowing towards resistively heated platinum with various composition ratios and various diluent gases of N2, Ar and CO2. Compared with N2 or Ar, the CO2 dilution shows higher ignition temperature by about 50 K, even at the same composition ratio. The ignition temperature increase is proportional to the dilution ratio. Through the numerical simulation, it is illustrated that higher ignition temperature is caused by the adsorption of CO2 and following dissociation on platinum surface, which was to date considered negligible in catalytic combustion. 相似文献
10.
Daniela M. Nevskaia Maria Luisa Rojas Cervantes Antonio Guerrero Ruíz Juan de Dios Lpez Gonzlez 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1995,63(3):249-256
Adsorption of Triton X-100 on various silica substrates has been investigated. A number of solids, including a natural quartz, this quartz washed with HCl acid and subsequently heated at 1273 K; two aerosils and one Kieselgel silicas were studied. These solids exhibit surface areas in the range of 5 to 430 m2 g?1. All the Triton adsorption isotherms display an S-shape at the adsorption temperatures studied (298 and 308 K). It has been found that the pretreatments of natural quartz (by water washing, impurities removed by acid and/or high temperature calcination) affect considerably the amounts of TX-100 adsorbed. Measurements of surface composition have been made by X-ray photoelectron spectroscopy (XPS) with particular emphasis on the presence of impurities and on the number of OH groups at the surface of the samples. The nature of the surface hydroxyl has also been studied by infrared spectroscopy. Furthermore, the specific number of hydroxyl groups on the surface of the silica samples has been determined by thermogravimetric analysis. Finally an attempt to correlate solid surface characteristics with adsorption isotherms has been developed. 相似文献