排序方式: 共有49条查询结果,搜索用时 0 毫秒
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报道了基于非刻蚀法的表面起皱机制来实现高分子薄膜表面的周期性梯度图案的简单可控制备.即对于处于机械拉伸状态的聚二甲基硅氧烷(PDMS)弹性基底,在其底部垫入"积木",而后对其进行紫外-臭氧(UVO)和氧等离子体(OP)的联合表面处理."积木"的加入引起了表面处理后表面硅氧层(SiOx)梯度厚度的形成,进而当释放拉伸应变后,诱导产生了梯度皱纹图案.结果表明:当UVO与OP联用处理时,不仅实现了较小拉伸应变下梯度皱纹形貌的制备,而且扩大了UVO单独使用时梯度皱纹周期的变化范围.通过OP与UVO的处理顺序和处理时间等因素的简单调节,进一步实现了不同梯度皱纹微结构的精细构筑. 相似文献
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Santanu Kundu Chelsea S. Davis Thomas Long Ravi Sharma Alfred J. Crosby 《Journal of Polymer Science.Polymer Physics》2011,49(3):179-185
Topological patterns on polymer surfaces can significantly alter and control adhesion. In this study, the effect of surface wrinkles on a spherical surface on adhesion has been studied. Surface wrinkling induced by swelling of a crosslinked polydimethylsiloxane elastomer constrained by a stiff, thin surface layer (silicate) is used to produce topographic features of various length scales over a large curved area. By controlling the properties of the stiff layer and the applied strain conditions, surface wrinkles of varying amplitude and wavelength are obtained. The effect of wrinkle morphology on adhesion is quantified, and the results display a transition from enhancement of adhesion to decrease depending upon wrinkle dimensions. A simple phenomenological model is proposed that describes the change of adhesion behavior as a function of wrinkle morphology. Our results provide a critical understanding toward tuning the adhesion behavior of nonplanar surfaces consisting of periodic topographic structures. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
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Xuezhe Zhao Shengwei Deng Yongmin Huang Honglai Liu Ying Hu 《Frontiers of Chemistry in China》2011,6(3):159-163
The wrinkling of phase-separated binary polymer blend film was studied through combining the Monte Carlo (MC) simulation for
morphologies with the lattice spring model (LSM) for mechanical properties. The information of morphology and structure obtained
by use of MC simulation is input to the LSM composed of a three-dimensional network of springs, which allows us to determine
the wrinkling and the mechanical properties of polymer blend film, such as strain, stress, and Young’s modulus. The simulated
results show that the wrinkling of phase-separated binary polymer blend film is related not only to the structure of morphology,
but also to the disparity in elastic moduli between polymers of blend. Our simulation results provide fundamental insight
into the relationship between morphology, wrinkling, and mechanical properties for phase-separated polymer blend films and
can yield guidelines for formulating blends with the desired mechanical behavior. The wrinkling results also reveal that the
stretching of the phase-separated film can form the micro-template, which has a wide application prospect. 相似文献
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Level-set G-equation and stationary flamelet chemistry are used in large eddy simulation of a propane/air premixed turbulent flame stabilized by a bluff body. The aim was to study the interaction between the flame front and turbulent eddies, and in particular to examine the effect of sub-grid scale (SGS) eddies on the wrinkling of the flame surface. The results indicated that the two types of turbulence eddies—the resolved large scale eddies and the unresolved SGS eddies—have different effects on the flame. The fluctuation of the flame surface, which is responsible for the broadening of the time averaged mean flame brush by turbulence, depends on the large resolved turbulence eddies. Time averaged mean flow velocity, temperature, and major species concentrations mainly depend on the large scale resolved eddies. The unresolved SGS eddies contribute to the wrinkling at the SGS level and play an important role in the enhancement of the propagation speed of the resolved flame front. In addition, the spatially filtered intermediate species, such as radicals, and the spatially filtered reaction rates strongly depend on the small SGS eddies. The asymptotic behavior of flame wrinkling by the SGS eddies, with respect to the decrease in filter size and grid size, is investigated further using a simplified level-set equation in a model shear flow. It is shown that to minimize the influence of the SGS eddies, fine grid and filter size may have to be used. 相似文献
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Qian Li Jian-Cai Zhao Wei-Bo Liu Ming-Hai Yuan 《Journal of Macromolecular Science: Physics》2017,56(2):124-133
Weather-strip seals in automotive door systems play a major role in determining the door closing effort, isolating the passenger compartment from water and reducing the wind noise inside the vehicle. The phenomenon of a wrinkle often occurs in weather-strips when they are assembled on the door surfaces which have bent or twisted profiles. Wrinkles in automobile weather-strip seals will affect the closing effort and noise isolation characteristics of the automotive door system. The wrinkle of anethylene-propylene-diene (EPDM) automobile weather-strip seals when bent and the critical conditions for a wrinkle to develop were characterized in this study. The hyperelastic material behavior of the EPDM sponge and EPDM dense rubber in the seal were modeled using the Foam model and Mooney–Rivlin model, respectively. Then a finite element analysis (FEA) model of the automobile weather-strip seal in assembly was developed and analyzed using then on linear FEA software Marc. The deformation of the seal and the thickness decrease in the critical region where it was prone to wrinkle were obtained by this FEA method. Finally the critical criterion of wrinkling was determined by analysis of the reaction forces in the critical region. The proposed analysis method can shorten the product design cycle and decrease the design and trial-product cost considerably. 相似文献
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WU Dan YIN YaJun XIE HuiMin SHANG YuanFang LI ChuanWei WU LiFu DAI XiangLu 《中国科学:物理学 力学 天文学(英文版)》2014,57(4):637-643
Wrinkling and buckling of nano-films on the compliant substrate are always induced due to thermal deformation mismatch.This paper proposes effective means to control the surface wrinkling of thin film on the compliant substrate,which exploits the curvatures of the curve cracks designed on the stiff film.The procedures of the method are summarized as:1)curve patterns are fabricated on the surface of PDMS(Polydimethylsiloxane)substrate and then the aluminum film with the thickness of several hundred nano-meters is deposited on the substrate;2)the curve patterns are transferred onto the aluminum film and lead to cracking of the film along the curves.The cracking redistributes the stress in the compressed film on the substrate;3)on the concave side of the curve,the wrinkling of the film surface is suppressed to be identified as shielding effect and on the convex side the wrinkling of the film surface is induced to be identified as inductive effect.The shielding and inductive effects make the dis-ordered wrinkling and buckling controllable.This phenomenon provides a potential application in the fabrication of flexible electronic devices. 相似文献
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The present paper is devoted to the study of finite inflation of a hyperelastic toroidal membrane on a cylindrical rim under uniform internal pressure. Both compliant and rigid frictionless rims have been considered. The compliant cylindrical rim is modeled as a linear distributed stiffness. The initial cross-section of the torus is assumed to be circular, and the membrane material is assumed to be a homogeneous and isotropic Mooney–Rivlin solid. The problem is formulated as a two point boundary value problem and solved using a shooting method by employing the Nelder–Meads search technique. The optimization function is constructed on a two (three) dimensional search space for the compliant cylinder (rigid cylinder). The effect of the inflation pressure, material properties and elastic properties of the rim on the state of stretch and stress, and on the geometry of the inflated torus have been studied, and some interesting results have been obtained. The stability of the inflated configurations in terms of occurrence of the impending wrinkling state in the membrane has also been studied. 相似文献
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In this paper,we present a simple method by combining surface wrinkling and template replication to create a series of hierarchical structures on polydimethylsiloxane(PDMS) elastomer.The primary stable lined patterns are formed by duplicating commercialized compact disk and digital versatile disk with PDMS.The secondary microscale patterns are from surface wrinkling,which is elicited by oxygen plasma(OP) treatment of the prestrained PDMS stamp followed with the prestrain release.By systematically varying the OP exposure duration,the prestrain,and the angle(θ) between the primary pattern orientation and the prestrain direction,we obtain highly ordered well-organized composite patterns from different patterning techniques and with different length scales and mechanical stabilities. 相似文献