全文获取类型
收费全文 | 3847篇 |
免费 | 328篇 |
国内免费 | 317篇 |
学科分类
数理化 | 4492篇 |
出版年
2024年 | 7篇 |
2023年 | 152篇 |
2022年 | 68篇 |
2021年 | 94篇 |
2020年 | 135篇 |
2019年 | 138篇 |
2018年 | 140篇 |
2017年 | 100篇 |
2016年 | 138篇 |
2015年 | 129篇 |
2014年 | 272篇 |
2013年 | 413篇 |
2012年 | 165篇 |
2011年 | 236篇 |
2010年 | 187篇 |
2009年 | 223篇 |
2008年 | 233篇 |
2007年 | 239篇 |
2006年 | 234篇 |
2005年 | 194篇 |
2004年 | 216篇 |
2003年 | 194篇 |
2002年 | 92篇 |
2001年 | 56篇 |
2000年 | 65篇 |
1999年 | 45篇 |
1998年 | 62篇 |
1997年 | 39篇 |
1996年 | 34篇 |
1995年 | 28篇 |
1994年 | 28篇 |
1993年 | 27篇 |
1992年 | 23篇 |
1991年 | 15篇 |
1990年 | 15篇 |
1989年 | 8篇 |
1988年 | 8篇 |
1987年 | 9篇 |
1986年 | 4篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1976年 | 2篇 |
1971年 | 1篇 |
1970年 | 2篇 |
1968年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有4492条查询结果,搜索用时 0 毫秒
1.
Hai-Ping Cao 《Journal of fluorine chemistry》2006,127(8):1079-1086
In the presence of sodium dithionite and DMSO, the intramolecular radical cyclization of 4-chloro-1,1,2,2,3,3,4,4-octafluorobutylbenzenes is achieved to give the corresponding cyclic compounds in moderate to good yields. 相似文献
2.
Grishin D. F. Semyonycheva L. L. Telegina E. V. Smirnov A. S. Nevodchikov V. I. 《Russian Chemical Bulletin》2003,52(2):505-507
Organometallic compounds Cp2TiCl2, (EtC5H4)2NbCl2, and (PriC5H4)2WCl2 were assessed as additives that control polymer chain growth in the polymerization of methyl methacrylate. In the presence of compounds mentioned in amounts comparable with that of the initiator, a uniform process with no gel-effect occured and respective linear increase in the molecular weight of the polymer up to high degrees of the monomer conversion was observed. 相似文献
3.
Zhu Linsheng 《东北数学》1998,(1)
in this paper, the classification and realization of complete Lie algebras withcommutative nilpotent radicals are given. From this, some results on the radicals of thesecomplete Lie algebras are obtained. 相似文献
4.
5.
François Loiseau Jean-Mary Simone David Carcache Pavel Bobal Reinhard Neier 《Monatshefte für Chemie / Chemical Monthly》2007,138(2):121-129
Summary. Free radical couplings from furan, as cheap starting material, were studied in view of developing a rapid strategy en route to the synthesis of derivatives of nonactin. The chain containing the alcohol function was introduced in one or two steps
in 86% yield. For the introduction of the second chain with the ester function two different coupling methods were tested.
Starting from the advanced intermediates obtained nonactin derivatives can be prepared by catalytic hydrogenation of the furan
ring. 相似文献
6.
Aryl substituted α-carbonyl bromo-alkynes undergo facile cyclizations to the corresponding substituted 4-methylene-tetrahydrofurans using indium(I) iodide in acetonitrile under sonication in high yields. The reaction is predicted to proceed via a radical process initiated by InI and a plausible radical pathway is suggested. 相似文献
7.
I. V. Ukrainets L. V. Sidorenko O. V. Gorokhova N. A. Jaradat 《Chemistry of Heterocyclic Compounds》2006,42(4):475-487
Various methods of synthesizing amides of 2-hydroxy-4-imino-1,4-dihydroquinoline-3-carboxylic acids have been studied. Results
of investigations on the antitubercular and antiinflammatory activity of the obtained compounds are discussed.
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 542–555, April, 2006. 相似文献
8.
V. I. Saloutin I. T. Bazyl' Z. E. Skryabina P. N. Kondrat'ev O. N. Chupakhin 《Russian Chemical Bulletin》1994,43(2):279-282
Reactions of pentafluorobenzoylpyruvic acid with amines afford the respective enamines. The intramolecular cyclization of the latter results inN-substituted 4-quinolone-2-carboxylic acids. Ammonia and triethylamine favor the cyclization of pentafluorobenzoylpyruvic acid to 2-carboxychromone.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 299–302, February, 1994. 相似文献
9.
J. P. S. Farinha J. M. G. Martinho H. Xu M. A. Winnik R. P. Quirk 《Journal of Polymer Science.Polymer Physics》1994,32(9):1635-1642
Cyclization of a polystyrene chain (Mn = 10,600; Mw/Mn = 1.09) both ends labeled with 4-(1-pyrenyl)butanoamide groups was studied in cyclohexane between 25 and 95°C. The amide groups (peptide bonds) at both ends can form an intrachain hydrogen bond between the amide hydrogen at one chain end and the carbonyl oxygen at the other. The presence of two sets of conformers, random coils, and chains cyclized through hydrogen bonding, complicates the data analysis. The pyrene excimer kinetics of this polymer is well described by a model composed of two monomers (hydrogen bonded and nonbonded chains) and one excimer, in equilibrium. The cyclization rate constant for hydrogen-bonded chains is larger than the one for nonhydrogen-bonded chains. The pyrene excimer binding energy (ca. 1.6 kcal/mol) is lower than the published value for nonhydrogen-bonded chains (~ 9 kcal/mol), suggesting that intrachain hydrogen bonding hinders the stabilization of the excimer. © 1994 John Wiley & Sons, Inc. 相似文献
10.