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The absolute stereochemistry of cyanohydrins, derived from ketones and aldehydes, is obtained routinely, in a microscale and derivatization‐free manner, upon their complexation with Zn‐MAPOL, a zincated porphyrin host with a binding pocket comprised of a biphenol core. The host–guest complex leads to observable exciton‐coupled circular dichroism (ECCD), the sign of which is easily correlated to the absolute stereochemistry of the bound cyanohydrin. A working model, based on the ECCD signal of cyanohydrins with known configuration, is proposed.  相似文献   
2.
Electron cyclotron resonance heating and electron cyclotron current drive (ECRH/ECCD) have developed significantly in recent years such as Tore Supra, JT-60U , Heliotron j. It has many advantages over other means of heating and current drive. Firstly, the launcher can be located far away from the plasma. Secondly, the fact that the ECRH/ECCD power can be injected as narrow Gaussian beams, giving rise to highly localized power deposition, makes ECRH/ECCD an ideal candidate for local MHD control.  相似文献   
3.
The optimized synergy conditions between electron cyclotron current drive(ECCD) and lower hybrid current drive(LHCD) with normal parameters of the EAST tokamak are studied by using the C3PO/LUKE code based on the understanding of the synergy mechanisms so as to obtain a higher synergistic current and provide theoretical reference for the synergistic effect in the EAST experiment. The dependences of the synergistic effect on the parameters of two waves(lower hybrid wave(LHW) and electron cyclotron wave(ECW)), including the radial position of the power deposition, the power value of the LH and EC waves, and the parallel refractive indices of the LHW(N) are presented and discussed.  相似文献   
4.
根据 HL-2M 装置物理实验加热的需求,完成了总功率为 8MW 的电子回旋共振加热及电流驱动 (ECRH/ECCD)系统设计,开展了波源、传输及天线等关键部件研制。8MW ECRH/ECCD 系统,由 8 套 105GHz/  1MW/3s 波源系统、8 条内径为 63.5mm 的真空传输线及三套极向实时可控的发射天线构成。目前,已完成 ECRH/ECCD 系统关键部件研制及其相关的桌面与高功率性能测试。测试结果表明,微波源回旋管输出微波功率 达到1MW/3s,在真空度为 10‒2Pa 的过模波纹圆波导传输线中能低耗稳定传输,发射天线极向全量程角度转动响 应时间在 50ms 以内。   相似文献   
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