全文获取类型
收费全文 | 2846篇 |
免费 | 308篇 |
国内免费 | 1520篇 |
学科分类
环境安全 | 4674篇 |
出版年
2024年 | 8篇 |
2023年 | 56篇 |
2022年 | 79篇 |
2021年 | 101篇 |
2020年 | 104篇 |
2019年 | 92篇 |
2018年 | 124篇 |
2017年 | 161篇 |
2016年 | 204篇 |
2015年 | 192篇 |
2014年 | 200篇 |
2013年 | 316篇 |
2012年 | 269篇 |
2011年 | 255篇 |
2010年 | 203篇 |
2009年 | 201篇 |
2008年 | 176篇 |
2007年 | 243篇 |
2006年 | 224篇 |
2005年 | 167篇 |
2004年 | 151篇 |
2003年 | 150篇 |
2002年 | 127篇 |
2001年 | 104篇 |
2000年 | 98篇 |
1999年 | 98篇 |
1998年 | 106篇 |
1997年 | 83篇 |
1996年 | 72篇 |
1995年 | 60篇 |
1994年 | 41篇 |
1993年 | 33篇 |
1992年 | 48篇 |
1991年 | 43篇 |
1990年 | 17篇 |
1989年 | 16篇 |
1988年 | 11篇 |
1987年 | 13篇 |
1986年 | 4篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 4篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1973年 | 2篇 |
排序方式: 共有4674条查询结果,搜索用时 15 毫秒
1.
Carbon coated monolith was prepared by sucrose solution 65 wt.% via dip-coating method. Sulfonation of incomplete carbonized carbon coated monolith was carried out in order to synthesize solid acid catalyst. The textural structure characteristics of the solid acid catalyst demonstrated a low surface area and pore volume. Palm fatty acid distillate (PFAD), a by-product of palm oil refineries, was utilized as oil source in biodiesel production. The esterification reaction subjected to different reaction conditions was performed by using the sulfonated carbon coated monolith as heterogeneous catalyst. The sulfonation process had been performed by using vapour of concentrated H2SO4 that was much easier and efficient than liquid phase sulfonation. Total acidity value of carbon coated monolith was measured for unsulfonated sample (0.5 mmol/g) and sulfonated sample (4.2 mmol/g). The effect of methanol/oil ratio, catalyst amount and reaction time were examined. The maximum methyl ester content was 89% at the optimum condition, i.e. methanol/oil molar ratio (15:1), catalyst amount (2.5 wt.% with respect to PFAD), reaction time (240 min) and temperature 80 °C. The sugar catalyst supported on the honeycomb monolith showed comparable reactivity compared with the sugar catalyst powder. However, the catalyst reusability studies showed decrease in FFA% conversion from 95.3% to 68.8% after four cycles as well as the total acidity of catalyst dropped from the value 4.2 to 3.1 mmol/g during these cycles. This might be likely due to the leaching out of SO3H group from the sulfonated carbon coated monolith surface. The leaching of active species reached a plateau state after fourth cycle. 相似文献
2.
Critical loads offer a unique way of evaluating impacts of acid deposition by quantifying environmental sensitivity. The critical loads of acidity for UK peat soils have been based upon an arbitrary reduction in pH of 0.2 units. This chemical shift needs to be better related to adverse effects on sensitive biological receptors. It is known that effective precipitation pH equates closely to soil solution pH, and the latter is directly linkable to biotic effects of pH change. On continuation of a long-term experiment assessing impacts of simulated acid rain on peat microcosms in a realistic outdoor environment, Calluna vulgaris continued to flourish at acid deposition loads well above the existing critical load. Calluna plants were harvested and analysed, and acid deposition treatments to the microcosms continued to allow natural vegetation to regenerate. A diverse mixture of moorland plants and bryophytes established at acidity treatments well above the existing critical load, and only a very high acid load resulted in no natural regeneration. A critical effective rain pH value of 3.6 is suggested as a basis for setting critical loads. At this pH, Calluna grows well, and a healthy diverse vegetation community re-establishes when harvested. It is suggested that the peat critical load should be set at the acid load that, at any specific site, would result in a mean effective precipitation pH of 3.6. 相似文献
3.
4.
Joe Leigh Simpson James L. Mills George G. Rhoads George C. Cunningham Howard J. Hoffman Mary R. Conley 《黑龙江环境通报》1991,11(8):641-648
No clear answer concerning whether multivitamin/folate supplementation prevents neural tube defects (NTDs) is provided by three studies in the United States. All these studies are occurrence in nature, no recurrence studies having been conducted. The Atlanta Birth Defects Study is subject to pronounced memory and recall biases, the length between event and interview being as long as 16 years. In a second study (Boston University), objections can be raised to certain aspects of the experimental design, and the claim that 22 per cent of women started vitamins sufficiently early after pregnancy diagnosis to influence NTD formation is suspicious. Our NICHD case control study of 541 women in California and Illinois revealed no evidence for multivitamins or folic acid preventing NTDs. U.S. public policy-makers face difficulties in applying results of recurrence or occurrence studies in high-risk areas to low-risk areas in the U.S. 相似文献
5.
6.
煤矸石制取聚羟基氯化铝的研究 总被引:2,自引:1,他引:2
介绍了用煤矸石制取聚羟基氯化铝的方法,研究了酸浸、调整盐基度等过程的最佳工艺过程。 相似文献
7.
酸雨对种子萌发影响的实验研究 总被引:1,自引:0,他引:1
采用PH值2.5、3.0、3.5、4.5的酸雨处理小麦种子,观察种子的萌发率、平均萌发天数和萌发势。结果表明:酸雨对种子的萌发率和平均萌发无显著影响,但对种子萌发势有显著影响。 相似文献
8.
9.
Model oligo esters of terephthalic acid with 1,2-ethanediol, 1,3-propanediol, and 1,4-butanediol have been investigated with regard to their biodegradability in different biological environments. Well-characterized oligomers with weight-average molar masses of from 600 to 2600 g/mol exhibit biodegradation in aqueous systems, soil, and compost at 60°C. SEC investigations showed a fast biological degradation of the oligomer fraction consisting of 1 or 2 repeating units, independent of the diol component used for polycondensation, while polyester oligomers with degrees of polymerization higher than 2 were stable against microbial attack at room temperature in a time frame of 2 months. At 60°C in a compost environment chemical hydrolysis also degrades chains longer than two repeating units, resulting in enhanced degradability of the oligomers. Metabolization of the monomers and the dimers as well by the microorganisms could be confirmed by comparing SEC measurements and carbon balances in a Sturm test experiment. Based on these results degradation characteristics of potential oligomer intermediates resulting from a primary chain scission from copolyesters consisting of aromatic and aliphatic dicarbonic acids can be predicted depending on their composition. These results will have an evident influence on the evaluation of the biodegradability of commercially interesting copolyesters and lead to new ways of tailor-made designing of new biodegradable materials as well. 相似文献
10.