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1.
Natural rubber (NR) can be degraded depending on various factors such as heat, mechanical force, chemical reaction, and light.
Light is a very interesting factor because it can cause the NR to degrade under low temperature and pressure. The photo-degradation
of NR films was carried out to investigate the effects of the light and the temperature on the reduction of the weight-average
molecular weight (Mw) and the double bonds in the NR films. The NR films, with and without catalysts, titanium dioxide (TiO2), and potassium persulfate (K2S2O8), were exposed to light from a mercury light bulb at 7,000 and 36,000 lux, and at the temperature of 25 °C and 80 °C for
192 hrs. After exposure, the Mw of the NR films was analyzed by gel permeation chromatography (GPC). Changes in the Mw were
used to construct a kinetic model for the process, (1/Mw)=(1/Mw0)+(kt/2M0) where k is the rate constant, and M0 is the Mw of the monomer unit. The linear relationship between 1/Mw and time suggested pseudo first-order processes with
random scission. The Mw distribution information from the GPC was used to calculate the number of double bonds in the NR films.
The trend of the double bonds reduction curves was quite similar to the result obtained from the calculation from the FTIR
spectra. This indicated that this calculation method might possibly be another alternative way to obtain the number of double
bonds in the NR. 相似文献
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4.
U. Bodenhofer 《Soft Computing - A Fusion of Foundations, Methodologies and Applications》2003,7(4):220-227
This paper is devoted to a general concept of openness and closedness with respect to arbitrary fuzzy relations – along with
appropriate opening and closure operators. It is shown that the proposed framework unifies existing concepts, in particular,
the one for fuzzy preorderings as well as the triangular norm-based approach to fuzzy mathematical morphology.
The author acknowledges support of the K
plus Competence Center Program which is funded by the Austrian Government, the Province of Upper Austria, and the Chamber of Commerce
of Upper Austria. 相似文献
5.
20 0 2年 5月 30日晚 7:5 5 ,徐州市工程集团某机械厂下料车间 ,氧气汇流排中一只即将开启使用的氧气瓶发生燃烧击穿事故 ,造成一死一伤的严重后果。事故发生的第二天笔者被特邀赶到现场 ,会同调查组对事故的性质、原因进行分析鉴定 ,并通过了原因分析鉴定结论。为防止此类事故的再次发生 ,引起充装或使用单位的足够重视 ,从中吸取教训 ,把事故消灭在萌芽状态 ,减少不必要的损失 ,现将这起氧气瓶燃割事故介绍如下。1 钢瓶及汇流排的原始情况钢瓶为河北涿鹿高压气瓶制造厂生产 ,气瓶原始数据如下 :气瓶编号 0 85 15 ,水压试验TP2 2 5 ,工… 相似文献
6.
The strength of adhesion of elastomers to rigid substrates generally increases with time of contact. This effect has been studied for samples of butyl and chlorobutyl rubber adhering to some rigid substrates. The peel strength increased continuously over long periods of contact until in some cases failure became cohesive within the elastomer layer. At higher temperatures the strength increased more rapidly, consistent with the WLF relation governing molecular motions. It is postulated that slow molecular rearrangements occur at the interface and increase the bond strength. A criterion for the observed transition from interfacial to cohesive failure is suggested. 相似文献
7.
Bo Hyun Ryu Sang Yup Lee Dong Hyun Lee Gui Young Han Tae-Jin Lee Ki June Yoon 《Catalysis Today》2007,123(1-4):303-309
Carbon black has recently been reported to act as an effective catalyst for methane decomposition and to exhibit stable catalytic behavior despite carbon deposition, and thus it can be used for CO2-free production of hydrogen from natural gas. In this work, various carbon blacks with different primary particle size were investigated with respect to methane decomposition under atmospheric pressure from 1123 to 1223 K. Catalytic characteristics, such as activity, activation energy and reaction order, were investigated and compared. It was observed that with decreasing primary particle size (or increasing specific surface area), the specific activity increased and the activation energy decreased. The reaction orders for various pelletized, rubber-reinforcing carbon blacks were 0.6–0.7, about the same regardless of the primary particle size, while they were near 1 for fluffy carbon blacks. Fluffy carbon black showed higher activity and activation energy than the pelletized carbon black of the same primary particle size. Changes of the surface morphology during carbon deposition were observed by TEM. Variations of the number of active sites were discussed in regard of the primary particle size, carbon deposition and binder. The presence of different types of active sites was also suggested. 相似文献
8.
原料及配方对单组分聚氨酯胶粘剂性能的影响 总被引:5,自引:0,他引:5
以不同性质的聚醚多元醇(210,220,330,3050)、TD1-80等为主要原料,分别采用一步法和预聚物法合成单组分聚氨酯胶粘剂,并用该胶粘结橡胶粉压制成铺垫材料。研究了不同多元醇、各多元醇的不同配比、合成工艺及不同异氰酸酯指数等因素对橡胶粉粘接料(以下简称粘接料)的影响。结果表明:以220和3050的1:1混合物,TDI为主要原料,用预聚物法合成的游离NCO含量为5%的单组分聚氨酯,其拉伸强度、扯断伸长率、耐水性、耐热性等均能满足橡胶粉粘结料的性能要求。 相似文献
9.
研究了PVC和白炭和黑对热力学不相容的NBR/PVC并有耐磨和耐疲劳性的影响,并探讨了其相应机理,借助扫描电镜(SEM)观察了并用体系的屈挠疲劳断面,发现随PVC用量增加和白炭黑用量减少,疲劳断面由原来的粗糙孔洞(Coarse-hole)裂纹型变成了波浪河流(Wave-river)型,并用体系优异的耐磨和耐疲劳性是由其相容性和界面过渡层结构等决定的。 相似文献
10.