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1.
Recently, in our laboratory a closed form expression for the correlation function of the hard-sphere dimer fluid obtained
from Wertheims multidensity Ornstein-Zernike integral equation theory with Percus-Yevick approximation was presented by Kim
et al. [2001]. However, it is difficult to apply its expression to perturbation theory and vapor-liquid equilibria calculations,
since it is of very complex form. In this work, we present a simplified expression for the first shell of the radial distribution
function (RDF) of the hard-sphere dimer fluid using a series expansion of the analytical expression. The expansion is carried
out in terms of both the packing fraction and the radial distance. Expressions are also obtained for the coordination number
and its first and second derivatives as functions of radial distance and packing fraction. These expressions, which are useful
in perturbation theory, are simpler to use than those obtained from the starting equation, while giving good agreement with
the original expression results. Then we present an simplified equation of state for the square-well dimer fluid of variable
well width (λ) based on Barker-Henderson perturbation theory using its expression for the radial distribution function of
the hard-sphere dimer fluid, and test its expression with NVT and Gibbs ensemble Monte Carlo simulation data [Kim et al.,
2001]. 相似文献
2.
Specific interactions in blends containing Chitosan and functionalized polymers. Molecular dynamics simulations 总被引:2,自引:0,他引:2
Chitosan (CS)/poly(vinyl alcohol) (PVA) and Chitosan/poly(2-hydroxyethyl methacrylate) (P2HEM) blends have been studied through molecular dynamic simulations. In a previous work it was found miscibility between these polymers and it was attributed to hydrogen bonding formation. However, the experimental information obtained was not enough to know which of the interacting groups of Chitosan, i.e. -CH2OH or -NH2, are responsible of the interaction. Therefore, we have performed molecular dynamics simulation runs of 1 ns in order to calculate radial distribution functions (RDF) for the groups tentatively involved in the interaction. The results are correlated with our previous experimental data. This way, we have obtained a more precise conclusive information about the interactions involved as function of the blends composition. For low compositions of PVA and P2HEM the interaction is predominantly with the hydroxymethyl groups of CS while as the composition of PVA and P2HEM increases, the interaction with the amine groups increases. 相似文献
3.
4.
Packed beds of fuel wood chips are commonly found in thermal conversion processes such as combustion or gasification. Wood chips in particular are mostly used as fuel for small-scale domestic heating boilers but also for commercial-scale combustion units. The characterization of spatial voidage distribution inside the wood chip beds is of great importance for flow and reactor modelling. This study focuses on the radial porosity variations of cylindrical beds of three different types of commercially available wood chips including chips classified as G30 size class. The conventional technique of consolidating packed beds with a resin was chosen as the experimental procedure. The radial voidage distribution in different cylindrical beds is determined by image analysis of sections of the solidified packings. Additionally, a packing of monosized spheres was investigated in order to assess the selected procedure in comparison with widely available literature data for spheres. The results are discussed and summarized in a mathematical expression correlating the radial voidage distribution depending on average wood chip size, packing core porosity and dimensionless distance from the tube wall. 相似文献
5.
The numerical simulation of comparative elastohydrodynamic lubrication between axisymmetrical and 3D elastic approaches on the radial lip seals is presented in order to determine the 3D effect of the elastic aspect of the seal lip. Indeed, the consideration of 3D model in other words the circumferential variation of the lip elastic deformation indicated a difference in the deformation distribution of the lip compared to the axisymmetrical approach. Consequently, the results show that the presence of the circumferential variation of the seal lip deformation has a significant effect on the pumping rate values. 相似文献
6.
An on-line learning neural controller for helicopters performing highly nonlinear maneuvers 总被引:1,自引:0,他引:1
This paper presents an on-line learning adaptive neural control scheme for helicopters performing highly nonlinear maneuvers. The online learning adaptive neural controller compensates the nonlinearities in the system and uncertainties in the modeling of the dynamics to provide the desired performance. The control strategy uses a neural controller aiding an existing conventional controller. The neural controller is based on a online learning dynamic radial basis function network, which uses a Lyapunov based on-line parameter update rule integrated with a neuron growth and pruning criteria. The online learning dynamic radial basis function network does not require a priori training and also it develops a compact network for implementation. The proposed adaptive law provides necessary global stability and better tracking performance. Simulation studies have been carried-out using a nonlinear (desktop) simulation model similar to that of a BO105 helicopter. The performances of the proposed adaptive controller clearly shows that it is very effective when the helicopter is performing highly nonlinear maneuvers. Finally, the robustness of the controller has been evaluated using the attitude quickness parameters (handling quality index) at different speed and flight conditions. The results indicate that the proposed online learning neural controller adapts faster and provides the necessary tracking performance for the helicopter executing highly nonlinear maneuvers. 相似文献
7.
8.
径向磁轴承柱槽比优化分析 总被引:3,自引:0,他引:3
本文建立了以径向磁轴承最大载承力Fmax为目标,在临界温升τ等多约束条件下,对定子柱槽比k的优化模型,设计变量选取轴承静态气隙s0和定子柱槽比k,采用模糊优化算法,计算结果表明,在其它参数不变的条件下,轴承静态气隙s0和定子柱槽比k在一定的取值范围内,对最大承载力Fmax有规律性影响,达当减小轴承静态气隙s0和增大定子柱槽比k都能显著提高轴承最大承载能力Fmax,结合试验结果对灵敏度进行了分析,并给出了相应结合。 相似文献
9.
10.
气固下行流化床反应器Ⅱ气固两相的流动规律 总被引:1,自引:1,他引:1
气固下行流化床反应器气固两相流动过程是比较复杂的,沿轴向气固两相运动可分为第一加速、第二加速和恒速3个运动段,沿径向局部气体速度、颗粒速度和颗粒浓度都具有不同程度的不均匀性。而这种不均匀性是由气固两相顺重力场湍动运动所决定的。和循环床提升管相比,下行管反应器气固两相沿径向分布的不均匀性得到有效地改善,气固可以实现超短接触操作,因而是一种新型高效气固超短接触反应器 相似文献