液相混合辅助低温制备Ca_2Si_5N_8:Eu~(2+)荧光粉

采用液氨介质溶解原料金属Ca、Eu形成金属-氨溶液,原料非晶硅悬浮于溶液中,通过液氨挥发使金属-氨溶液产生过饱和,并以金属酰胺形式沉析在非晶硅表面,将这种液相混合处理的原料在常压1100℃保温6h合成Ca2Si5N8:Eu2+荧光粉。采用XRD、SEM和PL光谱仪分别表征了产物的晶体结构、微观颗粒形貌以及发光性能。结果表明:这种液相混合降低了荧光粉合成温度,在常压下1100℃保温6h合成了结晶良好的Ca2Si5N8:Eu2+荧光粉;合成的荧光粉颗粒呈类球形且分散性较好;合成的Ca2Si5N8:Eu2+荧光粉激发峰为467nm,发射峰位于580nm。     

高能球磨与反应烧结合成YAG：Ce^3＋荧光粉的研究

采用高能球磨和反应烧结相结合的方法在1300℃、碳还原气氛下合成了YAG：Ce^3＋荧光粉，通过X射线衍射分析（XRD）、场发射扫描电子显微镜图谱（FESEM）、荧光光谱（Ex，Em）研究了反应时间、Ce^3＋的掺杂量对荧光粉性能的影响。研究结果表明，当反应时间为6h时获得的产物为单一的YAG相，颗粒分布均匀且接近球形；当掺杂Ce抖的摩尔分数x=0．06时，荧光粉的相对发射强度最大。     

Polarized light microscopy and spectroscopy of individual single-walled carbon nanotubes

Polarized light microscopy (PLM) is used to image individual single-walled carbon nanotubes (SWNTs) suspended in air across a slit opening. The imaging contrast relies on the strong optical anisotropy typical of SWNTs. We combine PLM with a tunable light source to enable hyperspectral excitation spectroscopy and nanotube chirality assignment. Comparison with fluorescence microscopy and spectroscopy confirms the assignment made with PLM. This represents a versatile new approach to imaging SWNTs and related structures.      

Ba2MgSiO5:Eu2+发光材料的制备及荧光性能

采用溶胶-凝胶法制备了系列Ba_2MgSiO_5:Eu~(2+)发光材料,并采用X射线衍射仪(XRD)、荧光光谱(PL)等测试方法对样品的物相结构和发光特性进行了表征及测试。研究结果表明:Ba_2MgSiO_5:Eu~(2+)发光材料中,加入少量Eu2+离子后没有明显改变Ba2MgSiO5晶体结构。确定了晶化时间=1 h,Eu~(2+)的最佳掺杂量为摩尔分数x(Eu~(2+))=0. 05,Ba_2MgSiO_5:Eu~(2+)发光强度最佳。     

锌合金ZZnAl4—1中Mg,Fe,Pb,Sn的光谱分析方法

本文法提供了将样品采用稀硝酸溶解，蒸干，在４００℃温度下灼烧成硝酸盐氧化物，研磨成细粉，以光谱纯碳粉作缓冲剂，用电弧激发试样进行分析，其准确度：Ｍｇ±４．４％，Ｆｅ±７．４％，Ｐｂ±２．７％，Ｓｎ±３．１％，现已用于生产分析。     

EQUIVALENT EXCITATION METHOD FOR VIBRATION ISOLATION DESIGN：THEORETICAL ANALYSIS AND EXPERIMENTAL RESULTS

In view of difficulties concerned with direct measurement of excitations inside source equipments and their significant influence on vibration isolation effectiveness, a dynamical model, for vibration isolation of a rigid machine with six-degree-of-freedom mounted on a flexible foundation through multiple mounts, is analyzed, in which the complicated and multiple disturbances inside the machine are described as an equivalent excitation spectrum. And a method for the estimation of the equivalent excitation spectrum according to system dynamic responses is discussed for the quantitative prediction of isolation effectiveness. Both theoretical analysis and experimental results are demonstrated. Further work shows the quantitative prediction of transmitted power flow in a flexible vibration isolation experiment system using the proposed equivalent excitation spectrum method, by comparison with its testing results.     

Luminescence properties of BaB8O13：Eu under UV and VUV excitation

The phosphor BaB8O13:Eu3+ were synthesized by solid-state reaction, and their luminescent properties were studied under 254 and 147 nm excitation. The excitation spectrum showed two broad bands in the range of 100-300 nm: one was the host lattice absorption with the maxima at 160 nm and the other was Ba-O absorption overlapped with the CT band of Eu3+, which indicated that the energy of the host lat-tice absorption could be efficiently transferred to the Eu3+. The overlapped bands were tended to separate when monitored by different wave-length, which indicated that at least two Ba2+ sites were available in BaB8O13. The emissions of Eu3+ (612 nm) and Eu2+ (405 nm) were both observed in the emission spectra of BaB8O13:Eu3+ under the excitation of either 254 or 147 nm. With the doping concentration of Eu3+ in-creasing, the 612 nm emission was enhanced while 405 nm emission was decreased under 254 nm excitation, which was due to the persistent energy transfer from Eu2+ to Eu3+. While under 147 nm excitation, the 612 nm emission was quenched and the 405 nm emission was en-hanced. It was concluded that the preferential excitation of Eu2+ under 147 nm excitation was one of the reasons for this facts.     

共沉淀法合成YAl3（BO3）4:Ce,Tb绿色荧光粉及其性能研究

采用化学共沉淀法合成YAl3(BO3)4:Ce,Tb绿色硼铝酸盐发光材料,通过X射线衍射(XRD)和光致发光(PL)光谱对其晶体结构和荧光光谱进行研究.测试结果表明:YAl3(BO3)4:Ce,Tb发光材料属于三方晶系、空间群R32,掺入Ce3+,Tb3+离子后晶格结构没有变化;发光材料的发射光谱主峰位于541 nm处的Tb3+的5D4→7F5跃迁峰,Ce3+离子对Tb3+有敏化作用;掺杂的稀土离子配比为Ce:Tb=0.3:0.1,B的掺杂量为25%,在1 100℃下、高温烧结2h的样品的荧光强度最好.     

Eu2+掺杂的发光材料的制备及荧光性能

采用溶胶-凝胶法制备了系列Sr_2MgSiO_5:Eu~(2+)发光材料,并采用X射线衍射仪(XRD)、荧光光谱(PL)等测试方法对样品的物相结构和发光特性进行了表征及测试。研究结果表明:Sr_2MgSiO_5:Eu~(2+)发光材料中,加入少量Eu~(2+)离子后没有明显改变Sr_2MgSiO_5晶体结构,提高晶化温度有利于Sr_2MgSiO_5晶相的生成。当晶化温度为1150℃时,晶化时间为2 h,光谱强度最大Ba2MgSiO5:Eu~(2+)发光强度最佳。本文合成Sr_2MgSiO_5:Eu~(2+)发光材料可以应用到白光LED的技术中。     

Pr3+摩尔浓度对CaTiO3:Pr3+红色长余辉材料的影响

制备了不同Pr^3 摩尔浓度下的CaTiOs：Pr^3 红色长余辉材料，测量了磷光体的的初始亮度、余辉曲线、激发光谱和发射光谱、热释光曲线。研究发现CaTiO3：Pr^3 合适的Pr^3 摩尔浓度为0．1％—0．2％，在该摩尔浓度下，材料具有较好初始亮度和余辉时间。