墨西哥湾南部晚侏罗纪主力烃源岩的形成条件

通过对墨西哥湾不同时代可采储量的分布特征和油源对比资料的分析认为,晚侏罗纪烃源岩是墨西哥湾南部最主要的烃源岩。资料显示,晚侏罗纪优质烃源岩形成的主控因素是稳定的构造和沉积条件以及超咸的还原环境,其中,"世界顶级"的晚侏罗纪提塘阶烃源岩主要形成于超咸的碳酸盐岩和/或蒸发岩沉积环境,属半深海还原环境,有机质以藻类为主,推测烃源岩中的有机质可能与极端干旱气候条件下的藻类勃发有关。     

The general solution of the HENON–HEILES problem

The general solution of the Henon–Heiles system is approximated inside a domain of the (x, C) of initial conditions (C is the energy constant). The method applied is that described by Poincaré as ‘the only “crack” permitting penetration into the non-integrable problems’ and involves calculation of a dense set of families of periodic solutions that covers the solution space of the problem. In the case of the Henon–Heiles potential we calculated the families of periodic solutions that re-enter after 1–108 oscillations. The density of the set of such families is defined by a pre-assigned parameter ε (Poincaré parameter), which ascertains that at least one periodic solution is computed and available within a distance ε from any point of the domain (x, C) for which the approximate general solution computed. The approximate general solution presented here corresponds to ε = 0.07. The same solution is further improved by “zooming” into four square sub-domain of (x, C), i.e. by computing sufficient number of families that reduce the density parameter to ε = 0.003. Further zooming to reduce the density parameter, say to ε = 10⁻⁶, or even smaller, although easily performable in both areas occupied by stable as well as unstable solutions, was found unnecessary. The stability of all members of each and all families computed was calculated and presented in this paper for both the large solution domain and for the sub-domains. The correspondence between areas of the approximate general solution occupied by stable periodic solutions and Poincaré sections with well-aligned section points and also correspondence between areas occupied by unstable solutions and Poincaré sections with randomly scattered section points is shown by calculating such sections. All calculations were performed using the Runge-Kutta (R-K) 8th order direct integration method and the large output received, consisting of many thousands of families is saved as “Atlas of the General Solution of the Henon–Heiles Problem,” including their stability and is available at request. It is concluded that approximation of the general solution of this system is straightforward and that the chaotic character of its Poincaré sections imposes no limitations or difficulties.     

Oxygen isotope compositions of quartz grains (4–16 μm) from Chinese eolian deposits and their implications for provenance

Oxygen isotope compositions were measured in quartz grains extracted from a 7.0 Ma red clay-loess sequence at Lingtai and six late Pleistocene loess sediments (Malan loess). Results show that the changes in oxygen isotope compositions of Malan loess are basically controlled by the geochemical characteristics of the source materials, while the effect of weathering process after dust deposition could be minor. The oxygen isotope distribution of quartz grains from red clay at Lingtai is similar to that of the overlying loess-paleosol sequence, thus indicating that the red clay at Lingtai has the same eolian origin as the loess-paleosol deposits. Furthermore, the oscillations of the isotope compositions in 4–16 μm-sized quartz grains may reflect the changes, to some extent, of the climatic systems of the source region.     

Measurements of stable carbon isotopic composition of ethane and propane over the western North Pacific and eastern Indian Ocean: A useful indicator of atmospheric transport process

Stable carbon isotopic composition of ethane and propane over the western North Pacific and eastern Indian Ocean between 31°N and 26°S was investigated from February through March 2004. The isotopic composition of ethane ranged from −28 to −18‰ and showed a gradual increase from north to south. Conversely, that of propane was between −31 and −24‰; it showed no systematic latitudinal variation. Investigation of the ethane/propane ratio indicates that ethane and propane that originated from northern mid-latitude countries in the eastern part of Eurasia were both transported into the western North Pacific region. However, the results of the isotopic analyses indicate the contribution of oceanic emission to the atmospheric propane during transport, although that contribution can not be discerned for ethane. A ship based stationary observation conducted in the western equatorial North Pacific showed that the isotopic composition of ethane varied from −25 to −19‰ and showed clear systematic diurnal variation: propane ranged between −32 to −26‰ and no such isotopic diurnal signal was observed. The diurnal variation for ethane is explained by entrainment of free tropospheric air, whereas the variation for propane was influenced by oceanic emissions as well as the entrainment. The contribution of oceanic emissions to the atmospheric propane inventory was considered from our isotopic observation. Isotopic composition of dissolved propane is estimated to be less than −38‰, and the contribution up to 79% was calculated when the isotopic composition of dissolved propane is assumed to be −40‰. Our study demonstrates that isotopic analysis can be more useful than ratio-based analysis to improve our present understanding of transport processes, especially for impact of the oceanic emissions on the atmospheric distribution of low level C₂–C₅ non-methane hydrocarbons such as propane in the remote marine atmosphere.