Evolution of 2:1 layered silicates in low-grade metamorphosed Liassic shales of Central Switzerland

White mica from the Liassic black shales and slates in Central Switzerland was analysed by transmission electron microscopy (TEM) and electron microprobe to determine its textural and compositional evolution during very low-grade prograde metamorphism. Samples were studied from the diagenetic zone, anchizone and epizone (T ≈100°–450 °C). Phyllosilicate minerals analysed include illite/smectite (I/S), phengite, muscovite, brammallite, paragonite, margarite and glauconite. Textural evolution primarily is towards larger, more defect-free grains with compositions that approach those of their respective end-members. The smectite-to-illite transformation reduced the amounts of the exchange components SiK_?1Al_?1, MgSiAl_?2, and Fe³⁺Al_?1. These trends continue to a lesser degree in the anchizone and epizone. Correlations between the proportion of smectite in I/S and the composition of I/S indicate that smectite layers may contain a high layer charge. Illite in I/S bears a compositional resemblance to macrocrystalline phengite in some samples, but is different in others. Paragonite first appears in the upper diagenetic zone or lower anchizone as an interlayer-deficient brammallite, and it may be mixed with muscovite on the nanometre scale. Owing to the small calculated structure factor for paragonite-muscovite superstructures, conventional X-ray powder diffraction cannot distinguish between mixed-layer structures and a homogeneous compositionally intermediate solid solutions. However, indirect TEM evidence shows that irregularly shaped domains of Na- and K-rich mica exist below 10 nm. Subsequent coarsening of domains at higher grades produced discrete paragonite grains at the margins of muscovite crystals or in laths parallel to the basal plane of the host muscovite. Margarite appears in the epizone and follows a textural evolution similar to paragonite in that mixtures of margarite, paragonite, and muscovite may initially occur on the nanometre scale. However, no evidence of interlayer-poor margarite has been found.     

区域土壤环境地球化学研究——异常成因判别·环境质量·污染程度评价的思路与方法

从概念内涵和应用目标出发,认为土壤环境地球化学质量评价应该分为质量现状和污染程度两个方面.在此基础上探讨了区域地球化学资料在土壤环境现状质量评价、异常成因识别、污染元素累积速率和土壤污染程度评价研究的基本思路和方法.     

极谱催化波测定天然水中微量锗的研究

系统研究了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４－Ｖ体系报道极谱催化波的影响因素，测定了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４三元配合物的配合比为１：２：１。实验初步证明了该体系催化波为具有吸附性质的平行催化波。本法检出限为０．１４ｍｇ．ｍＬ＾－１，相对标准偏差小于９．８９％，标准回收率为９３．７０％－１０９．０％，０－５０ｍｇ．ｍＬ＾－１的锗具有良好的线性关系。     

Grade estimation using fuzzy- set algorithms

This paper presents a new approach for estimating unknown ore grades within a mining deposit in a fuzzy environment using fuzzy c- means clustering and a fuzzy inference system. Based on a collection of cluster centers obtained from fuzzy c- means, a fuzzy rule base and fuzzy search domains are established to compute grades at these cluster centers. These cluter center- grade pairs act as control information in the fuzzy space- grade system in order to infer unknown grades on the basis of fuzzy interpolation, fuzzy extrapolation, and a defuzzification process of fuzzy control.     

临沧超大型锗矿床有机质与锗矿化的地球化学特征

临沧锗矿床是一产于第三系含煤岩系中的超大型矿床。矿床的最初锗源与盆地西缘的二云母花岗岩有关。主矿体产于下煤组沉积旋回的早期地层中，每一沉积阶段早期形成的褐煤和碳质泥岩中富含锗，最高含量达１４７０×１０＾－６。褐煤和碳质泥岩在矿化过程中平均富集了１６４－１６９倍。根据锗含量，褐煤和碳质泥岩可分为锗含量小于１２×１０＾－６的低锗煤（泥岩）和大于９０×１０＾－６的高锗煤（泥岩）。高锗煤中有机质富含氧官能     

内蒙古胜利煤田共生锗矿的成因地球化学初探

用统计和作图的分析方法,对内蒙古胜利煤田中共生锗矿床的锗品位与挥发分、灰分、硫分的关系进行了研究。结果表明煤中锗品位与挥发分呈正相关、与原煤灰分负相关、与洗煤灰分正相关关系;全区煤属中硫煤,锗品位与原煤和洗煤硫分均呈正相关关系,煤的灰分指数较低(3 579);锗分布不均匀,富锗煤矿明显属于断裂坳陷边缘沉积,锗品位可以在煤层的顶部、中部、底部同时或单个部位呈现高值,大多数煤层中部出现锗高品位值,这有别于以往所报道的锗品位只在煤层顶、底部相对富集的研究结论。认为胜利煤田锗主要与有机质结合;锗的有利聚集条件是水动力较弱、地下水位较低、强还原的停滞沼泽环境;泥炭聚集阶段有机质的吸附作用是锗的主要富集机制。     

一种新玉种—黄龙玉

黄龙玉矿床主要分布在云南省保山市龙陵县小黑山一带,矿体产于三叠系公养河群板岩与花岗岩接触带上。自古生代以来,除石炭纪、古近纪和新近纪外,其它地层均有出露。矿区岩浆活动频繁,具有多期次多阶段的岩浆侵入。黄龙玉的化学成分主要为SiO2,矿物成分为石英、玉髓和蛋白石,相对密度2.65～2.70,折射率1.54～1.56,Fe3+为致色离子,颜色成因以内源氧化转色为主,隐晶质—微粒结构,块状构造、条带状构造和角砾状构造。本文对黄龙玉产出的地质特征、宝石矿物学特征、品质特征以及与相似宝玉石—田黄和黄色翡翠对比等方面进行了深入阐述,为市场宝石的鉴别提供了一定的参考价值。     

乌力吉木仁河三级区水资源变异及归因分析

随着气候变化和人类活动对水资源影响越来越显著,大量水文序列的统计规律不再满足一致性要求而出现了变异。水资源日益重要的社会地位,要求在对水文变异进行检测的同时,需进一步量化影响其变异的因素,但目前归因分析的研究仍以定性或半定量为主。由于降雨和径流是水循环中关键的水文要素,且分别可以反映气候变化和人类活动对水资源的影响,利用降雨-径流关系提出了定量研究水资源变异的归因分析方法。结合乌力吉木仁河三级区1956~2000的年径流和年降雨序列,在对其分别进行变异诊断的基础上,定量地分析了造成该区水文变异的原因。计算结果表明:气候变化对乌力吉木仁河三级区水资源变异的贡献率为24%,而人类活动影响的贡献率为76%,可见人类活动是造成该区水资源变异的主要因素。     

模糊地理实体不确定性综合描述研究

从二型模糊的角度讨论了模糊地理实体的不确定性,基于空间数据的位置误差,利用模糊集的λ-截集和圆误差带模型推导了模糊地理实体隶属度的误差模型,并给出了隶属度不确定性的度量方法,提出了用隶属度误差立方体来综合描述模糊点的不确定性。     

新疆尼勒克县喀英迪地区铅锌矿地质特征及成因

喀英迪铅锌矿主要产于早石炭世阿克沙克组及其与晚奥陶世呼独克达坂组的接触带上。通过普查工作共圈定15个铅锌矿体。其中主要矿体4个,Ⅰ-4矿体处于晚奥陶世呼独克达坂组灰岩与早石炭世阿克沙克组的不整合接触面上及其两侧,工程控制总长度为523m,最大斜深100m。倾向70°～100°,倾角一般20°～50°,连续性较好。该矿体铅单工程厚0.86～5.64m,平均2.86m,厚度变化系数为70.57%;锌单工程厚0.80～5.64m,平均1.81m,厚度变化系数为93.97%,属于变化较稳定型矿体。铅单工程品位0.62%～16.47%,平均4.53%,品位变化系数114.34%;锌单工程品位0.53%～12.37%,平均3.78%,品位变化系数57.47%。属于有用组分分布较均匀型矿体。通过对矿床地质特征的研究,认为该矿床属沉积岩容矿的、层控的、构造控制非岩浆型低温热液矿床。