南海波高熵和风速熵

根据风速的统计分布，给出了有因次风速熵和无因次风速熵的定义及其计算方法，使用ＧＥＯＳＡＴ高度计１９８６年１１月－１９８９年２月的有效波高和风速的资料，计算，分析了南海海域上的波高熵，风速熵，给出它们的时间变化特征和空间变化特征，并对不同随机量的无因次熵，即随机度进行了比较。     

全球海洋与大气界面的熵通量估算

给出并讨论了海洋系统中由于热量交换、物质交换以及外力做功引起的熵通量的表达式;同时,根据新近调整的全球海 气界面的气候平均资料,估计了全球海洋与大气界面气候年平均的熵通量(熵流),这一熵通量主要取决于海 气界面的热量和物质交换的空间不均匀性。计算结果显示,由热量交换分量引起的熵通量对海洋系统的总熵通量起到主要的贡献作用,其值约为-555.6mW·(m2·K)-1;由海表风应力做功引起的熵通量相对较小,约为-0.09mW·(m2·K)-1;由物质交换引起的熵通量最小,仅为-0.02mW·(m2·K)-1。总的来说,海洋系统从外界获得的总熵通量为-555.7mW·(m2·K)-1,这也就意味着在气候平均定态下,海洋系统内部的熵产生在量值上等于系统的熵交换,即为555.7mW·(m2·K)-1。海洋系统的负熵流与其内部的各种不可逆过程引起的熵产生取得平衡,确保了全球海洋系统处于非平衡热力学定态,并维持着海洋系统中各种尺度的时 空有序现象的消长过程。     

最大熵原理与地震频度-震级关系

地震是一种随机事件 ,它的发生具有极大的不确定性 ,因而可以用熵来进行描述。地震以最无序的方式在各地发生 ,意味着地震熵达到了极大值。古登堡 (Gutenberg)和里克特 (Richter)根据资料和经验得出的地震频度 -震级关系式实际上是在给定的约束条件下 ,当地震熵取极大值时得到的一种负指数分布。文中从最大熵原理得出了同一形式的地震频度 -震级关系 ,使它的来源从理论上得到了解释     

广东及邻区地震活动熵值的异常特征

应用文献」１「的方法，对广东及部分邻近地区进行了熵值计算和分析处理，结果表明，时间熵，频度熵和强度熵在ＭＬ≥４．７级地震之前，大都存在较明显的低值变化，即存在减熵现象，地震大多数以生在减熵的中，后期，少数发生在减熵初期。三种熵值变化基本同步，震级越大，熵值波动越大，其中尤以强度熵变化幅度最大，频度熵次之，时间熵最弱。     

河流调整中的熵、熵产生和能耗率的变化

河流是一个真正的开放系统,而不是孤立系统或封闭系统。运用经典热力学和非平衡态热力学基本原理,分析研究了河流调整中的熵、熵产生和能耗率的变化。指出:熵和熵产生是两个不同的概念;最小熵产生原理等价于最小能耗率原理;冲积河流在调整过程中遵循最小熵产生原理或最小能耗率原理,而不是最大熵原理。     

The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.     

乡村生产空间系统演化的逻辑认知及数理表达

乡村生产空间系统健康有序运行是实施乡村振兴、营建人与自然和谐共生的物质基础和载体,精准控制系统由低级有序向高级有序发展是关键。综合社会学、哲学、系统学和地理学等多学科理论,建构乡村生产空间系统演化的逻辑认知概念模型,对其演化的逻辑起点(人地关系)、逻辑顺序(时间、空间和流三维分析)以及流驱动机理进行质性研究,探寻乡村生产空间系统演化的内在本质;借鉴耗散结构理论和熵变理论,构建乡村生产空间系统演化熵变模型并作出相关释义,为研究人地关系系统演化提供思路,以丰富和拓展乡村地理学的理论。     

台风运动内在随机性的研究

本文用差分方法，对决定性的正压涡度方程实施了四组数值积分。根据模式输出量，求得了台风中心移速的一维序列和二维序列。计算了移速序列的关联维数和Ｋ熵。结果表明模式大气中台风中心的移动具有内在随机性。最后讨论了局域热源和基流对台风移动路径随机性和可预测性的影响。     

Quantifying Organization of Atmospheric Turbulent Eddy Motion Using Nonlinear Time Series Analysis

Using three methods from nonlinear dynamics, we contrast the level of organization inthe vertical wind velocity (w) time series collected in the atmospheric surface layer(ASL) and the canopy sublayer (CSL) for a wide range of atmospheric stability ()conditions. The nonlinear methods applied include a modified Shannon entropy, waveletthresholding, and mutual information content. Time series measurements collected overa pine forest, a hardwood forest, a grass-covered forest clearing, and a bare soil, desertsurface were used for this purpose. The results from applying all three nonlinear timeseries measures suggest that w in the CSL is more organized than that in the ASL, and that as the flows in both layers evolve from near-neutral to near-convective conditions, the level of organization increases. Furthermore, we found that the degree of organization in w associated with changes in is more significant than the transition from CSL to ASL.