Dissolution and depletion of ferromagnesian minerals from Holocene tephra layers in an acid bog,New Zealand,and implications for tephra correlation

This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies.     

铜川王石凹黑色高岭石粘土岩的成因分析

黑色高岭石粘土岩，是铜川王石凹煤矿石炭纪煤系地层顶部，五号煤层的上部一层稳定的煤矸石。经偏光显微镜及费氏台测试光性特征、化学试验及分析鉴定表明，这是一种由高岭石组成的，成分很纯、颗粒大、结晶良好的高岭石粘土岩。据微量元素含量分析，此高岭石系淡水沉积物。     

一种提高粘土矿物去除赤潮生物能力的新方法

在研究粘土颗粒与赤潮生物絮凝作用的基础上，建立了粘土表面改性对其絮凝作用影响的理论模型，认为改变粘土颗粒的表面性质提高其去除赤潮生物能力的主要途径，提出在粘土中引入ＰＡＣＳ（聚羟基氯化铝）的改性方法。结果表明，对于微型原甲藻（Ｐｒｏｒｏ－ｃｅｎｔｒｕｍ ｍｉｎｉｍｕｎ）体系，粘土中引入微量ＰＡＣＳ后，其去除率达９０％以上的高岭土用量由原来的２ｇ／Ｌ降至０．１ｇ／Ｌ，去除效率提高近２０倍。考察了ＰＡ     

Upper Cretaceous carbonate hosted zinc–lead–barite deposits in Northern Thrust Zone, northern Iraq: petrography and geochemistry

Zinc–lead–barite deposits located in Lefan and Lower Banik localities of about 25 km northeast of Zakho City, Northern Iraq consist of a group of strata-bound sulfides hosted in Upper Cretaceous (Upper Campanian–Maastrichtian) dolomitic limestone. Carbonate-hosted ores contain 3.77% Zn, 2% Pb, and 5% Fe, while in lower Banik, they contain 1.5% Zn, 0.37% Pb, and 1.4% Fe. Diagenetic processes, such as dolomitization and recrystalization in addition to the type of microfacies, provided appropriate physical and chemical conditions that permitted the passage of ore-bearing fluids and participated in precipitation and ore localization. These deposits are precipitated in a platform and developed within the Foreland Thrust Belt. Ore precipitated as infill of intergranular dolomite porosity with replaced dolomite and rudist shells forming disseminated crystals that occupy intergranular pore spaces around dolomite and calcite and as infill of dissolution spaces and fractures.     

Direct shear tests on Mexico City clay with reference to friction pile behaviour

Summary This paper presents results of static and cyclic direct shear tests performed on undisturbed and remoulded samples of Mexico City clays, including results of soil-on-interface tests. Experiments show that the static adhesion coefficient depends on the soils' liquidity index and that it diminishes due to the effect of repeated dynamic loads. Dynamic overstrength effects were not apparent, as has been observed when testing this clay in other apparatus. Interface strength in remoulded clays is initially less than half the strength of interfaces with undisturbed materials but it increases with time. At least in the materials tested in this research, it did not equal the strength of interfaces with undisturbed materials. Correction factors derived from experimental data can be used to modify the adhesion coefficient to account for dynamic and remoulding effects.     

Atomistic calculations of structural and elastic properties of serpentine minerals: the case of lizardite

The physical properties of the hydrous phyllosilicate lizardite have been investigated by atomistic simulation using the GULP code based on transferable semi-empirical interatomic potentials. Lizardite behavior was first investigated during structure relaxation at room temperature. The Helmholtz free energy is minimum for an equilibrium structure that is in agreement with experiment. The bulk, shear, and Young modulii for lizardite were calculated along with the Poisson ratio. From the shear and bulk modulii, we also calculated translational and longitudinal acoustic wave velocities that are important quantities for tectonophysics models. As expected, lizardite is stiffer in the a direction parallel to the layers than in the c perpendicular direction; the variation of the unit cell parameters with pressure is in good agreement with experiment. The cohesive energy between two successive layers along c direction was calculated at 0.33 eV (i.e., 0.11 eV per OH bond) in good agreement with recent ab initio calculations. Upon pressure and temperature variations, we evidenced that structural changes are mainly pressure induced; pressure being accommodated by a decrease of the c parameter up to 10 GPa. We also found that the change of slope in the derivative of the c cell parameter with respect to pressure occurring around 2 GPa originates from the bending of the interlayer hydroxyl groups with respect to the layer normal direction.     

大洋粘土制备白炭黑后的铝回收实验研究

为了回收大洋粘土制备白炭黑后残液中的Al3 ,并获得氧化铝超细粉体,实验选用NH3.H2O为沉淀剂,在常温下采用沉淀法使残液中Al3 以氢氧化铝形式沉淀并去除其它杂质离子,然后将得到的沉淀在1200℃灼烧,保温1h。利用IR和XRD测试了产物的物相组成和结构,证实实验可以获得纯度较高的α-Al2O3;而SEM和粒度分析结果显示产物粒度细小,部分颗粒可以达到纳米级;BET结果显示Al2O3的比表面积可达32m2/g。根据氧化铝结构和性能等优选的实验条件为大洋粘土的进一步开发利用提供了参考依据。     

A non-linear stress-stiffness model for geomaterials at small to intermediate strains

A double exponential fitting model (DEFM) capable of expressing the non-linear stress-stiffness relationship of geomaterials has been proposed by Shibuya et al. (1997). The model comprises two material constants; the elastic stiffness at very small strains and the strength, together with other free parameters to determine the complete stress-stiffness relationship. In this paper, the capability of the original function used for DEFM in simulating the tangent stiffness-stress relationship of geomaterials is first discussed. Second, the methods for determining the free model parameters, as well as its conversion to obtain a stress-strain relationship are proposed. The applicability of DEFM to predicting non-linear stress-stiffness relationship is examined in detail in a total of forty-nine fitting cases of compression test data on sedimentary rock, artificial soft rock and soft clay. It is found that the DEFM is effective in expressing the non-linear stress-stiffness relationship of various kinds of geomaterials at small to intermediate strains, say less than 0.5%. The superiority of this model compared to other fitting models currently in use is also demonstrated in some of the fitting cases.     

国外漂白粘土和澄清粘土的产销现状综述

漂白粘土和澄清粘土应具有较大的表面积、较高的吸附性能及褪色能力,多由膨润土经活化(酸化)处理后制成。当前,德国、美国在世界漂白土生产中占据重要地位。漂白粘土和澄清粘土世界市场销量约86万t/a,其中70％～80％用于食用油和油脂工业。漂白粘土的发展受食用油工业发展的影响最大,亚洲还有较大的发展空间。澄清粘土多用作葡萄酒、果汁等的澄清剂,也有一定的发展前景。漂白土再利用的途径,仍在探索中。