North European last glacial–interglacial transition (LGIT; 15–9 ka) tephrochronology: extended limits and new events

High‐precision correlation of palaeoclimatic and palaeoenvironmental records is crucial for testing hypotheses of synchronous change. Although radiocarbon is the traditional method for dating late Quaternary sedimentary sequences, particularly during the last glacial–interglacial transition (LGIT; 15–9 ka), there are inherent problems with the method, particularly during periods of climate change which are often accompanied by major perturbations in atmospheric radiocarbon content. An alternative method is the use of tephras that act as time‐parallel marker horizons. Within Europe, numerous volcanic centres are known to have erupted during the LGIT, providing considerable potential for high‐precision correlation independent of past radiocarbon fluctuations. Here we report the first identification of the Vedde Ash and Askja Tephra in Ireland, significantly extending the known provenance of these events. We have also identified two new horizons (the Roddans Port Tephras A and B) and tentatively recognise an additional horizon from Vallensgård Mose (Denmark) that provide crucial additional chronological control for the LGIT. Two phases of the Laacher See Tephra (LST) are reported, the lower Laacher See Tephra (LLST) and probably the C2 phase of the Middle Laacher See Tephra (MLST‐C2) indicating a more northeasterly distribution of this fan than reported previously. Copyright © 2006 John Wiley & Sons, Ltd.     

基于不同GCP数量和获取方法的数字正射影像的制作与评定

SPOT-5影像的高分辨率和高信息量的性质,使其得到了广泛的应用,特别是在全国第二次土地利用调查中得到了更加深入的应用。而数字正射影像的制作是SPOT-5遥感影像应用的关键所在。本文在介绍DOM制作的基础上,依据当前获取GCP主要的三种途径采用ERDAS遥感图像处理软件进行了实验,并对最终的结果精度进行分析,总结了DOM制作过程的相关问题。     

Crustal structure of the Lofoten–Vesterålen continental margin, off Norway

By compiling wide-angle seismic velocity profiles along the 400-km-long Lofoten–Vesterålen continental margin off Norway, and integrating them with an extensive seismic reflection data set and crustal-scale two-dimensional gravity modelling, we outline the crustal margin structure. The structure is illustrated by across-margin regional transects and by contour maps of depth to Moho, thickness of the crystalline crust, and thickness of the 7+ km/s lower crustal body. The data reveal a normal thickness oceanic crust seaward of anomaly 23 and an increase in thickness towards the continent–ocean boundary associated with breakup magmatism. The southern boundary of the Lofoten–Vesterålen margin, the Bivrost Fracture Zone and its landward prolongation, appears as a major across-margin magmatic and structural crustal feature that governed the evolution of the margin. In particular, a steeply dipping and relatively narrow, 10–40-km-wide, Moho-gradient zone exists within a continent–ocean transition, which decreases in width northward along the Lofoten–Vesterålen margin. To the south, the zone continues along the Vøring margin, however it is offset 70–80 km to the northwest along the Bivrost Fracture Zone/Lineament. Here, the Moho-gradient zone corresponds to a distinct, 25-km-wide, zone of rapid landward increase in crustal thickness that defines the transition between the Lofoten platform and the Vøring Basin. The continental crust on the Lofoten–Vesterålen margin reaches a thickness of 26 km and appears to have experienced only moderate extension, contrasting with the greatly extended crust in the Vøring Basin farther south. There are also distinct differences between the Lofoten and Vesterålen margin segments as revealed by changes in structural style and crustal thickness as well as in the extent of elongate potential-field anomalies. These changes may be related to transfer zones. Gravity modelling shows that the prominent belt of shelf-edge gravity anomalies results from a shallow basement structural relief, while the elongate Lofoten Islands belt requires increased lower crustal densities along the entire area of crustal thinning beneath the islands. Furthermore, gravity modelling offers a robust diagnostic tool for the existence of the lower crustal body. From modelling results and previous studies on- and off-shore mid-Norway, we postulate that the development of a core complex in the middle to lower crust in the Lofoten Islands region, which has been exhumed along detachments during large-scale extension, brought high-grade, lower crustal rocks, possibly including accreted decompressional melts, to shallower levels.     

High-T phase transition of synthetic ANaB(LiMg)CMg5Si8O22(OH)2 amphibole: an X-ray synchrotron powder diffraction and FTIR spectroscopic study

The synthetic amphibole Na_0.95(Li_0.95Mg_1.05)Mg₅Si₈O₂₂(OH)₂ was studied in situ at high-T, using IR OH-stretching spectroscopy and synchrotron X-ray powder diffraction. At room-T the sample has P2₁ /m symmetry, as shown by the FTIR spectrum. It shows in the OH region two well-defined and intense absorptions at 3,748 and 3,712 cm⁻¹, respectively, and two minor bands at 3,667 and 3,687 cm⁻¹. The main bands are assigned to the two independent O–H groups in the primitive structure. The two minor bands evidencing the presence of small amount of vacant A-site (^A□_0.05). With increasing T, these bands shift continuously and merge into a unique absorption at high temperature. A change as a function of increasing T is revealed by the evolution of the refined unit-cell parameters, whose trend shows a transition to C2/m at about 320–330°C. The spontaneous scalar strain, fitted with a tricritical 2–6 Landau potential, gives a T _c of 325(10)°C (β parameter = 0.27). Comparison with the second-order P2₁ /m ⇔ C2/m phase transition at 255°C for synthetic amphibole ^ANa_0.8^B(Na_0.8Mg_1.2)^CMg₅Si₈O₂₂(OH)₂ indicates that the substitution of Na with Li at the B-sites strongly affects the thermodynamic character and the T _c of the phase transition. The comparison of LNMSH amphiboles with cummingtonitic ones shows that the high-T thermodynamic behaviour is affected by A-site occupancy.     

层状侵入体韵律层理形成过程的定量模拟——以四川攀枝花层状岩体为例

层状侵入体的韵律层理是一种特殊的岩石构造,长期以来其成因倍受关注,成因假说很多。本文在综合这些观点关于岩浆物理,化学性质的研究,尤其是在岩浆房地对流特征研究成果的基础上,提出了新的成因解释,认为固化带前锋处矿物的结晶,熔浆组分的扩散及固化带前锋本身的推进等３个因素的相互耦合是形成韵律层理的主要机制,这个过程是发生在一定过冷却条件下的,在这种定性认识基础上,笔者提出了旨在对韵律层理形成过程进行模拟计     

Weak ENSO Asymmetry Due to Weak Nonlinear Air–Sea Interaction in CMIP5 Climate Models

State-of-the-art climate models have long-standing intrinsic biases that limit their simulation and projection capabilities.Significantly weak ENSO asymmetry and weakly nonlinear air–sea interaction over the tropical Pacific was found in CMIP5(Coupled Model Intercomparison Project, Phase 5) climate models compared with observation. The results suggest that a weak nonlinear air–sea interaction may play a role in the weak ENSO asymmetry. Moreover, a weak nonlinearity in air–sea interaction in the models may be associated with the biases in the mean climate—the cold biases in the equatorial central Pacific. The excessive cold tongue bias pushes the deep convection far west to the western Pacific warm pool region and suppresses its development in the central equatorial Pacific. The deep convection has difficulties in further moving to the eastern equatorial Pacific, especially during extreme El Ni o events, which confines the westerly wind anomaly to the western Pacific. This weakens the eastern Pacific El Ni o events, especially the extreme El Ni o events, and thus leads to the weakened ENSO asymmetry in climate models. An accurate mean state structure(especially a realistic cold tongue and deep convection) is critical to reproducing ENSO events in climate models. Our evaluation also revealed that ENSO statistics in CMIP5 climate models are slightly improved compared with those of CMIP3. The weak ENSO asymmetry in CMIP5 is closer to the observation. It is more evident in CMIP5 that strong ENSO activities are usually accompanied by strong ENSO asymmetry, and the diversity of ENSO amplitude is reduced.     

Robustness of Precipitation Projections in China:Comparison between CMIP5 and CMIP3 Models

Three sources of uncertainty in model projections of precipitation change in China for the 21st century were separated and quantified: internal variability,inter-model variability,and scenario uncertainty.Simulations from models involved in the third phase and the fifth phase of the Coupled Model Intercomparison Project(CMIP3 and CMIP5) were compared to identify improvements in the robustness of projections from the latest generation of models.No significant differences were found between CMIP3 and CMIP5 in terms of future precipitation projections over China,with the two datasets both showing future increases.The uncertainty can be attributed firstly to internal variability,and then to both inter-model and internal variability.Quantification analysis revealed that the uncertainty in CMIP5 models has increased by about 10%–60% with respect to CMIP3,despite significant improvements in the latest generation of models.The increase is mainly due to the increase of internal variability in the initial decades,and then mainly due to the increase of inter-model variability thereafter,especially by the end of this century.The change in scenario uncertainty shows no major role,but makes a negative contribution to begin with,and then an increase later.     

CMIP5模式对东太平洋ITCZ偶极子模态模拟能力的评估

本研究利用第五次国际间耦合模式比较计划(Coupled Model Intercomparison Project phase 5, CMIP5)中的24个模式的工业革命前控制试验(Pre-industrial Control, picontrol)模拟结果, 结合观测资料, 评估了24个CMIP5 模式对东太平洋热带辐合带偶极子(Eastern Pacific ITCZ dipole, EPID)降水模态的模拟能力, 并建立了其与模式对热带太平洋气候态模拟之间的联系。结果表明: 1) 绝大多数模式在北半球春季(2—4月)对EPID模态模拟能力较差, 主要原因在于CMIP5模式对热带辐合带(Intertropical Convergence Zone, ITCZ)的模拟偏差, 其中模拟效果较差的模式在2—4月的气候态降水分布在赤道以南, 且降水普遍偏强; 2) 对各模式的EPID模态选取的季节按照技巧评分最高进行调整后, 大部分模式能较好地模拟出EPID模态的空间分布特点, 技巧评分在0.6以上, 其中模拟效果好的模式(技巧评分大于0.7)中EPID模态出现的月份同时在中东太平洋气候态表现出“双ITCZ”特征, 且多模式集合结果的模拟误差小于绝大多数模式。     

基于CMIP5多模式集合资料的中国气温和降水预估及概率分析

选用国际耦合模式比较计划第五阶段（CMIP5）提供的30个全球大气-海洋耦合模式（AOGCMs）在典型浓度路径（RCPs）情景下气温和降水量的预估结果,采用扰动法,用站点观测资料作为气候背景场替代AOGCM模拟的气候平均,尝试校正气候预估结果的系统性偏差。通过集合方法,用概率的形式给出中国平均气温升高1 ℃,2 ℃和3 ℃以及降水量增加10%,20%和30%概率的空间分布,讨论了中国未来平均气温和降水量可能的变化。结果表明：经过扰动法处理后的气温和降水量预估集合保留了当前气候的局地信息。预估平均气温在中国均有上升,北方地区尤其是青藏高原地区变暖的程度大于南方地区,北方大部分地区平均气温升高的趋势为0.28 ℃/10a。在21世纪初,中国北方地区年平均气温升高1 ℃的可能性超过50%。到了21世纪末期,中国大部分地区平均气温升高2 ℃的可能性超过60%,新疆北部以及青藏高原南部地区气温升高3 ℃的可能性超过50%。预估中国降水量普遍增多,中国北方地区降水量增多的程度要明显大于江淮流域及其以南地区,尤其是西北地区降水量增多非常显著,降水量增多30%的可能性超过70%以上。     

TritonX-100－5-Br-PADAP光度法测定铜和镍

研究了非离子型表面活性剂Ｔｒｉｔｏｎ Ｘ－ １００ 存在下,用５ － Ｂｒ － ＰＡＤＡＰ 光度法测定铜、镍的方法。结果表明：在ｐＨ９ ．０ 的硼砂缓冲介质中,５ － Ｂｒ － ＰＡＤＡＰ 与铜和镍生成紫红色络合物,λＣｕｍ ａｘ ＝ ５７５ ｎｍ ,εＣｕ ＝ １ ．０４ ×１０５ Ｌ·ｍｏｌ－ １·ｃｍ － １ ;λＮｉｍ ａｘ ＝ ５７５ ｎｍ ,εＮｉ ＝ １ ．１４ ×１０５ Ｌ·ｍｏｌ－ １·ｃｍ － １ 。铜和镍的质量浓度分别在０ ～５６０ μｇ／ Ｌ和０ ～４４０ μｇ／ Ｌ符合比尔定律。加入六偏磷酸钠后,由于偏磷酸镍的形成,镍不再与５ － Ｂｒ － ＰＡＤＡＰ 显色,可通过铜及铜镍总量的测定,计算出镍的含量。用该方法实测了钢样中铜和镍的含量,结果与推荐值相符,对铜和镍５ 次测定的ＲＳＤ均小于５ ％ 。