天然气水合物与传统油气资源共生成藏模式初探

天然气水合物与常规油气资源的成藏在时空上存在密切联系,在一定条件下可以共生成藏。存在泄漏共生、封盖共生和遮盖侧储三种基本的共生成藏模式。泄漏共生模式是先期形成了传统油气藏,而后由于发生油气泄漏并在其上方形成天然气水合物,其特征是在水合物的下方生、储、盖齐备;封盖共生模式则是先在上部形成天然气水合物,同时作为下部传统油气藏的盖层,其特征是水合物之下的传统油气藏具备生、储成藏条件,但缺乏盖层成藏要素;遮盖侧储模式是由于水合物矿藏的遮盖作用,迫使在下部形成的烃类物质向上运移时改道,在旁侧具成藏条件的邻区成藏。实际的地质成藏可能会出现这些基本模式的组合形式。     

Accumulation by securitization: Commercial poaching,neoliberal conservation,and the creation of new wildlife frontiers

Part of a broader interest in the escalating securitization of conservation practice, scholars are beginning to take note of an emerging relationship between conservation–securitization, capital accumulation, and dispossession. We develop the concept of accumulation by securitization to better grasp this trend, positioning it in the critical literatures on neoliberal conservation, green grabbing, and conservation-security. The concept captures the ways in which capital accumulation, often tied to land and resource enclosure, is enabled by practices and logics of security. Security logics, moreover, increasingly provoke the dispossession of vulnerable communities, thereby enabling accumulation. We ground the concept by turning to the Greater Lebombo Conservancy (GLC) in the Mozambican borderlands. This is a new privately-held conservancy built as a securitized buffer zone to obstruct the movement of commercial rhino poachers into South Africa’s adjacent Kruger National Park. We show how wildlife tourism-related accumulation here is enabled by, and in some ways contingent upon, the GLC’s success in curbing poaching incursions, and, relatedly, how security concerns become the grounds upon which resident communities are displaced. In terms of the latter, we suggest security provides a troubling, depoliticized alibi for dispossession. Like broader neoliberal conservation and green grabbing, we illustrate how accumulation by securitization plays out within complex new networks of state and private actors. Yet these significantly expand to include including security actors and others motivated by security concerns.     

Strain accumulation in sand due to cyclic loading: drained triaxial tests

Our aim is the prediction of the accumulation of strain and/or stress under cyclic loading with many (thousands to millions) cycles and relatively small amplitudes. A high-cycle constitutive model is used for this purpose. Its formulas are based on numerous cyclic tests. This paper describes drained tests with triaxial compression and uniaxial stress cycles. The influence of the strain amplitude, the average stress, the density, the cyclic preloading history and the grain size distribution on the direction and the intensity of strain accumulation is discussed.     

Scalar Similarity for Relaxed Eddy Accumulation Methods

The relaxed eddy accumulation (REA) method allows the measurement of trace gas fluxes when no fast sensors are available for eddy covariance measurements. The flux parameterisation used in REA is based on the assumption of scalar similarity, i.e., similarity of the turbulent exchange of two scalar quantities. In this study changes in scalar similarity between carbon dioxide, sonic temperature and water vapour were assessed using scalar correlation coefficients and spectral analysis. The influence on REA measurements was assessed by simulation. The evaluation is based on observations over grassland, irrigated cotton plantation and spruce forest.Scalar similarity between carbon dioxide, sonic temperature and water vapour showed a distinct diurnal pattern and change within the day. Poor scalar similarity was found to be linked to dissimilarities in the energy contained in the low frequency part of the turbulent spectra ( < 0.01 Hz).The simulations of REA showed significant change in b-factors throughout the diurnal course. The b-factor is part of the REA parameterisation scheme and describes a relation between the concentration difference and the vertical flux of a trace gas. The diurnal course of b-factors for carbon dioxide, sonic temperature and water vapour matched well. Relative flux errors induced in REA by varying scalar similarity were generally below ± 10%. Systematic underestimation of the flux of up to − 40% was found for the use of REA applying a hyperbolic deadband (HREA). This underestimation was related to poor scalar similarity between the scalar of interest and the scalar used as proxy for the deadband definition.     

莺歌海盆地乐东地区石英裂隙内流体包裹体特征及其对天然气成藏制约

莺歌海盆地乐东地区是我国典型高温超压天然气勘探领域,其关键储层黄流组砂岩以天然气富含CO₂为特征,对其中石英颗粒内裂隙包裹体的研究能为CO₂来源和天然气成藏信息提供重要线索。本文通过对黄流组砂岩石英颗粒内包裹体进行岩相学、显微测温与激光拉曼分析,结果表明黄流组砂岩石英颗粒内正常捕获流体包裹体均一温度主要分布在155~165益与170~180益两个温度区间,流体包裹体成分为CO₂（气）和H₂O（液）两种或CO₂（气）和CO₂（液）、H₂O（液）三种。这些特征表明乐东地区黄流组至少经历两期富含CO₂的热液活动,记录了埋藏晚期无机CO₂在火山活动或深大断裂发育期充注成藏的信息。     

楚雄龙岗地区超级不整合与金成矿

龙岗地区陇川运动-华力西运动间造成整个古生代地层缺失，中上三叠统直接覆于下元古界哀牢山岩群、大红山岩群等基底岩系之上，本文称为“超级不整合”。华力西期-喜马拉雅期历次地壳事件在“超级不整合”接触带形成“矿质”的“浪淘砂”式、叠次‘堆积’作用，对该区金成矿有决定性作用，先后发现小水井与大龙潭两个典型金矿床。前者为“地下水热卤水溶滤中低温热液蚀变角砾岩微粒浸染型金矿床”，可类比为“卡林型”；后者为“原生沉积地下热水溶滤中低温热液蚀变砂砾岩微粒-粗粒型金矿床”，为该区首次发现的新类型。     

Sedimentary Phosphorus Form Distribution and Cycling in the Littoral Subzones of a Eutrophic Lake

Algae which bloom in open water and accumulate in the littoral zones may affect the biogeochemical cycle of phosphorus in eutrophic lakes. To determine such effects, a part of the lakeshore with little allochthonous nutrient input in Taihu Lake, China was selected for this field study. Distinct differences in sedimentary P forms were found among the different littoral subzones. The surface sedimentary total phosphorus (TP) content was 655 mg/kg in the eulittoral subzone and 631 to 641 mg/kg in the infralittoral subzone. Both were much higher than that in the profundal zone (410 mg/kg). Calcium‐bound P (Ca‐P) was significantly correlated to exchangeable P (Ex‐P), and they both had the highest contents in the infralittoral subzone and the lowest in the profundal zone. The aluminum‐ and iron‐bound P (Al‐P, Fe‐P) contents decreased from land to water along the ecotone section. Lower Fe/P ratios and higher Al‐P/Fe‐P ratios appeared in the infralittoral subzone, as compared with the profundal zone. This suggested that the accumulated algae could lead to a great deposit of P in the littoral zones. However, the active sedimentary P form transformation in the littoral zones would also result in a partial release of the accumulated P to the overlying water.     

江苏东海地区石英脉地质特征及找矿方向

区域变质作用、韧性剪切作用和超高压变质作用为SiO2富集创造条件,印支期-燕山期的构造活动为石英脉富集定位创造构造环境。东海群地层、韧性剪切带、超高压变质带为石英脉的形成提供了SiO2物质来源。     

Bioconcentration of selected endocrine disrupting compounds in the Mediterranean mussel, Mytilus galloprovincialis

The occurrence of three endocrine disrupting compounds, 4-n-nonylphenol, triclosan and bisphenol A, was investigated in different bivalves originating from the Aegean Sea (Greece). The bioconcentration potential of these compounds was studied using the Mediterranean mussel (Mytilus galloprovincialis). Tissue samples were extracted by sonication. Analysis was performed by gas chromatography-mass spectrometry. According to the field survey results, the average concentrations of 4-n-nonylphenol, triclosan and bisphenol A, were 158, 461 and 404 ng g⁻¹ (dry weight), respectively. During 28 days of exposure at 300 ng L⁻¹, the tissue concentrations of compounds were constantly increased. Steady state was not observed up to the end of the experiment. Kinetic bioconcentration factors varied from 1.7 (4-n-nonylphenol and triclosan) to 4.5 L g⁻¹ (bisphenol A). Following exposure, mussels were relocated to clean water for 28 days. This experiment revealed that depuration rates for all of the target compounds were lower than uptake rates. The biological half-lives of each compound ranged between 12 days (triclosan) and 26 days (bisphenol A).