Vertical distribution and water solubility of phosphorus and heavy metals in sediments of the St. Lucie Estuary, South Florida, USA

Accumulation and distribution of heavy metals and phosphorus in sediments impact water quality. There has been an increasing concern regarding fish health in the St. Lucie Estuary, which is related to increased inputs of nutrients and metals in recent decades. To investigate vertical changes of contaminants (P, Cd, Cr, Co, Cu, Ni, Pb, Zn, and Mn) in sediments of the St. Lucie Estuary in South Florida, 117 layer samples from six of the 210 to 420 cm depth cores were analyzed for their total and water-soluble P and heavy metals, clay, total Fe, Al, K, Ca, Mg, Na, and pH. Principal component analysis (PCA) was used in two sets of analytical data (total and water-soluble contaminant concentrations) to document changes of contaminants in each core of sediments. The PCA of total contaminants and minerals resulted in two factors (principal components). The first and second factors accounted for 61.7 and 17.2 % of the total variation in all variables, and contrast indicators associated with contaminants of P, Cd, Co, Cr, Ni, Pb, Zn, and Mn and accumulation of Fe and Al oxides, respectively. The first factor could be used for overall assessment of P and heavy metal contamination, and was higher in the upper 45–90 cm than the lower depths of each core. The concentrations of P and heavy metals in the surface layers of sediments significantly increased, as compared with those in the sediments deeper than 45–90 cm. The PCA of water-soluble contaminants developed two factors. The second factor (Cu–P) was higher in the upper than the lower depths of the sediment, whereas the highest score of the first factor (Cd–Co–Cr–Ni–Pb–Zn–Mn) occurred below 100 cm. The water-soluble Cu and P concentrations were mainly dependent on their total concentrations in the sediments, whereas the water-soluble Cd, Co, Cr, Ni, Pb, Zn, and Mn concentrations were mainly controlled by pH.     

Horizontal and vertical components of earthquake ground motions at liquefiable sites

Field observations on ground motions from recent earthquakes imply that current knowledge is limited with regard to relating vertical and horizontal motions at liquefiable sites. This paper describes a study with the purpose of clarifying this emerging issue to some extent. A series of numerical analyses is carried out on a liquefiable soil deposit with a verified, fully coupled, nonlinear procedure. It is shown that the transformation of vertical motions in the deposit differs considerably from the transformation of horizontal motions. Both the amplitude and frequency content of the horizontal motions are strongly dependent on the shaking level or the associated nonlinear soil behavior. The transfer function for vertical motions is however likely to be independent of the intensity of input motions; no reduction in the amplitude occurs even in the case of strong shaking. The results are shown to be in consistence with the laboratory observations on shaking table tests and recent field observations that less nonlinearity exists for vertical motions. It is also shown that the possibility exists for using information on spectral ratios between the horizontal and vertical surface motions to quickly identify in situ soil behavior and liquefaction that are not readily covered by conventional field or laboratory experimentation procedures.     

Computational modeling of cyclic mobility and post-liquefaction site response

Under seismic excitation, liquefied clean medium to dense cohesionless soils may regain a high level of shear resistance at large shear strain excursions. This pattern of response, known as a form of cyclic mobility, has been documented by a large body of laboratory sample tests and centrifuge experiments. A plasticity-based constitutive model is developed with emphasis on simulating the cyclic mobility response mechanism and associated pattern of shear strain accumulation. This constitutive model is incorporated into a two-phase (solid–fluid), fully coupled finite element code. Calibration of the constitutive model is described, based on a unique set of laboratory triaxial tests (monotonic and cyclic) and dynamic centrifuge experiments. In this experimental series, Nevada sand at a relative density of about 40% is employed. The calibration effort focused on reproducing the salient characteristics of dynamic site response as dictated by the cyclic mobility mechanism. Finally, using the calibrated model, a numerical simulation is conducted to highlight the effect of excitation frequency content on post-liquefaction ground deformations.     

Spatial variation of seismic motion induced by propagation of body waves

Spatial variation of earthquake ground motion is an important phenomenon that cannot be ignored in the design and safety of strategic structures. Several models have been developed to describe this variation using statistical, mathematical or physical approaches. The latter approach is not specific to an event. A recent contribution, which uses such an approach and called complete stochastic deamplification approach (CSDA), was developed [1]. The aim of this paper is to analyze the spatial variation of earthquake motion induced by the propagation of body waves using the CSDA. Coherency functions are evaluated for the cases of SH–SV–P waves propagating through stratified soil. Results obtained show that the variation of the coherency function is not the same for vertical and horizontal components and that the motion is more coherent at depth than at the free surface. In fact, we found that the rate of decrease with frequency and distance is not the same if P–SV waves propagate through stratified soil.     

Distribution of vertical crustal movement rates in the Tohoku district, Japan, predicted by least-squares collocation

Least-squares prediction using an empirically deduced local covariance function was performed to investigate the temporal change in the rates of vertical crustal movements in the Tohoku district, Japan. Levelling data covering an area of approximately 450 × 275 km² observed between 1966 and 1995 were used and the results shown in the form of contour maps. Firstly we derived a covariance function of the rates of vertical crustal movement with a Gaussian form function. We used this function to estimate the spatial distribution of the rates of vertical crustal movements. By the present method, a steady tilt of the Tohoku district to the east, toward the Japan Trench and an areal uplift in the southwestern part were well reproduced. Moreover, a significant temporal change in vertical movement rates is clearly seen. Received: 15 July 1996      

The role of diapycnal mixing for the equilibrium response of thermohaline circulation

Using a zonally averaged, one-hemispheric numerical model of the thermohaline circulation, the dependence of the overturning strength on the surface equator-to-pole density difference is investigated. It is found that the qualitative behavior of the thermohaline circulation depends crucially on the nature of the small-scale vertical mixing in the interior of the ocean. Two different representations of this process are considered: constant vertical diffusivity and the case where the rate of mixing energy supply is taken to be a fixed quantity, implying that the vertical diffusivity decreases with increasing stability of the water column. When the stability-dependent diffusivity parameterization is applied, a weaker density difference is associated with a stronger circulation, contrary to the results for a fixed diffusivity. A counterintuitive consequence of the stability-dependent mixing is that the poleward atmospheric freshwater flux, which acts to reduce the thermally imposed density contrast, strengthens the thermally dominated circulation and its attendant poleward heat transport. However, for a critical value of the freshwater forcing, the thermally dominated branch of steady states becomes unstable, and is succeeded by strongly time-dependent states that oscillate between phases of forward and partly reversed circulation. When a constant vertical diffusivity is employed, on the other hand, the thermally dominated circulation is replaced by a steady salinity-dominated state with reversed flow. Thus in this model, the features of the vertical mixing are essential for the steady-state response to freshwater forcing as well as for the character of flow that is attained when the thermally dominated circulation becomes unstable.Responsible Editor: Jin-Song von Storch     

Slab behaviour and its surface expression: new insights from gravity modelling in the SE-Carpathians

We use lithosphere-scale gravity models to calculate gravity anomalies resulting from oceanic subduction, continental collision, slab steepening, delamination, and break-off. Local isostasy was assumed for determining vertical movements caused by mass changes related to these tectonic processes. Our results show that subduction is accompanied by basin subsidence on the upper plate caused by the heavy lithospheric root of the subducting slab. The basin evolution goes parallel with the slab evolution and shows considerable modifications when the processes at depth change (slab steepening, delamination, break-off). Characteristic gravity anomaly curves were acquired for the different tectonic scenarios. These curves together with other data (e.g. basin evolution on the upper and the lower plate) were used for the reconstruction of the tectonic evolution of the SE-Carpathians which includes Tertiary subduction and collision followed by slab steepening and delamination.     

反向VSP透射层析成像法在岩墙松动层检测中的应用

通过实例介绍了反向VSP透射层析成像方法的基本原理、数据采集和资料处理方法。利用该方法在检测岩墙松动层厚度中取得了很好的勘探效果。     

三维变分同化雷达资料暴雨个例试验

采用中国新一代数值预报模式及其同化系统开展雷达资料的三维变分同化和数值模拟研究.通过一次暴雨个例的对比试验,结果表明:不考虑垂直运动影响的情况下,仅同化多普勒雷达径向风资料可以增加初始场中的中小尺度系统信息,并在一定程度上改善预报开始阶段的降水;同化由反射率因子导出的垂直速度、雨水混合比并令上升区饱和,可以较大改善降水预报结果;联合同化径向速度和反射率因子资料将得到它们的共同影响.模拟的β中尺度对流系统6 h的演变过程与观测十分一致,基本消除了旋转加强现象.发展旺盛阶段的对流单体南北方向范围约50 km,最大上升速度位于500 hPa附近,超过3.0 m/s;雨水最大含量在400 hPa附近,超过5.0 g/kg;云水最大值位于600 hPa,约0.5 g/kg;造成的降水强度可达30 mm/h,具有明显的β中尺度系统的特征.初始场中水汽是否达到β中尺度降水维持所需条件是至关重要的,如果初始场中水汽条件较差,即使含有云水、雨水、垂直速度的信息,这些信息也会很快消亡,难以维持下去;此外,雷达资料的质量控制也是十分重要的.     

地面资料在侦测暴雨天气过程中的应用

利用地面常规观测资料和自动站加密温度资料以及卫星云图资料,分析了2005年7月6—7日和7月9—10日发生在江淮流域及其附近的两次暴雨过程的地面要素分布特征,发现强降水带分布在非锋性斜压带和斜压槽附近。然后利用NCEP再分析资料,用第二类热成风螺旋度和非地转湿矢量诊断解释了非锋性斜压带和斜压槽产生强降水的动力机制,结果表明在地面非锋性斜压带和斜压槽处易发生锋生和斜压现象,从而诱发强降水。