Biogeochemical investigation in south eastern Andhra Pradesh: the distribution of rare earths, thorium and uranium in plants and soils

The concentration of rare earth elements (REE), thorium and uranium were determined by inductively coupled plasma mass spectrometry (ICP−MS) in the plant species, Pterocarpus santalinus, P. marsupium and P. dalbergioides, and the soils on which they were growing. Higher concentrations of lanthanum (La), cerium (Ce) were observed in both plants and soils. Large amounts of thorium and uranium were found in the soil. In all tree species, the concentration of REEs were higher in the heartwood than the leaves. The heartwood of P. santalinus accumulated larger quantities of uranium (average concentration of 1.22 ppm) and thorium (mean value of 2.57 ppm) than the other two species. Received: 8 September 1999 · Accepted: 15 December 1999     

Correlations between heavy metals and organic carbon extracted by dry oxidation procedure in urban roadside soils

The organic fraction in soils has a significant influence on heavy metal transport. In this study, the organic carbon content was measured by dry oxidation procedure from 21 Xuzhou urban roadside soils to assess the relationships between the concentrations of heavy metals (Pb, Cu, Zn, and Cr) and the amount of organic carbon. The anthropogenic heavy metals (e.g. Pb, Cu, Zn) were strongly correlated with organic carbon (denoted by C_org−c) extracted by dry oxidation while natural heavy metal (e.g. Cr) showed no correlation to the C_org−c. The anthropogenic heavy metals were also strongly correlated with the amount of the total carbon. These results show that the anthropogenic heavy metals are mainly enriched in the organic matter in the Xuzhou urban roadside soils.     

云南武定荒箐铁铜多金属矿矿床成因

矿床产于断层破碎带中,受断层和地层层位控制,与迤纳厂矿床具有一定的相似性。铁矿为中低温热液裂隙充填型脉状矿床,而铜矿床应为沉积——变质型。     

Anthropogenic influence on trace element geochemistry of healing mud (peloid) from Makirina Cove (Croatia)

Due to their balneotherapeutic features, the organic-rich sediments in Makirina Cove are an important source of healing mud. An environmental geochemistry approach using normalization techniques was applied to evaluate the anthropogenic contribution of trace metals to sediments used as healing mud. Sediment geochemistry was found to be associated with land-use change and storm events, as well as with proximity of a road with heavy traffic in the summer months. Local valley topography preferentially channels lithogenic and pollutant transport to the cove. Concentrations and distribution of trace metals indicate lithogenic (Ni, Cr, Co) and anthropogenic (Pb, Cu, Zn and Se) contributions to the sediments. The calculation of enrichment factors indicates a moderate (EFs between 2–3.5) input of anthropogenic Cu and Pb in surficial sediments to a depth of 10 cm. Patients using the Makirina Cove sediments as healing mud could be to some extent exposed to enhanced uptake of metals from anthropogenic sources via dermal contact.     

Diagnosis of trace metal contamination in sediments: the example of Ensenada and El Sauzal, two harbors in Baja California, Mexico

Total metal concentrations in sediments from within Ensenada and El Sauzal Harbors are generally higher than at the mouths. Grain-size analyses suggested that this enrichment could be due to the presence of fine-grained sediments in the inner part of the harbors rather than to anthropogenic perturbations. The (Me/Al)(sample) ratios for Pb, Co, Ni and Fe were significantly higher for Ensenada Harbor relative to El Sauzal Harbor, whereas the ratios for Cd, Mn, Zn and Cu were statistically equivalent for both harbors. Calculated enrichment factors [EF(Me)=(Me/Al)(sample)/(Me/Al)(shale)] indicated that the metals showing slight enrichment were those associated with anthropogenic contamination (Pb, Zn), or probably related to primary productivity in the water column (Cd, Co). The levels of most of the metals were not greatly enriched, a consideration that is of the utmost importance when contamination issues are at stake.     

波浪底摩擦力对重砂富集的影响——以鲁南近岸区为例

根据浅水波浪的底摩擦效应，对鲁南灵山湾和臼－岚山镇近岸区进行了波浪的海底摩擦力计算。波浪的海底摩擦力等值图与已知滨海锆石砂矿资料对比表明，底摩擦力大于０．１８Ｎ／ｍ＾２的动力分选区有利于重矿物砂富集。据此，进一步预测了鲁南近岸带的砂矿富集区。     

Comparison of magnetic parameters with vehicular Br levels in urban roadside soils

Chemical methods are generally chosen to monitor soil pollution but magnetic measurements proved to yield additional information at low cost and less time consumption. In this investigation, the novel use of rapid and non-destructive magnetic measurements to characterize Br levels in Xuzhou (China) urban roadside soils was reported. X-ray fluorescence spectrometry (XRF) was used to quantify Br in the soil samples. Data from 21 roadside soil samples confirm Br contamination, with a mean level of 4.36 mg kg⁻¹ and a range of 2.4–8.7 mg kg⁻¹. These values are higher than that of unpolluted soils in Xuzhou that averages 1.1 mg kg⁻¹. Hierarchical clustering analysis shows Br in Xuzhou roadside soils is mainly from road traffic. Clear correlations between Br levels and simple magnetic parameters [mass specific susceptibility (χ _LF), susceptibility of anhysteretic remanent magnetization (χ _ARM), saturation isothermal remanence (SIRM)] are observed. The present study shows that these three magnetic parameters can be used as a proxy for Br levels in Xuzhou urban roadside soils.     

永平水泄铜钴矿控矿因素

水泄铜钴矿区地质条件较为复杂,控矿因素较多,通过分析认为主要受断层及岩性控制,地层初始富集,构造及区域变质作用提供通道及热源。水的循环、溶解作用形成热卤水成矿。     

银额盆地巴隆乌拉白垩系巴音戈壁组黑色页岩沉积环境及有机质富集模式

银额盆地早白垩世沉积的巴音戈壁组湖相页岩是一套重要的烃源岩。通过对巴隆乌拉剖面黑色页岩进行地球化学分析,研究其主量、微量和稀土元素特征,以及黑色页岩沉积的古环境及有机质富集模式。结果表明,Sr/Ba值为0.14~0.24,平均值为0.18,B/Ga值为3.89~6.51,平均值为5.03,相当B含量为230.88×10-6~375.99×10-6,平均值为294.95×10-6,古盐度为11.97‰~15.83‰,平均值为14.70‰;V/(V+Ni)值为0.67~0.84,平均值为0.74,Ceanom值为-0.113~0.018,平均值为-0.055;古气候指数(C)为0.80~1.34,平均值为1.06,化学蚀变指数(CIA)为75~81,平均值为79;古水深为4.16~88.04 m,平均值为33.40 m;P/Ti值为0.10~0.22,平均值为0.15,过剩钡(BaXS)为-46.5×10-6~144.5×10-6,平均值为38.85×10-6。综合各参数特征,研究区黑色页岩沉积于温暖、湿润、半咸水、缺氧的还原环境,沉积水体较深,具有低的古生产力条件。有机碳含量与沉积环境间相关性的研究表明,巴音戈壁组黑色页岩有机质富集是古盐度、氧化-还原条件、古气候、古生产力等因素共同作用的结果。研究结果可为银额盆地中生界沉积演化和油气资源评价提供理论支撑。     

云南三江口地区超基性岩岩石化学及成因

三江口地区超基性岩按岩石类型可分六种,岩石的m/f值小于6 5,属铁质超基性岩,呈包体状产于下二叠统木星土岩组(P1mx.)及上二叠统洛吉组(P2lj)中,与其为同源异相产物,形成于板块裂陷环境。岩浆活动时期大致为晚古生代 早三叠世早期,可能代表古特提斯形成的早期阶段。成果为进一步研究和恢复该区古构造格局提供重要依据。