含硫化物镁铁质-超镁铁质侵入体中橄榄石Mg、Ni含量的制约:原理、模式及Voisey's Bay侵入体样品研究

镁铁质-超镁铁质岩浆结晶分离早期形成镁铁矿物,镁铁矿物中的Ni和Mg是相容元素。随着结晶分离作用的进行,Ni、Mg在硅酸盐岩浆及后形成的硅酸盐物质中的丰度下降。橄榄石中Ni含量及硅酸盐物质MgO/FeO比值都与母岩浆的相关值相关,据此可推断母岩浆的信息,它们之间可由实验测得的系数相联系。当岩浆饱和硫化物时,在结晶分离过程中硫化物珠滴会与镁铁硅酸盐物质一道析出,同时,与硫化物非饱和岩浆相比,过多的Ni会随之析出。这也反映在Ni、Mg含量比无硫化物分离时有更迅速的降低上。Ni、Mg含量变化值可以在VoiseysBay侵入体的模式曲线上反映出,加拿大Labrador的这一侵入体赋存了一个世界级的Ni-Cu-Co硫化物矿床。过去的作法是将侵入体中橄榄石的Ni、Mg含量与Simkin和Smith得出的各种火成岩中橄榄石的Ni、Mg含量相比较以确定Ni亏损,进而假定橄榄石来自硫化物饱和、有经济价值的岩浆。现在的研究显示这种简单的对比会导致错误。将样品数据与模式曲线对比并反映出侵入体矿物结晶堆积特征是重要的方法。使用这一方法,样品数据能很好地被模式曲线拟合。以在VoiseysBay的研究为例,当硫化物液相与硅酸盐矿物被去除后,硫化物非饱和的分离作用期就会显现出来,随后是硅酸盐结晶作用期。     

小体积萃取-石墨炉原子吸收法测定高纯硝酸钡中纳克级重金属元素

本文研究了石墨炉原子吸收光谱法测定高纯硝酸钡中超痕量重金属元素的分析技术。提出在大量钡基体存在时,采用小体积萃取体系APDC-MIBK同时萃取纳克级的Fe、Cu、Co和Ni。该法具有灵敏度高、无干扰、操作方便和减少沾污等特点。方法检出限为:Fe 7.2ng/g、Cu 12.8ng/g、Co 4.4ng/g和Ni 6.7ng/g。应用于红外光纤原料硝酸钡、硝酸铝中痕量重金属的测定,效果良好。     

Li_2O-(Mg、Zn、Ni)O-V_2O_5三元体系的相平衡

对Li_2O-(Mg、Zn、Ni)O-V_2O_5三元体系在500—800℃相图的研究表明,在每个系统内部都出现了一个依端员组分摩尔比为1:2:1的化合物。即橄榄石型的LiMgVO_4,硅铍石型的LiZnVO_4和尖晶石型的LiNiVO_4。不同的是,Li_2O-MgO-V_2O_5中发现了第二个三元相和一个固溶体。LiO_2-NiO-V_2O_6中得出一个固溶体,而LiZnNO_4中未得固溶体。     

The 2020/21 Extremely Cold Winter in China Influenced by the Synergistic Effect of La Niña and Warm Arctic

In the first half of winter 2020/21,China has experienced an extremely cold period across both northern and southern regions,with record-breaking low temperatures set in many stations of China.Meanwhile,a moderate La Ni?a event which exceeded both oceanic and atmospheric thresholds began in August 2020 and in a few months developed into its mature phase,just prior to the 2020/21 winter.In this report,the mid?high-latitude large-scale atmospheric circulation anomalies in the Northern Hemisphere,which were forced by the negative phase of Arctic Oscillation,a strengthened Siberian High,an intensified Ural High and a deepened East Asian Trough,are considered to be the direct reason for the frequent cold surges in winter 2020/21.At the same time,the synergistic effect of the warm Arctic and the cold tropical Pacific(La Ni?a)provided an indispensable background,at a hemispheric scale,to intensify the atmospheric circulation anomalies in middle-to-high latitudes.In the end,a most recent La Ni?a prediction is provided and the on-coming evolution of climate is discussed for the remaining part of the 2020/21 winter for the purpose of future decision-making and early warning.     

IMPACT OF LATENT HEAT FLUX ON INDIAN SUMMER MONSOON DURING EL NI(N)O/LA NI(N)A YEARS

El Ni(n)o or La Ni(n)a manifest in December over the Pacific and will serve as an index for the forecasting of subsequent Indian summer monsoon,which occurs from June to mid-September.In the present article,an attempt is made to study the variation of latent heat flux (LHF) over the north Indian Ocean during strong El Ni(n)o and strong La Ni(n)a and relate it with Indian monsoon rainfall.During strong El Ni(n)o the LHF intensity is higher and associated with higher wind speed and lower cloud amount.During E1 Ni(n)o all India rainfall is having an inverse relation with LHF.Seasonal rainfall is higher in YY+1 (subsequent year) than YY (year of occurrence).However there is a lag in rainfall during El Ni(n)o YY+1 from June to July when compared with the monthly rainfall.     

Perturbed solution of sea-air oscillator for the E1 Ni(n)o/La Ni(n)a-Southern Oscillation mechanism

A class of coupled system of the E1 Ni(n)o/La Ni(n)a-Southern Oscillation (ENSO) mechanism is studied. Using the perturbed theory, the asymptotic expansions of the solution for ENSO model are obtained and the asymptotic behavior of solution for corresponding problem is considered.     

缅甸莫苇塘红土型镍矿矿物学特征

莫苇塘红土型镍矿分为土状矿和岩状矿,矿物成分基本相同,但量上有差异。矿石主要由蛇纹石类硅酸盐矿物和褐铁矿、赤铁矿等氧化物、氢氧化物矿物组成,有用组份镍主要赋存于硅酸盐类矿物和氧化物、氢氧化物类矿物中。     

中条山西南段与变基性岩有关的铜矿地质特征及成因浅析

与变基性岩有关的铜矿 ,是在中条山西南段新发现的一种新的铜矿类型 ,其形成是在原始基性岩浆侵入或喷发作用形成的矿源岩或矿化体基础上 ,经过区域变质和印支 -燕山期构造 -岩浆热液的改造加富而成 ,其成因应属与变基性岩有关的变质 -热液改造型铜 (镍、铁 )矿床。     

干旱区绿洲土壤共存重金属元素形态变化及生物有效性实验分析——以Cd、Zn、Ni元素为例

采用盆栽试验,初步研究了干旱区绿洲土壤—胡萝卜系统中镉、锌、镍3种重金属的形态变化特征及其生物有效性问题。结果表明:供试绿洲土壤原状土中,Cd、Zn、Ni均以稳定的残渣态形式存在,而处理土壤中重金属被钝化的量有限,Cd的存在形式主要以碳酸盐态为主,Zn、Ni则主要以铁锰氧化态为主;3种元素的活性大小依次为Cd>Ni>Zn。根据回归分析,元素Zn对胡萝卜块茎和茎叶吸收Zn量贡献最大的分别是Zn的碳酸盐结合态和铁锰氧化态;元素Ni对胡萝卜各部位吸收贡献最大的均为Ni的铁锰氧化态。     

一个重构的153年热带太平洋次表层上卷海温资料

次表层上卷海温对改进ENSO(厄尔尼诺-南方涛动,El Ni o-Southern Oscillation)模拟水平及ENSO年代际变化均具有重要作用。利用一个中等复杂程度耦合模式(intermediate coupled model,简称ICM)和Nudging(张弛逼近)同化方法,重构了1856—2008年间热带太平洋地区的次表层上卷海温。统计检验表明,重构的次表层上卷海温与近50年的3种分析资料间具有较高的相关性和较小的均方根误差。此外,通过此重构的次表层上卷海温资料重新驱动ICM模式,模拟得到的海表温度距平(sea surface temperature anomaly,简称SSTA)可以真实地反映出ENSO的年际和年代际变化,表明此重构的次表层上卷海温资料可用于气候研究,特别是用于ENSO的大尺度低频变化或年代际气候变化研究。