Synergistic effect of F and triggered oxygen vacancies over F-TiO2 on enhancing NO ozonation

Oxidation-absorption technology is a key step for NO_x removal from low-temperature gas. Under the condition of low O₃ concentration (O₃/NO molar ratio = 0.6), F-TiO₂ (F-TiO₂), which is cheap and environmentally friendly, has been prepared as ozonation catalysts for NO oxidation. Catalytic activity tests performed at 120°C showed that the NO oxidation efficiency of F-TiO₂ samples was higher than that of TiO₂ (about 43.7%), and the NO oxidation efficiency of F-TiO₂-0.15 was the highest, which was 65.3%. Combined with physicochemical characteristics of catalysts and the analysis of active species, it was found that there was a synergistic effect between F sites and oxygen vacancies on F-TiO₂, which could accelerate the transformation of monomolecular O₃ into multi-molecule singlet oxygen (¹O₂), thus promoting the selective oxidation of NO to NO₂. The oxidation reaction of NO on F-TiO₂-0.15 follows the Eley-Rideal mechanism, that is, gaseous NO reacts with adsorbed O₃ and finally form NO₂.     

In vitro characteristics of human fetal cells obtained from chorionic villus sampling and amniocentesis

In vitro characteristics of human fetal cells have been investigated after chorionic villus sampling at the first trimester and amniocentesis at the second trimester of pregnancy. Light microscopy revealed heterogeneous morphology of cell types in both the chorionic villus culture and the amniotic fluid cultures. Based on the experiments performed, chorionic villus cells are more sensitive to pronase, trypsin, and versene during subculture and have a higher DNA content per single cell and release more [¹²⁵I]-Beta-human chorionic gonadotropin into culture medium than those found in amniotic fluid cells. The practical applications of this study are discussed.     

浅谈混凝沉淀在炼油污水中的应用

随着国家对环保的重视，为确保处理效果，混凝沉淀技术在一些炼油污水中得到应用，并取得了较好的效果。     

Carbon isotope ratios in logged and unlogged boreal forests: Examination of the potential for determining wildlife habitat use

Due to assimilation of recycled CO₂ from litter decomposition and photosynthetic changes in carbon fractionation at low light levels, the foliage at the base of a forest is often more depleted in¹³C compared to that exposed to the atmosphere in either the canopy or in open clearings. This is referred to as the canopy effect. African research has indicated that these habitat differences in foliar ¹³C can be substantial enough to affect the carbon isotope ratios of resident fauna. Previous work documenting a 30-year chronology on moose teeth from Isle Royale National Park indicated a progressive depletion in¹³C and suggested that this could be due to forest regrowth following extensive burning. The present study examined the assumption implicit in this hypothesis that foliar ¹³C varies between open and closed boreal forest sites. I found a marginal canopy effect of 2 ¹³C difference between upper canopy and ground flora for a forest in northwestern Ontario and an average difference of 1.2 in under- and mid-story vegetation between closed forests and open clear-cuts. Because of these small differences, the utility of carbon isotope analysis in quantifying temporally integrated exploitation of deforested habitats will be low for northern boreal locations. In denser forests, such as those in the tropics or western North American where the canopy effect can be expected to be much greater, ¹³C analysis may still offer some promise for determining selection by wildlife of disturbed habitats.     

Enzymatic degradation of poly([R,S] β-hydroxybutyrate)

The synthetic analogue of a bacterially produced polyester, poly(-hydroxybutyrate) (PHB) was synthesized from racemic -butyrolactone using anin situ trimethyl aluminum-water catalyst. The polymer was fractionated into samples differing in molecular weight and isotactic diad content. The latter was closely related to degree of crystallinity. The biodegradation of these fractions were examined by monitoring mass loss over time in the presence of anAlcaligenes faecalis T1 extracellular bacterial poly(-hydroxybutyrate) depolymerase. The fraction with high isotactic diad tacticity content showed little or no degradation over a 50 hour incubation period, whereas the fraction of intermediate isotactic diad content degraded in a continuous steady fashion at a rate that was less than that for bacterial PHB. The low isotactic diad fraction underwent a rapid initial degradation, followed by no further mass loss. The presence of stereoblocks in the polymer structure of the various fractions was an influence on the degree of susceptibility towards degradation and is related to sample crystallinity.     

池州悬钩子的食用价值与茶多酚含量研究

研究了池州市悬钩子属植物的食用价值与其中茶多酚(TP)的含量,目的是为了综合利用悬钩子属植物,促进其全面开发,提高经济效益.用正交实验法确定了提取TP的最佳实验条件,用分光光度法测定其含量.从分析结果看,悬钩子属植物中含有一定量的TP.因此,在开发悬钩子属植物果实作为第三代水果资源时,从其茎叶中提取TP具有一定的经济价值,这对促进悬钩子资源的开发与利用是很有意义的.     

内蒙古典型草原土壤的氟含量

对内蒙古草原区典型草原不同区域内土壤氟水平及分布规律进行了研究。结果表明，典型草原土壤氟含量从东到西呈上升趋势，典型草原土壤表层氟含量平均值为２８５．４６ｍｇ／ｋｇ，与国内外有关文献值相比属中等水平，处于内蒙古土壤表层氟背景值范围内。     

污水低氧脱氮机制及其应用研究进展

阐述了污水低氧脱氮的基本原理,即抑制或去除亚硝酸盐氧化菌(NOB),同时保留氨氧化菌(AOB),并保持其活性;探讨了污水低氧脱氮实现途径;详细介绍了几种典型的污水低氧脱氮工艺(短程硝化(SHARON)工艺、厌氧氨氧化(ANAMMOX)工艺、好氧反氨化(DEMON)工艺、低氧自养硝化反硝化(OLAND)工艺、甲烷营养型硝化反硝化工艺和亚硝酸盐型完全自养脱氮(CANNON)工艺)的应用研究进展;最后对污水低氧脱氮处理工艺的工程运用进行了展望.     

Johnson & Ettinger模型和Volasoil模型在污染物室内挥发风险评价中的应用和比较

在土壤污染和地下水污染的现场,挥发过程是挥发性污染物暴露的重要途径.设置典型土壤污染场景作为研究对象,选取Johnson&Ettinger模型和Volasoil模型进行室内挥发过程的模拟和暴露浓度的计算.对两个模型中污染物的运移机理进行了比较和分析.尽管方法和参数选择有所不同,二者对污染源处三相平衡浓度的计算本质上是一致的.暴露浓度的计算结果表明,两个模型对室内挥发过程的模拟可能会有较大差异,与污染现场的具体情况有关.参数影响的分析表明,污染源顶部埋深对二者暴露浓度的影响一致,Johnson&Ettinger模型对污染土壤含水率的大小非常敏感.建议考虑房屋结构的实际情况,选用或者改进模型进行室内挥发过程的评价.