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1.
Ti wire electrodes were immersed in acidic solutions containing H2SO4 and HCl of various concentrations at 353 K to evaluate corrosion rate by measurement of electric resistance change (resistometry). Addition of hydrochloric acid to sulphuric acid solution promoted depassivation of Ti. After depassivation, the immersion potential dropped to the hydrogen evolution potential and a hydride layer was formed on the surface. The hydride layer dissolved continuously in the acidic solution. SEM observation showed that Ti wires dissolved almost uniformly in the early stage and that the dissolution then trace became irregular due to nonuniform growth of the hydride layer. Dissolution rate of a Ti wire was estimated almost accurately by resistometry. 相似文献
2.
Yoichi Shindo Naoya Katagiri Toichi Ebisuno Masatoshi Hasegawa Miyuki Mitsuda 《大分子材料与工程》1996,240(1):231-239
Poly (vinyl alcohol) with pendent styrylpyridinium groups (SbQ) is insolubilized by photoirradiation. An association takes place in SbQ groups. The association of polymer chains becomes marked with increasing the number of SbQ groups. Mainly intermolecular crosslinks were formed. Transparent and homogeneous macrogels consisting of several intermolecular crosslinks are obtained. The proportion of the free water to the bound water in PVA-SbQ gels was 3.3?2.9 despite of the large change in conversion of photodimerization of SbQ groups, x=0.27?0.58. The water uptake after swelling of the gels in water increased 6–27 times compared to the original weight at pH=7. The higher the degree of photocrosslinking, the lower was the degree of swelling. The water diffusion coefficients, D, were (2.2?5.8) × 10?5 cm2 S?1 for a 88% saponified PVA with 1 . 3 mol% SbQ groups. The volume of the gel increased discontinuously about 10-fold for the 99% saponified PVA with 0 . 096 mol% SbQ and 51% water (49% acetone). The acetone concentration at the transition decreased with increasing the degree of saponification of the PVA. 相似文献
3.
The pre-treatment of a silica-supported gallium oxide catalyst with H2 at 823 K increased the yield of aromatics and the selectivity to aromatics in the dehydrogenation of propane over the catalyst at 823 K. Gallium oxide in the catalyst was partially reduced with H2 at 823 K. NH3 desorption and DRIFTS studies on the gallium oxide catalyst suggest that the dehydrogenation of propane over a silica-supported gallium oxide catalyst would proceed in the following way: (1) the dehydrogenation of propane to produce propene would occur on Ga sites including Gaδ+–H sites and (2) the aromatization of propene to aromatics on Ga–O–H acid sites. 相似文献
4.
The synthesis of super-microporous aluminosilicate with a pore diameter of 14.6 Å has been achieved, by means of synthesis under specified conditions with a skeletal material comprising TMOS and a small quantity of sodium aluminate, and a conventional alkyl-trimethylammonium halide (C10TMABr) as a template. This super-microporous aluminosilicate has an adsorption capacity of 0.2 ml/g at a relative water vapor pressure of 0.2, and thus is promising as an adsorbent for an adsorption heat-pump. 相似文献
5.
Tsunehiro Aki Kazutaka Hachida Megumi Yoshinaga Yuko Katai Takashi Yamasaki Seiji Kawamoto Toshihide Kakizono Takashi Maoka Seiko Shigeta Osamu Suzuki Kazuhisa Ono 《Journal of the American Oil Chemists' Society》2003,80(8):789-794
Thraustochytrids, marine protists whose dominant genera are Thraustochytrium and Schizochytrium, belong to the kingdom Chromista and are known as an industrial source of DHA. We describe here that thraustochytrid strain
KH105, isolated as a DHA producer, also accumulates significant levels of β-carotene and xanthophylls including canthaxanthin
and astaxanthin. A4-d cultivation using a medium composed of 10% glucose and less than 0.3% of nitrogen sources in a half-concentration
of seawater gave an astaxanthin production up to 6.1 mg/L, and canthaxanthin content reached more than 10 mg/L under conditions
where a higher concentration of nitrogen sources (6%) was employed. It might be advantageous in mass production systems for
these carotenoids to be extracted readily by simply suspending the cells with organic solvents such as acetone and chloroform.
Analyses on the morphological and life history features of the KH105 strain revealed that it belongs to the genus Schizochytrium. This particular species of thraustochytrids is thus considered to be a promising source of xanthophylls as well as DHA for
use in the food industry. 相似文献
6.
A DC (data center) demands air-conditioning power as large as the 1/3-1/2 of total electricity consumption. Thus, energy saving of cooling power of DC yields considerable effect on both economic and environmental views. PV (Photovoltaic) and absorption refrigerator with CGS (cogeneration systems) or gas boiler are possible power saving options. The waste warm air from DC would be utilized for greenhouse heating when DC and greenhouse locate near in the suburbs. In this study, the authors develop an energy network model to assess the potential contribution of DC as a major electric power and chilled air consumer as well as the warm air supplier in a district to the energy efficiency improvement. The evaporation heat of LNG (liquefied natural gas) utilization is also considered as well as PV, CGS. This model is applied to the cases of the urban area in Tokyo which involves athletic center, shops and hospital and the suburbs including greenhouse and then compared. 相似文献
7.
8.
Yoshihiko Okada Kaori Sasaki Baiqian Zhong Hideki Ishida Takeshi Mitsuda 《Journal of the American Ceramic Society》1994,77(5):1319-1323
A mixture of CaO and silicic acid prepared with a Ca/Si ratio of 2.0 was hydrothermally synthesized at 80° to 200°C, and the thermal decomposition behavior of the products (C-S-H with Ca(OH)2 ) was analyzed using XRD, 29 Si MAS NMR, and the trimethylsililation method (TMS). It was found that the main silicate anion structure of C-S-H was a mixture of a dimer and a single-chain polymer (larger than Si5 O16 ) and that polymerization advanced with an increase of the synthesizing temperature. On heating, the products decomposed to form β-C2 S. It was found that the decomposition was gradual and that the-higher the temperature of hydrothermal synthesis, the lower was the temperature of the decomposition into β-C2 S. Although the decomposition proceeded to form a monomer (β-C2 S) from the polymer and dimer, this dimer was resistant to heat and did not decompose unless heated to above 400°C. 相似文献
9.
A novel technique to improve the adhesion of a diamond-like carbon (DLC) film to an Al alloy was demonstrated in this study. DLC films were deposited by diode rf bias sputtering. The Al component in the substrate was initially deposited on a graphite target during the sputter-cleaning of the substrate. Then the graphite target and the deposited Al were simultaneously sputtered to form an interface layer between the DLC film and the substrate in the early stage of deposition. We call this method substrate sputtering and redeposition (SSRD), which enhanced the antiwear lifetime of DLC/Al alloy samples. X-ray photoelectron spectroscopy clarified that a thicker mixed layer of Al and C was formed around the interface in the case of a longer substrate sputtering duration in the SSRD method. This interface structure could account for the strong adhesion of the DLC film to the substrate and the reduced delamination of the film obtained using the SSRD method. 相似文献
10.
Munehisa Yasuniwa Shinsuke Tsubakihara Koji Iura Yoshinori Ono Yusuke Dan Kazuhisa Takahashi 《Polymer》2006,47(21):7554-7563
The crystallization behavior of poly(l-lactic acid) was studied in the range of 80-160 °C. The peak crystallization time (τp) was defined and obtained from the crystallization isotherm measured with a differential scanning calorimeter (DSC). Isothermal crystallization temperature (Tc) dependence of log(τp) discretely changed at 113 °C (= Tb). The linear growth rate of spherulite, G, was measured with a polarizing microscope. The Tc dependence of G and the size of the spherulite also discretely changed at Tb. Crystal structures for samples isothermally crystallized at temperatures which were higher and lower than Tb were orthorhombic (α-form) and trigonal (β-form), respectively. The discrete change of the crystallization behavior was explained by the formation of different crystal. 相似文献