全文获取类型
收费全文 | 379757篇 |
免费 | 82073篇 |
国内免费 | 51950篇 |
学科分类
工业技术 | 513780篇 |
出版年
2024年 | 3496篇 |
2023年 | 7437篇 |
2022年 | 10480篇 |
2021年 | 13163篇 |
2020年 | 14065篇 |
2019年 | 22459篇 |
2018年 | 24167篇 |
2017年 | 26124篇 |
2016年 | 25504篇 |
2015年 | 25983篇 |
2014年 | 26893篇 |
2013年 | 28687篇 |
2012年 | 27902篇 |
2011年 | 25904篇 |
2010年 | 22553篇 |
2009年 | 19434篇 |
2008年 | 17163篇 |
2007年 | 16121篇 |
2006年 | 15600篇 |
2005年 | 14193篇 |
2004年 | 13884篇 |
2003年 | 11746篇 |
2002年 | 10976篇 |
2001年 | 9778篇 |
2000年 | 9477篇 |
1999年 | 9873篇 |
1998年 | 9091篇 |
1997年 | 7779篇 |
1996年 | 7245篇 |
1995年 | 6667篇 |
1994年 | 5509篇 |
1993年 | 4736篇 |
1992年 | 4167篇 |
1991年 | 3058篇 |
1990年 | 2460篇 |
1989年 | 2233篇 |
1988年 | 1694篇 |
1987年 | 805篇 |
1986年 | 665篇 |
1985年 | 516篇 |
1984年 | 341篇 |
1983年 | 292篇 |
1982年 | 306篇 |
1981年 | 277篇 |
1980年 | 239篇 |
1978年 | 162篇 |
1976年 | 302篇 |
1975年 | 243篇 |
1972年 | 257篇 |
1960年 | 206篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
通过制备不同晶相结构〔单斜相(m-ZrO_2)、四方相(t-ZrO_2)和无定型(a-ZrO_2)〕ZrO_2载体,再通过沉积沉淀法制得Cu/m-ZrO_2、Cu/t-ZrO_2和Cu/a-ZrO_2催化剂,分别用于催化二乙醇胺脱氢合成亚氨基二乙酸反应。采用XRD、氮气物理吸附脱附、XPS、H_2-TPR、CO_2-TPD对催化剂的结构进行了表征。结果表明,Cu/m-ZrO_2催化剂界面更加有利于Cu~+/Cu~0稳定存在,具有更多的碱性位点,且抗氧化性较好。在二乙醇胺脱氢反应中,Cu/m-ZrO_2催化剂性能最好,反应时间为2.5 h,亚氨基二乙酸收率为97.64%。 相似文献
2.
Prediction of methane adsorption content in continental coal-bearing shale reservoir using SLD model
Shale gas, as an important unconventional resource, has drawn global attention. It is mainly composed of adsorption gas and free gas. Adsorption gas content could play an important guiding role on both the selection of favorable perspective area and the exploration and exploitation of shale gas resources. In order to accurately measure adsorption gas content, a new approach was established to predict the adsorption isotherm of methane on shale. Based on the simplified local-density (SLD) method, both the adsorption isotherms of illite, illite/smectite mixed-layer, cholorite and type III kerogen and the total shale rock could be well fitted. The fitting results show good coincidences with the true experimental test data, which proves the method is reasonable and dependable and the prediction results are effective and credible. In addition, the good simulation results show that the SLD parameters can reflect the pore structure characteristics and corresponding adsorption characteristics of the shale samples, which can be used for the quantitative characterization of shale pore system. 相似文献
3.
采用异佛尔酮二异氰酸酯(IPDI)、聚乙二醇200、400、600、800(PEG200、PEG400、PEG600、PEG800)、2,2-二羟甲基丙酸(DMPA)、1-苯基-1,2-乙二醇、中和剂三乙胺(TEA)、甲乙酮肟等为原料,制备了一种阴离子聚氨酯分散剂.通过FTIR、GPC、TG表征了分散剂的结构与性能.利用自制的分散剂采用研磨法制备了液体靛蓝分散液,以液体靛蓝分散液粒径、离心稳定性、储存稳定性为指标,探讨了分散剂链长、用量对分散液性能的影响.结果表明,研磨1 h后,以PEG400为软段合成的聚氨酯分散剂用量为染料质量的60%时制备的液体靛蓝粒径为277.1 nm,1000 r/min离心稳定性达到93.98%,3000 r/min离心稳定性为51.13%,常温放置7 d后粒径变化在20 nm以内,染色后织物的颜色深度(K/S)为10左右,约是粉状靛蓝染色K/S的2倍,染色织物的颜色性能并未改变,SEM显示分散体颗粒大小分布均匀,与分散剂甲基萘磺酸钠的甲醛缩合物(MF)和木质素85A相比,其分散体系稳定性差别不大. 相似文献
4.
5.
In this paper, we study scheduling games under mixed coordination mechanisms on hierarchical machines. The two scheduling policies involved are ‐ and ‐, where ‐ (resp., ‐) policy sequences jobs in nondecreasing order of their hierarchies, and jobs of the same hierarchy in nonincreasing (resp., nondecreasing) order of their processing times. We first show the existence of a Nash equilibrium. Then we present the price of anarchy and the price of stability for the games with social costs of minimizing the makespan and maximizing the minimum machine load. All the bounds given in this paper are tight. 相似文献
6.
The synthesis of BaMgAl10O17∶ Eu2 (BAM) phosphors using the sol-gel method and their luminescence properties were reported. The blue-light emitting BAM was synthesized using citric acid and ethylene glycol as chelating materials. Emission of blue-light was obtained from these phosphors. The luminescent intensity increases as the temperature of heat treatment is increased. This study investigated the effects of the molar ratio of ethylene glycol to citric acid (Φ value), with respect to the phase formation and luminescence properties of BAM. The variation of the Φ value resulted in the change of the sol-gel reaction mechanism and the microstructures of the resultant powders. An increase in Φ value leads to an increase in the rate of BAM phase formation. The photoluminescent intensity of the prepared phosphors increases with heating temperatures because of enhanced crystallization. 相似文献
7.
垦71井区三维VSP资料波场分离方法应用研究 总被引:8,自引:5,他引:3
三维VSP资料是多偏移距VSP资料,资料中多种类型的波叠合在一起形成复杂波场。从复杂波场中分离出单一的保幅反射波波场是三维VSP波场分离的重要工作。常规二维VSP波场处理方法单一,难以适用于复杂的三维波场处理。针对三维VSP资料的波场特点,以分离上行反射P波为例,将单一波场分离方法加以适当组合,对垦71井区三维VSP实际资料进行了应用研究。结果表明,波场分离处理中叠加消去法和中值滤波相结合以及F—K滤波和中值滤波相结合的方法克服了单一方法的缺陷,波场处理后获得了波组特征明显、波场清晰单一的上行反射P波保幅波场,取得了较好的波场分离效果。 相似文献
8.
Over tensile stress ranges giving creep lives up to 2000 hours at 373 to 463 K, the creep and creep fracture properties of
7010 are compared with results recorded for 7075 and other precipitation-hardened aluminum alloys. Using the ϕ methodology
to quantify the systematic variations in creep curve shape with changing test conditions, the behavior patterns displayed
by the different alloys are shown to depend on the extent to which precipitate coarsening causes a progressive loss of creep
strength with increasing test duration and temperature. The ϕ relationships also introduce new approaches for rationalization
and interpretation of creep data sets, based on the activation energy for lattice diffusion in the alloy matrices and the
yield stress or UTS at the creep temperatures. 相似文献
9.
An inventory analysis of rural pollution loads in China. 总被引:1,自引:0,他引:1
Rural pollution has attracted increasing attention over the past decade for its important consequences on surface and groundwater quality. This is particularly so in China due to the wide and effective control of industrial and municipal wastewater discharges over the past decade. Based on the discussion of rural activities in China, this paper develops a new method of inventory analysis through the definition of elementary unit (EU). This inventory analysis approach is then applied to estimate the total rural pollution loads of COD, TN and TP, as well as their spatial distributions in China. Further analysis is also conducted to investigate the correlations between rural pollution loads and agricultural production outputs, as well as population. It is found that China's agriculture is developing largely at the cost of environment quality, and a high population, as well as the increasing demand for agricultural products, is one of the dominant driving forces. The constructed EKC, which describes the relationship between rural pollution loads and agricultural income, also reveals that current agricultural development in China is mostly far from de-locked from the environmental problem. 相似文献
10.
Based on the current spin density functional theory, a theoretical model of three vertically aligned semiconductor quantum dots is proposed and numerically studied. This quantum dot molecule (QDM) model is treated with realistic hard-wall confinement potential and external magnetic field in three-dimensional setting. Using the effective-mass approximation with band nonparabolicity, the many-body Hamiltonian results in a cubic eigenvalue problem from a finite difference discretization. A self-consistent algorithm for solving the Schrödinger-Poisson system by using the Jacobi-Davidson method and GMRES is given to illustrate the Kohn-Sham orbitals and energies of six electrons in the molecule with some magnetic fields. It is shown that the six electrons residing in the central dot at zero magnetic field can be changed to such that each dot contains two electrons with some feasible magnetic field. The Förster-Dexter resonant energy transfer may therefore be generated by two individual QDMs. This may motivate a new paradigm of Fermionic qubits for quantum computing in solid-state systems. 相似文献