激光光源粒子计数器响应曲线对粒子折射率敏感度及多值性的分析

采用激光作光源的光学粒子计数器(L_OPC)克服了白炽灯作光源时使用寿命短、发光强度不稳定、需要经常标定的缺点,但激光波长的单一也带来了一些问题,如响应曲线对折射率敏感度的变化和多值性等问题。利用Mie散射理论,通过数值模拟实验,对L_OPC的这些问题进行了分析,提出了L_OPC实验样机的设计参数。     

双差分测量对流层臭氧的实验研究

 提出了利用266nm,289nm,308nm三波长进行臭氧测量的数值模拟和实际测量实验研究。三波长双差分和双波长差分的模拟实验结果表明,当对流层气溶胶分布相当不均匀,后向散射比梯度较大时,气溶胶对双波长差分测量臭氧影响很大,而对三波长双差分测量臭氧影响较小。     

ALTERATION IN CHROMATIN CONFORMATION OF PROLIFERATING AND DIFFERENTIATING ENZYME GENES IN NORMAL MOUSE LIVER AND ASCITES HEPATOMA CELLS AND ITS RELATION TO THE GENE EXPRESSION OF ENZYMES

Nuclei from the normal mouse liver were partially digested with micrococcal nuclease, followed by DNA extraction, agarose gel clectrophoresis and dot blot hybridization with ~(32)P-labeled cDNA probes of CPS_1 and ACT complex, It was clearly shown that the CPS_1 genes were distributed on the monomer, dimer. and trimer of nucleosomes, while the genes coding for ACT complex were distributed on the condensed oligonucleosomes. An opposite manner of distribution of CPS_1 and ACT complex genes was, however, noted in the case of ascites hepatoma cells, in which the specific activity of ACT was 13 times higher than that in the normal liver, while that of CPS_1 was remarkably reduced. Similar patterns of change in mRNA level of CPS_1 and ACT complex were observed in the normal mouse liver and ascites hepatoma cells, indicating a close relationship between chromatin structure and gene expression of these enzymes.     

增塑剂对1,1,1-三[1′-(2′-氧杂-4′-氧代-5′-氮杂-5′-甲基)十二烷基]丙烷PVC膜钠离子电极性能的影响

以1,1,1-三[1′-(2′-氧杂-4′-氧代-5′-氮杂-5′-甲基)十二烷基]丙烷(即ETH 227,Fluka No.71732)为中性载体的钠离子选择电极由于具有较强的抗钾离子干扰的能力,因而颇受注意。Guggi等首先用邻硝基苯辛醚和癸二酸二丁酯增塑,以合成的ETH227制成了K_((Na)~+,K~+)~(pot),<<10~(-2)的PVC膜钠离子电极.Jenny等以癸二酸二异辛酯为增塑剂,     

Er3+在二氧化硅介孔分子筛中的高效率发光及其分析

研究了一种新型的负载Er3 的二氧化硅介孔分子筛纳米材料,分析了其在有无功能化试剂全氟甲基磺酰(bis(perfluoromethylsulfonyl)amine)修饰作用下的吸收和荧光光谱特性,获得了高强度的荧光发射.应用Judd-OfelI理论计算了强度参数(Ω2=1.88×10-20,Ω4=5.45×10-20 cm2,Ω6=3.11×1O-20cm2)、跃迁振子强度、自发跃迁概率、能级辐射寿命等重要的光谱参数,讨论了吸收和发射跃迁截面(Ωem=10.9×10-21 cm2),研究了在介孔分子筛纳米材料中的Er3 在不同的抽运功率条件下的荧光强度变化情况.比较了Er3 在不同基质材料中的带宽特性.研究表明二氧化硅介孔分子筛有利于实现高效率的激光输出或具有较宽带宽的高增益光放大,能够成为掺铒激光器或光放大器的新型基质材料.     

基于双F-P干涉仪的多普勒测风激光雷达的性能分析

自行研制了一台基于双边缘技术的多普勒激光雷达,用于测量对流层大气风场。该雷达采用具有高光谱分辨率的双Fabry-Perot干涉仪来检测气溶胶后向散射的多普勒频移量。给出了多普勒测风激光雷达的结构和参数。利用干涉仪参数讨论了雷达系统的测量精度。实验测定了双干涉仪的频谱曲线。通过计算和分析,由测量的干涉仪频谱曲线的的标准偏差引起的系统测量误差为0.5 m/s。系统的测量误差随着测量的高度和所测速度的增加在增大,在高度10 km测量50 m/s的风速时系统的测量误差小于2 m/s。     

激光雷达信号随机误差的估算

在分析随机误差来源和激光雷达数据特点的基础上,介绍一种新的随机误差计算方法——噪音比例因子方法.该方法用一次测量数据列中远处背景信号算出噪音比例因子,再由噪音比例因子求出任一距离上有用信号的随机误差.用实测的激光雷达信号进行检验,结果表明,这种方法是可靠且可行的.     

农药甲霜灵对映体的高效液相色谱分离及手性拆分热力学研究

以正己烷 异丙醇为流动相 ,在纤维素 三 (3 ,5 二甲基苯基氨基甲酸酯 ) (CDMPC)涂敷型手性固定相上 ,对农药甲霜灵外消旋体进行了拆分 ,考察了流动相组成、柱温等对甲霜灵对映体的保留和分离的影响 ;对甲霜灵R、S对映体与固定相之间的保留和分离的热力学机理进行了讨论     

Generation of UV laser light by stimulated Raman scattering in D2, D2/Ar and D2/He using a pulsed Nd:YAG laser at 355nm

A pulsed Nd:YAG laser at 355nm is used to pump Raman cell filled with D_2, D_2/Ar and D_2/He. With adequately adjusted parameters, the maximum photon conversion efficiency of the first-order Stokes light (S_1, 396.796nm) reaches 33.33% in D_2/Ar and the stability of S_1 in pure D_2 is fairly high, the energy drift being less than 10% when the pump energy drifts in the range of 5%. The conversion efficiency and stability, which are functions of the composition and pressure of the Raman medium and the energy of pump laser, are investigated. The result has been used to optimize the laser transmitter system for a differential absorption lidar system to measure NO_2 concentration profiles.     

光学粒子计数器测量结果的订正

本文根据球形粒子的米(Mie)散射原理计算了光学粒子计数器的散射相函数和仪器响应曲线。根据被测粒子的折射率对测量结果做出订正。在研究大气气溶胶粒子尺寸谱变化规律时,这种订正是很重要的。文中举例说明了实际订正方法。