Transient and spatial modeling and simulation of polybrominated diphenyl ethers reaction and transport in air, water and soil

The release of the wastes containing polybrominated diphenyl ethers into the environment is a worldwide major concern. Investigation of spatial and temporal variations of polybrominated diphenyl ethers concentrations due to different factors, especially the transport of these species between air and water as well as between air and soil is the purpose of present research. A model was developed and solved using the methods of finite difference and lines. Simulations were implemented for three dimensions of width, length, and height and also time for the air compartment, whereas for the soil and water compartments, variations were considered only with respect to height and time. Transport between water and soil was disregarded for simplicity at this stage. Vancouver’s landfill was considered as a case study. Lower concentrations in air and higher concentrations in water at the interface show that these pollutants tend to diffuse from air to water. Concentrations of all four pollutants decrease near the interface in soil as time passes, but they are predicted to be almost constant at other levels.     

Groundwater resources evaluation in calcareous limestone using geoelectrical and VLF-EM surveys (El Salloum Basin,Egypt)

Understanding and developing groundwater resources in arid regions such as El Salloum basin, along the northwestern coast of Egypt, remains a challenging issue. One-dimensional (1D) electrical sounding (ES), two-dimensional (2D) electrical resistivity imaging (ERI), and very low frequency electromagnetic (VLF-EM) measurements were used to investigate the hydrogeological framework of El Salloum basin with the aim of determining the potential for extraction of potable water. 1D resistivity sounding models were used to delineate geoelectric sections and water-bearing layers. 2D ERI highlighted decreases in resistivity with depth, attributed to clay-rich limestone combined with seawater intrusion towards the coast. A depth of investigation (DOI) index was used to constrain the information content of the images at depths up to 100 m. The VLF-EM survey identified likely faults/fractured zones across the study area. A combined analysis of the datasets of the 1D ES, 2D ERI, and VLF-EM methods identified potential zones of groundwater, the extent of seawater intrusion, and major hydrogeological structures (fracture zones) in El Salloum basin. The equivalent geologic layers suggest that the main aquifer in the basin is the fractured chalky limestone middle Miocene) south of the coastal plain of the study area. Sites likely to provide significant volumes of potable water were identified based on relatively high resistivity and thickness of laterally extensive layers. The most promising locations for drilling productive wells are in the south and southeastern parts of the region, where the potential for potable groundwater increases substantially.

     

Structuring factors of the spatio-temporal variability of macrozoobenthos assemblages in a southern Mediterranean lagoon: How useful for bioindication is a multi-biotic indices approach?

The authors investigated the impact of the extension of the El Kantra Channel on the composition and structure of macrobenthic assemblages in Boughrara Lagoon (Gulf of Gabes, Tunisia along with the use of 4 biotic indices (AMBI, BENTIX, M-AMBI and TUBI). Thirteen stations were sampled seasonally in 2012–2013. Forty-one species were found in 2012–2013 not recorded in 2009–2010, including 20 species of polychaetes belonging to the trophic groups of deposit-feeders and carnivores which are expected to increase in areas disturbed by organic pollution. During the survey, we recorded a high fish mortality, essentially caused by the development of harmful algal blooms (HAB) which increased organic matter deposition, thus inducing polychaete development. This seems to weaken the bio-indicating power of biotic indices used here which, paradoxically, classified all sampled stations at a high ecological status. A review of these indices and their applicability to all marine environments is recommended.     

PM10 Source Apportionment in Ahvaz,Iran, Using Positive Matrix Factorization

Source apportionment of particulate matter <10 µm in diameter (PM₁₀), having considerable impacts on human health and the environment, is of high priority in air quality management. The present study, therefore, aimed at identifying the potential sources of PM₁₀ in an arid area of Ahvaz located in southwest of Iran. For this purpose, we collected 24‐h PM₁₀ samples by a high volume air sampler. The samples were then analyzed for their elemental (Al, As, B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Mg, Mn, Na, Ni, Pb, Se, Si, Sn, Sr, Li, Ti, V, Zn, Mo, and Sb) and ionic (NH, Cl^?, NO, and SO) components using inductively coupled plasma optical emission spectrometry and ion chromatography instruments, respectively. Eight factors were identified by positive matrix factorization: crustal dust (41.5%), road dust (5.5%), motor vehicles (11.5%), marine aerosol (8.0%), secondary aerosol (9.5%), metallurgical plants (6.0%), petrochemical industries and fossil fuel combustion (13.0%), and vegetative burning (5.0%). Result of this study suggested that the natural sources contribute most to PM₁₀ particles in the area, followed closely by the anthropogenic sources.     

The concept of ecological succession applied to phytoplankton over four consecutive years in five ponds featuring a salinity gradient

The distribution of phytoplankton abundance, biomass and species composition coupled with environmental factors and metazooplankton was studied relatively intensively and over a period of four consecutive years in five ponds featuring a gradient of increasing salinity from near to that of sea water to a nine-fold concentration from 2000 to 2003. The results indicate that the physical characteristics of the water (temperature and salinity) were quite similar over the years. Nutrients, which were concentrated in pond A1, decreased with increases in salt concentration. The composition of the phytoplankton community showed strong seasonality. Diatoms dominated in the first ponds A1, A16 and C2-1, followed by dinoflagellates. Chlorophyceae dominated the phytoplankton community in the hypersaline ponds M2 and TS. Cyanobacteriae were relatively abundant in ponds M2 and TS. The highest phytoplankton density and biomass were found in the ponds with the highest salinity due to the proliferation of Dunaliella salina (Chlorophyta: Volvocales). The inter-annual study of phytoplankton succession in the Sfax solar salterns showed slight differences among the years of study due to the stability of the environmental conditions. Phytoplankton communities were permanently primitive, stage 1 – structured as they failed to build complexity because of salt stress which operates for longer and above any other variables. This reduced frequency of disturbance to the existing course of regulation, allowed the community to “mature” from its “primitive” state, rather than experience frequent structural setbacks.     

Neoproterozoic calc‐alkaline peraluminous granitoids of the Deleihimmi pluton,Central Eastern Desert,Egypt: implications for transition from late‐ to post‐collisional tectonomagmatic evolution in the northern Arabian–Nubian Shield

The widely distributed late‐collisional calc‐alkaline granitoids in the northern Arabian–Nubian Shield (ANS) have a geodynamic interest as they represent significant addition of material into the ANS juvenile crust in a short time interval (∼630–590 Ma). The Deleihimmi granitoids in the Egyptian Central Eastern Desert are, therefore, particularly interesting since they form a multiphase pluton composed largely of late‐collisional biotite granitoids enclosing granodiorite microgranular enclaves and intruded by leuco‐ and muscovite granites. Geochemically, different granitoid phases share some features and distinctly vary in others. They display slightly peraluminous (ASI = 1–1.16), non‐alkaline (calc‐alkaline and highly fractionated calc‐alkaline), I‐type affinities. Both biotite granitoids and leucogranites show similar rare earth element (REE) patterns [(La/Lu)_N = 3.04–2.92 and 1.9–1.14; Eu/Eu* = 0.26–0.19 and 0.11–0.08, respectively) and related most likely by closed system crystal fractionation of a common parent. On the other hand, the late phase muscovite granites have distinctive geochemical features typical of rare‐metal granites. They are remarkably depleted in Sr and Ba (4–35 and 13–18 ppm, respectively), and enriched in Rb (381–473 ppm) and many rare metals. Moreover, their REE patterns show a tetrad effect (TE_1,3 = 1.13 and 1.29) and pronounced negative Eu anomalies (Eu/Eu* = 0.07 and 0.08), implying extensive open system fractionation via fluid–rock interaction during the magmatic stage. Origin of the calc‐alkaline granitoids by high degree of partial melting of mafic lower crust with subsequent crystal fractionation is advocated. The broad distribution of late‐collisional calc‐alkaline granitoids in the northern ANS is related most likely to large areal and intensive lithospheric delamination subsequent to slab break‐off and crustal/mantle thickening. Such delamination caused both crustal uplift and partial melting of the remaining mantle lithosphere in response to asthenospheric uprise. The melts produced underplate the lower crust to promote its melting. The presence of microgranular enclaves, resulting from mingling of mantle‐derived mafic magma with felsic crustal‐derived liquid, favours this process. The derivation of the late‐phase rare‐metal granites by open system fractionation via fluid interaction is almost related to the onset of extension above the rising asthenosphere that results in mantle degassing during the switch to post‐collisional stage. Consequently, the switch from late‐ to post‐collisional stage of crustal evolution in the northern ANS could be potentially significant not only geodynamically but also economically. Copyright © 2011 John Wiley & Sons, Ltd.     

MAG Waves in Sunspots Umbrae: Slow Waves Leaking to the Corona

The linear oscillations of a stratified atmosphere embedded in a uniform vertical magnetic field are studied here. We use a simple theoretical model, formed by the superposition of two isothermal layers, representing, respectively, i) the photosphere and the chromosphere, and ii) the corona. The bottom layer behaves, for some modes, as a resonant cavity where MAG waves are semi-trapped. We find the existence of two types of modes: 1) Fast modes which are trapped below the transition layer, 2) Mixed modes which are resonant modes in the first layer and leak part of the energy to the corona. These mixed modes have been found to be damped in the horizontal direction and can explain the observed slow modes in the corona.     

Earthquake response of concrete arch dams: a plastic–damage approach

There are several alternatives to evaluate seismic damage‐cracking behavior of concrete arch dams, among which damage theory is the most popular. A more recent option introduced for this purpose is plastic–damage (PD) approach. In this study, a special finite element program coded in 3‐D space is developed on the basis of a well‐established PD model successfully applied to gravity dams in 2‐D plane stress state. The model originally proposed by Lee and Fenves in 1998 relies on isotropic damaged elasticity in combination with isotropic tensile and compressive plasticity to capture inelastic behaviors of concrete in cyclic or dynamic loadings. The present implementation is based on the rate‐dependent version of the model, including large crack opening/closing possibilities. Moreover, with utilizing the Hilber–Hughes–Taylor time integration scheme, an incremental–iterative solution strategy is detailed for the coupled dam–reservoir equations while the damage–dependent damping stress is included. The program is initially validated, and then, it is employed for the main analyses of the Koyna gravity dam in a 3‐D modeling as well as a typical concrete arch dam. The former is a major verification for the further examination on the arch dam. The application of the PD model to an arch dam is more challenging because the governing stress condition is multiaxial, causing shear damage to become more important than uniaxial states dominated in gravity dams. In fact, the softening and strength loss in compression for the damaged regions under multiaxial cyclic loadings affect its seismic safety. Copyright © 2013 John Wiley & Sons, Ltd.