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1.
通过制备不同晶相结构〔单斜相(m-ZrO_2)、四方相(t-ZrO_2)和无定型(a-ZrO_2)〕ZrO_2载体,再通过沉积沉淀法制得Cu/m-ZrO_2、Cu/t-ZrO_2和Cu/a-ZrO_2催化剂,分别用于催化二乙醇胺脱氢合成亚氨基二乙酸反应。采用XRD、氮气物理吸附脱附、XPS、H_2-TPR、CO_2-TPD对催化剂的结构进行了表征。结果表明,Cu/m-ZrO_2催化剂界面更加有利于Cu~+/Cu~0稳定存在,具有更多的碱性位点,且抗氧化性较好。在二乙醇胺脱氢反应中,Cu/m-ZrO_2催化剂性能最好,反应时间为2.5 h,亚氨基二乙酸收率为97.64%。 相似文献
2.
采用异佛尔酮二异氰酸酯(IPDI)、聚乙二醇200、400、600、800(PEG200、PEG400、PEG600、PEG800)、2,2-二羟甲基丙酸(DMPA)、1-苯基-1,2-乙二醇、中和剂三乙胺(TEA)、甲乙酮肟等为原料,制备了一种阴离子聚氨酯分散剂.通过FTIR、GPC、TG表征了分散剂的结构与性能.利用自制的分散剂采用研磨法制备了液体靛蓝分散液,以液体靛蓝分散液粒径、离心稳定性、储存稳定性为指标,探讨了分散剂链长、用量对分散液性能的影响.结果表明,研磨1 h后,以PEG400为软段合成的聚氨酯分散剂用量为染料质量的60%时制备的液体靛蓝粒径为277.1 nm,1000 r/min离心稳定性达到93.98%,3000 r/min离心稳定性为51.13%,常温放置7 d后粒径变化在20 nm以内,染色后织物的颜色深度(K/S)为10左右,约是粉状靛蓝染色K/S的2倍,染色织物的颜色性能并未改变,SEM显示分散体颗粒大小分布均匀,与分散剂甲基萘磺酸钠的甲醛缩合物(MF)和木质素85A相比,其分散体系稳定性差别不大. 相似文献
3.
4.
Over tensile stress ranges giving creep lives up to 2000 hours at 373 to 463 K, the creep and creep fracture properties of
7010 are compared with results recorded for 7075 and other precipitation-hardened aluminum alloys. Using the ϕ methodology
to quantify the systematic variations in creep curve shape with changing test conditions, the behavior patterns displayed
by the different alloys are shown to depend on the extent to which precipitate coarsening causes a progressive loss of creep
strength with increasing test duration and temperature. The ϕ relationships also introduce new approaches for rationalization
and interpretation of creep data sets, based on the activation energy for lattice diffusion in the alloy matrices and the
yield stress or UTS at the creep temperatures. 相似文献
5.
Improved homogenization of Ni in sintered steels through the use of Cr-containing prealloyed powders
The homogenization of Ni in powder metal (PM) steel compacts is usually difficult even after high-temperature sintering at
1250°C. An earlier study by the authors demonstrated that this problem can be alleviated through the addition of 0.5 wt pct
Cr in the form of stainless steel powders. To further improve the microstructure and mechanical properties of Ni-containing
PM steels and to understand the mechanisms, an attempt was made in this study using the Fe-3Cr-0.5Mo prealloyed powder as
the base material. The results showed that the distribution of the Ni additives was significantly improved. As a result, the
tensile strength of the Fe-3Cr-0.5Mo-4Ni-0.5C compact sintered at 1250°C reached 1323 MPa. The elongation was higher than
1 pct. These sinter-hardened properties, which were attained using a slow furnace cooling rate, were comparable to those of
the sinter-hardened alloys reported in the literature using accelerated cooling and were equivalent to those of the best quenched-and-tempered
alloys registered in the Metal Powder Industries Federation (MPIF) standards. These improvements were attributed to the positive
effect of Cr addition on alloy homogenization due to the reduction of the repelling effect between Ni and C, as was demonstrated
through the thermodynamic analysis using the Thermo-Calc program. 相似文献
6.
Supported metal catalysts, particularly noble metals supported on SiO2, have attracted considerable attention due to the importance of the silica–metal interface in heterogeneous catalysis and in electronic device fabrication. Several important issues, e.g., the stability of the metal–oxide interface at working temperatures and pressures, are not well-understood. In this review, the present status of our understanding of the metal–silica interface is reviewed. Recent results of model studies in our laboratories on Pd/SiO2/Mo(1 1 2) using LEED, AES and STM are reported. In this work, epitaxial, ultrathin, well-ordered SiO2 films were grown on a Mo(1 1 2) substrate to circumvent complications that frequently arise from the silica–silicon interface present in silica thin films grown on silicon. 相似文献
7.
Ludmil Drenchev Jerzy Sobczak Rajiv Asthana Savko Malinov 《Journal of Computer-Aided Materials Design》2003,10(1):35-54
Ordered porosity metal materials belong to a relatively new class of porous materials named gasars. This paper presents a mathematical model of the complex physical phenomena in the production of gasars. Analyses for heat transfer, solidification kinetics and gas diffusion were coupled to describe the formation of unique gasar structure. Several criterial functions were introduced to provide significant quantitative information about the relationship between the operating technological parameters and the final structure. The computational outcomes of the numerical simulation were compared with the characteristics of real gasar ingots. The model was applied to determine the boundary conditions that would provide approximately constant physical conditions on the solidification front. The structure sensitiveness of gasars with respect to the different technological parameters is discussed. 相似文献
8.
深水海底泥浆举升钻井技术及其应用前景 总被引:2,自引:1,他引:1
为了解决深水钻井中遇到的问题,由Conoco公司领导的工业联合项目组研发了海底泥浆举升钻井(以下简称SMD)技术。采用该技术进行深水钻井时,隔水管内充满海水,泥浆用小直径管线从海底返回,在返回环空中形成两个压力梯度,实现双梯度控压钻井。文中着重介绍了SMD的理论依据、系统工作原理、系统关键设备以及SMD井控程序的HAZOP分析等。从技术适用性、经济性、装备以及可能存在的风险等方面对该技术在南中国海钻井中使用的可行性进行研究,并展望其应用前景。 相似文献
9.
10.
北部湾盆地福山凹陷CO2气成因探讨 总被引:2,自引:1,他引:1
北部湾盆地福山凹陷油气钻探中发现了高含CO2气的天然气气藏。对CO2气稳定碳同位素、伴生稀有气体氦和氩同位素进行了分析研究,结果显示,福山凹陷CO2气稳定碳同位素偏重,(13CCO2为-5.01~-10.08‰,绝大多数样品大于-7.0‰,为无机成因CO2气特征;伴生稀有气体氦同位素3He/4He值为(4.74~5.03)×10-6,R/Ra值为3.38~3.59;伴生稀有气体氩同位素40Ar/36Ar值为1881~2190,也显示出幔源或壳幔混合CO2气的特征。综合判定认为,福山凹陷CO2为壳幔混合成因。始新统流沙港组岩浆岩体分布特征与CO2气藏分布范围基本一致,也表明幔源-岩浆可能是福山凹陷CO2气的主要来源。与南海北部边缘盆地其它地区如珠江口盆地西部、琼东南盆地东部CO2气成因一致,都为幔源-岩浆来源,或壳幔混合来源。 相似文献