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1.
The effect of bacterial and fungal activities on organic matter degradation in Brazilian soils was studied by a microcalorimetric method. Bacteria and fungi isolated from tropical soils and added to: Rhodic eutrudox (R), Typic eutrudox (V) and Quartzipsamment (Q) soils amended separately with moisture (control) (A) and 25% of cattle manure (E), municipal refuse compost (L), earthworm casts (H) or 23 μg of trifluralin (T) were investigated. The number of colony forming units in soil suspension was quantified by microscopy and inoculated in respective soil. All processes were measured at intervals of 7 days over a period of 35 days. The exothermic thermal effect (μJ) per cm3 of bacteria or fungi per gram of dry soil, respectively, for each substrate was: [(9±1), (4±1)] RA; [(478±24), (105±5)] RE; [(121±6), (71±4)] RL; [(121±6), (71±4)] RH; [(8±1); (3±1)] RT; [(10±1), (9±1] VA; [(347±17), (261±13)] VE; [(71±4), (28±1)] VL; [(22±1), (33±2)] VH; [(7±1), (10±1)] VT; [(19±1), (12±1)] QA; [(1301±65), (46±2)] QE; [(89±4), (9±1)] QL; [(130±7), (11±1)] QH; [(32±2), (8±1)] QT. The calorimetric values are higher for bacteria than for fungi. In general, the results showed higher activities in the soil amended with cattle manure than with other additives. 相似文献
2.
Fulvia Orsini Guido Sello Silvana Bernasconi Gianfranco Fallacara 《Tetrahedron letters》2004,45(50):9253-9255
Several conduritol and conduramine analogues have been synthesized from β-substituted naphthalenes via a chemoenzymatic approach, in a high regio- and stereocontrolled way. 相似文献
3.
Tarozzi A Marchesi A Hrelia S Angeloni C Andrisano V Fiori J Cantelli-Forti G Hrelia P 《Photochemistry and photobiology》2005,81(3):623-629
Ultraviolet-A (UVA) radiation causes significant oxidative stress because it leads to the generation of reactive oxygen species (ROS), leading to extensive cellular damage and eventual cell death either by apoptosis or necrosis. We evaluated the protective effects of cyanidin-3-O-beta-glucopyranoside (C-3-G) against UVA-induced apoptosis and DNA fragmentation in a human keratinocyte cell line (HaCaT). Treatment of HaCaT cells with C-3-G before UVA irradiation inhibited the formation of apoptotic cells (61%) and DNA fragmentation (54%). We also investigated antioxidant properties of C-3-G in HaCaT cells against ROS formation at apoptotic doses of UVA; C-3-G inhibited hydrogen peroxide (H2O2) release (an indicator of cellular ROS formation) after UVA irradiation. Further confirmation of the potential of C-3-G to counteract UVA-induced ROS formation comes from our demonstration of its ability to enhance the resistance of HaCaT cells to the apoptotic effects of both H2O2 and the superoxide anion (O2*-), two ROS involved in UVA-oxidative stress. Furthermore, in terms of Trolox Equivalent Antioxidant Activity, C-3-G treatment led to a greater increase in antioxidant activity in the membrane-enriched fraction than in the cytosol (55% vs 19%). The protective effects against UVA-induced ROS formation can be attributed to the higher membrane levels of C-3-G incorporation. These encouraging in vitro results support further research into C-3-G (and other anthocyanins) as novel agents for skin photoprotection. 相似文献
4.
Bronger RP Silva SM Kamer PC van Leeuwen PW 《Dalton transactions (Cambridge, England : 2003)》2004,(10):1590-1596
A highly active and regioselective catalyst obtained from a novel dicationic ligand (1) and Rh(CO)2(acac) for hydroformylation of 1-hexene and 1-octene in ionic liquids is reported. Optimisation studies of various reaction parameters led to an unprecedentedly active (TOFs > 6200 mol mol(-1) h(-1), T= 100 degrees C), selective (l/b ratios > 40) and stable hydroformylation procedure. No catalyst leaching (Rh-loss < 0.07% of initial rhodium intake, P-loss < 0.4% of the initial phosphorus intake) or losses in performance could be measured during 1-octene hydroformylation recycle experiments in 1-butyl-3-methylimidazolium hexafluorophosphate. At low catalyst loadings activities and regioselectivities competitive with one-phase catalysis in conventional solvents were observed. At high catalyst loadings the system is extremely stable and has a long shelf-life as a result of the formation of stable, if inactive rhodium dimers. 相似文献
5.
Luigia Serpico Mauro De Nisco Flavio Cermola Michele Manfra Silvana Pedatella 《Molecules (Basel, Switzerland)》2021,26(9)
A simple and efficient route for the synthesis of new glycoconjugates has been developed. The approach acts as a model for a mini-library of compounds with a deoxy-selenosugar core joined to a polyphenolic moiety with well-known antioxidant properties. An unexpected stereocontrol detected in the Mitsunobu key reaction led to the most attractive product showing a natural d-configuration. Thus, we were able to obtain the target molecules from the commercially available d-ribose via a shorter and convenient sequence of reactions. 相似文献
6.
Castellano PM Vignaduzzo SE Maggio RM Kaufman TS 《Analytical and bioanalytical chemistry》2005,382(7):1711-1714
A new, repeatable, and rapid method has been developed for resolution of binary mixtures of acetaminophen and diclofenac with minimum sample pretreatment and without separation of the analytes. The method, based on the PLS1 processing of absorbance data in the UV region, was successfully used for quantification of the drug content of three tablet preparations. The results obtained were in good agreement with HPLC recovery data. The method also enabled determination of drug-dissolution profiles of these commercial tablets, by simultaneous determination of both analytes during the dissolution test. 相似文献
7.
Angelo Ranise Francesco LucchesiniMatteo Caviglia Silvana AlfeiAndrea Spallarossa Chiara Caneva 《Tetrahedron》2013
A simple one-pot procedure for the stereoselective synthesis of Knoevenagel-type indoles is described. The method is based on the in situ reaction of indole iminium salts (four of them are fully characterized) with acyclic symmetrical and unsymmetrical active methylene reagents in the presence of triethylamine. In general, the overall yields are moderate to good. Some of relevant reaction parameters and steric effects affecting stereoselectivity are discussed. 相似文献
8.
Silvana P. Ravía Mariela Risso Santiago Kröger Silvana Vero Gustavo A. Seoane Daniela Gamenara 《Tetrahedron: Asymmetry》2013,24(19):1207-1211
(2S,3R)-Sitophilate, the male-produced aggregation pheromone of the granary weevil Sitophilus granarius (L.) was prepared stereoselectively using a novel chemoenzymatic approach in 50% overall yield. The synthetic design was based on an enantioselective fungal reduction of ethyl 2-methyl-3-oxopentanoate with a strain of Aureobasidium pullulans (CCM H1), followed by a Mitsunobu inversion at C3. The last step in the synthetic sequence was a lipase-mediated transesterification using the commercially available Candida antarctica B lipase (CaL B, Novozym 435) using microwave irradiation under solvent-free conditions. 相似文献
9.
10.
(2Z,1S)-1,3-diphenyl-2-propenol (3) is obtained from the chiral 5,6-dihydro-1,4-dithiin 1b in two steps and 60% enantiomeric excess. Combining our previously reported stereoselective double bond formation and this 1,4 asymmetric induction introduces a new route to chiral allylic alcohols with cis geometry from simple aldehydes and methyl ketones. 相似文献