Synthesis of highly dense and fine-grained aggregates of mantle composites by vacuum sintering of nano-sized mineral powders

Synthesized mineral powders with particle size of <100 nm are vacuum sintered to obtain highly dense and fine-grained polycrystalline mantle composites: single phase aggregates of forsterite (iron-free), olivine (iron containing), enstatite and diopside; two-phase composites of forsterite + spinel and forsterite + periclase; and, three-phase composites of forsterite + enstatite + diopside. Nano-sized powders of colloidal SiO₂ and highly dispersed Mg(OH)₂ with particle size of ≤50 nm are used as chemical sources for MgO and SiO₂, which are common components for all of the aggregates. These powders are mixed with powders of CaCO₃, MgAl₂O_4, and Fe(CO₂CH₃)₂ to introduce mineral phases of diopside, spinel, and olivine to the aggregates, respectively. To synthesize highly dense composites through pressureless sintering, we find that calcined powders should be composed of particles that have: (1) fully or partially reacted to the desired minerals, (2) a size of <100 nm and (3) less propensity to coalesce. Such calcined powders are cold isostatically pressed and then vacuum sintered. The temperature and duration of the sintering process are tuned to achieve a balance between high density and fine grain size. Highly dense (i.e., porosity ≤1 vol%) polycrystalline mantle mineral composites with grain size of 0.3–1.1 μm are successfully synthesized with this method.     

Gas flow in the solar nebula leading to the formation of Jupiter

Three-dimensional gas flow in the solar nebula, which is subject to the gravity of the Sun and proto-Jupiter, is numerically calculated by using a three-dimensional hydrodynamic code - i.e., the socalled smoothed-particle method. The flow is circulating around the Sun as well as falling into a potential well of proto-Jupiter. The results for various masses of proto-Jupiter show that (1) the e-folding growth time of proto-Jupiter by accretion of the nebular gas is as short as about 300 years in stages where the mass of proto-Jupiter is 0.2 ~ 0.5 times the present Jovian mass, and that (2) proto-Jupiter begins to push away the nebular gas from the orbit of proto-Jupiter and form a gap around the orbit, when its mass is about 0.7 times the present Jovian mass. It is possible that this pushing-away process determined the present Jovian mass.     

Comparison of the acid-base responses to CO2 and acidification in Japanese flounder (Paralichthys olivaceus)

To investigate whether the biological toxicity of aquatic hypercapnia is due to the direct effects of CO2 or to the effects of acidification of seawater by CO2, the Japanese flounder (Paralichthys olivaceus) was subjected to seawater equilibrated with a gas mixture of air containing 5% CO2 (pH 6.18) or seawater acidified to the same pH with 1 N H2SO4. All the fish died within 72 h in the CO2 exposure group, whereas no mortality occurred in the acid group. Acid-base parameters as well as plasma ion concentrations were severely perturbed in the CO2 exposure group, whereas they were minimally affected in the acid group. These results clearly demonstrate that the mortality in the CO2 group is a direct result of the elevated levels of dissolved CO2 and not to the effects of the reduced water pH.     

Experimental Study of Factors Controlling Sorption of Heavy Metals on Ariake Clay and Implication for Practice

A series of batch tests have been presented to investigate the effects of solid-solution contact time, solid:solution ratio, and pH of solution on sorption of Cd²⁺ and Pb²⁺ on Ariake clay from Kyushu region of Japan. The results show that, among the three investigated factors, solid:solution ratio (SD/SN) seems to be the crucial controlling factor. The Freundlich sorption parameters determined from the batch tests were applied to a typical field landfill in which the Ariake clay was used as soil barrier. The impacts of the landfill were assessed by numerical analysis. Based on the analysis result, the significance of selecting proper solid:solution ratio for determining sorption parameters from batch test has been discussed.     

Alpine Hydrogeology: The Critical Role of Groundwater in Sourcing the Headwaters of the World

Groundwater discharge in alpine headwaters sustains baseflow in rivers originating in mountain ranges of the world, which is critically important for aquatic habitats, run-of-river hydropower generation, and downstream water supply. Groundwater storage in alpine watersheds was long considered negligible, but recent field-based studies have shown that aquifers are ubiquitous in the alpine zone with no soil and vegetation. Talus, moraine, and rock glacier aquifers are common in many alpine regions of the world, although bedrock aquifers occur in some geological settings. Alpine aquifers consisting of coarse sediments have a fast recession of discharge after the recharge season (e.g., snowmelt) or rainfall events, followed by a slow recession that sustains discharge over a long period. The two-phase recession is likely controlled by the internal structure of the aquifers. Spatial extent and distribution of individual aquifers determine the groundwater storage-discharge characteristics in first- and second-order watersheds in the alpine zone, which in turn govern baseflow characteristics in major rivers. Similar alpine landforms appear to have similar hydrogeological characteristics in many mountain ranges across the world, suggesting that a common conceptual framework can be used to understand alpine aquifers based on geological and geomorphological settings. Such a framework will be useful for parameterizing storage-discharge characteristics in large river hydrological models.     

Quantifying terrain controls on runoff retention and routing in the Northern Prairies

The role of hummocky terrain in governing runoff routing and focussing groundwater recharge in the Northern Prairies of North America is widely recognised. However, most hydrological studies in the region have not effectively utilised information on the surficial geology and associated landforms in large-scale hydrological characterization. The present study uses an automated digital elevation model (DEM) analysis of a 6500-km² area in the Northern Prairies to quantify hydrologically relevant terrain parameters for the common types of terrains in the prairies with different surficial deposits widespread in the prairies, namely, moraines and glaciolacustrine deposits. Runoff retention (and storage) capacity within depressions varies greatly between different surficial deposits and is comparable in magnitude with a typical amount of seasonal snowmelt runoff generation. The terrain constraint on potential runoff retention varies from a few millimetres in areas classified as moraine to tens of millimetres in areas classified as stagnant ice moraine deposits. Fluted moraine and glaciolacustrine deposits have intermediate storage capacity values. The study also identified the probability density function describing a number of immediate upstream neighbours for each depression in a fill-and-spill network. A relationship between depression parameters and surficial deposits, as well as identified depression network structure, allows parametrisation of hydrologic models outside of the high-resolution DEM coverage, which can still account for terrain variation in the Prairies.     

Standardization of baseline and additionality determination under the CDM

Clean Development Mechanism (CDM) project developers have long complained about the complexities of project-specific baseline setting and the vagaries of additionality determination. In response to this, the CDM Executive Board took bold steps towards the standardization of CDM methodologies, culminating in the approval of guidelines for the establishment of performance standards in November 2011. The guidelines specify a performance standard stringency level for both baseline and additionality of 80% for several priority sectors and 90% for all other sectors. However, an analysis of 14 large-scale CDM methodologies that use performance standard approaches challenges this top-down approach to the performance standard design. An appropriate performance standard stringency level strongly depends on sector and technology characteristics. A single stringency level for baseline and additionality determination is appropriate only for greenfield projects, but not for retrofit ones. Overly simple, highly aggregated performance standards are unlikely to ensure high environmental integrity, and difficult questions regarding stringency and updating frequency will eventually have to be addressed on a rather disaggregated level. A careful balance between data requirements and the practicability of performance standards is essential because the heavy data requirements of the existing performance standard methodologies have been the key barrier to their actual implementation.

Policy relevance

CDM regulators have been pushed by many stakeholders to standardize baseline setting and eliminate project-specific additionality determination. At first glance, performance standards seem to provide the perfect solution for both tasks. However, a one-size-fits-all political decision – e.g. the average of the top 20% performers as enshrined in the Marrakech Accords – is inappropriate. Substantial disaggregation of performance standards is required both technologically and geographically in order to limit over- and under-crediting and close loopholes for non-additional projects. As a lack of reliable and complete data has been and will be a key bottleneck for the development of performance standards, international support for data collection will be indispensable, but costly, and time-consuming. Empirically driven, techno-economic assessments of performance standard stringency levels must be the central task of the future work on standardized methodologies, and should not be sidelined by perceived needs of policy makers to take bold decisions under time pressures.     

Mineralogy,Fluid Inclusions,and Sulfur Isotopes of the Huanzala Deposits,Peru: Early Skarn and Late Polymetallic Replacement Style Mineralizations

Carbonate‐replacement polymetallic mineralization at the Huanzala deposits (9°51′S, 77°00′W) was conducted in two contrasting stages that occurred in almost the same location. Early‐stage mineralization has a relation with a granodiorite porphyry stock, whereas the late‐stage mineralization is genetically associated with quartz porphyry sills. The early stage involved low to intermediate sulfidation Cu–Zn–(Pb) mineralization associated with metasomatic skarn, and the late stage involved high to intermediate sulfidation Cu–Zn–Pb–(Mn) mineralization associated with hydrothermal alteration characterized by paragonitic sericitization. The orebodies are hosted by steeply dipping (approximately 60°NE) Lower Cretaceous carbonate rocks in a relatively narrow range of approximately 4 km in horizontal extent and less than 1 km in depth. The pathway of the early‐stage brine‐derived fluids (300–>400°C, >33 wt% NaCl equivalent) along a plot of log against 1000/T is best explained by the progressive dual decline of the value and the temperature under rock‐buffering conditions; this decline saw the pathway progress through the stability field of pyrrhotite to reach that of pyrite and promoted a decrease in FeS from 14.5 to 1.6 mol% in the sphalerite. In contrast, an explanation for the pathway of the late‐stage fluids (140–290°C, 3–13 wt% NaCl equivalent) is given by an almost isothermal decline at approximately 270°C, with passing through the stability field of pyrite–bornite to reach that of chalcopyrite, promoting an increase in FeS from 0.1 to 1.6 mol% in the sphalerite, suggesting gas‐buffering conditions. The ore formation pressure records in the fluid inclusions illustrate an approximately 2‐km erosion during the roughly 2‐Myr total lifetime of the hydrothermal system.     

Swelling–shrinkage properties and soil improvement of compacted expansive soil, Ning-Liang Highway, China

In this paper, the swelling–shrinkage properties of the compacted expansive soil in the Huaiyin Section of the Ning-Lian Highway are introduced, and swelling–shrinkage mechanisms are discussed based on changes in soil water content, dry density, material composition and fabric. The improvement of the compacted expansive soil by lime is also discussed briefly. It is concluded that careful attention should be paid to this type of compacted expansive soil.