The local structure of Ca-Na pyroxenes. I. XANES study at the Na K-edge

 X-ray absorption Na K-edge spectra have been recorded on synthetic endmember jadeite and on a series of natural Ca-Na pyroxenes compositionally straddling the Jd-Di join. The C2/c members of the series are systematically different from the P2/n members. Differences can be interpreted and explained by comparing the experimental spectra with theoretical spectra. These have been calculated by the multiple-scattering formalism from the atomic positional parameters determined by single-crystal X-ray diffraction structure refinement on the same samples. In the full multiple scattering region of the spectra (1075 to 1090 eV) C-pyroxenes exhibit three features which reflect the 6-2 configuration of the O back-scattering atoms around the Na absorber located at the center of the cluster (site M2 of the jadeite structure). P-pyroxenes show more complicated spectra in which at least four (possibly five) features can be recognized; they reflect the two types of configuration (6-2 and 4-2-2) of O around Na in the two independent M2 and M21 eight-fold coordinated sites of the omphacite structure. A weak, sometimes poorly resolved peak at 1079 eV is diagnostic and discriminates C- from P-pyroxenes. The Garnet Ridge C2/c impure jadeite exhibits a spectrum which is intermediate between those of jadeite and omphacite. The Hedin-Lundqvist potential proves best for these insulating materials and allows multiple-scattering calculations agreeing well with experiments. Received: July 11, 1996/Revised, accepted: October 21, 1996     

Geomorphologic map of the 1<Superscript>st</Superscript> Mutnaya River,Southeastern Kamchatka,Russia

The Kamchatka Peninsula–situated in the Pacific “Ring of Fire”–has 29 active and over 400 extinct volcanoes. Since it is situated in the northeastern extremity of Russia, in subarctic climate, the volcanic landforms are overprinted by the 446 glaciers. This research focuses on the 1^stMutnaya catchment which drains the southern slopes of two active volcanoes: Avachinsky and Koryaksky. Those volcanoes are a permanent threat for the cities of Petropavlovsk and Elizovo, which are the 2 of 3 cities of the peninsula. Hence, most of the studies carried out in the area dealt with the natural hazards and only few focus on landscape evolution. Thus, the purpose of this study was to elaborate a cartographic approach which integrates classic geomorphology with state of the art GIS and remote sensing techniques. As result, different landforms and related processes have been analysed and included in the first general geomorphologic map of the 1^stMutnaya catchment.     

Pathogenic fungi: an unacknowledged risk at coastal resorts? New insights on microbiological sand quality in Portugal

Whilst the potential impact on beach users from microorganisms in water has received considerable attention, there has been relatively little investigation into microbial contaminants in sand. Thirty three beaches across Portugal were analyzed during a five year period (2006-2010) to determine the presence of yeasts, pathogenic fungi, dermatophytes, total coliforms, Escherichia coli and intestinal enterococci in sand.Our results showed that 60.4% of the samples were positive for fungi and that 25.2% were positive for the bacterial parameters. The most frequent fungal species found were Candida sp. and Aspergillus sp., whereas intestinal enterococci were the most frequently isolated bacteria. Positive associations were detected among analyzed parameters and country-regions but none among those parameters and sampling period.Regarding threshold values, we propose 15 cfu/g for yeasts, 17 cfu/g for potential pathogenic fungi, 8 cfu/g for dermatophytes. Eighty four cfu/g for coliforms, 250 cfu/g for E. coli, and 100 cfu/g for intestinal enterococci.     

中亚萨亚克矿田成矿岩体矿物学和地球化学:岩浆性质与成矿意义

萨亚克大型铜矿田位于哈萨克斯坦北巴尔喀什斑岩成矿带中部,以矽卡岩型矿床为主。通过对矿区石英闪长岩的矿物化学和地球化学研究,发现石英闪长岩呈斑状结构,斑晶为斜长石和角闪石,其中的斜长石斑晶主要为中长石,角闪石斑晶为镁质普通角闪石;岩石属于高钾钙碱性系列,富集Rb、Sr、Ba等大离子亲石元素和轻稀土元素,亏损Nb、Ta和重稀土元素,高Sr/Y、La/Yb比值,与埃达克岩相似。地球化学特征指示萨亚克矿区侵入岩形成于岛弧环境,为矽卡岩-斑岩型成矿提供了有利的构造背景,岩石可能是岛弧玄武质岩浆在高压下经结晶分异而成。根据角闪石温压计及其成分与氧逸度和岩浆中水含量之间的关系,确定萨亚克石英闪长玢岩中角闪石斑晶结晶时岩浆的温度为799~843℃、处于3.6~9.6km深度范围内(P=1.2~3.2kbar)、氧逸度logfO2=-11.5~-12.0(ΔFMQ=2.0~2.8)、平均水含量为1.2%,相对较高的氧逸度和水含量有利于形成富含挥发分和Cu、Au等成矿物质的岩浆,是最终演化形成大型岩浆-热液型铜矿田(斑岩型、矽卡岩型)的有利条件。     

Effects of intensive aquifers exploitation on groundwater salinity in coastal wetlands

The coastal plain of the Río de la Plata constitutes a large wetland which develops on the right margin of the river estuary. Anthropic activities such as intensive exploitation of groundwater carried out in the vicinity of the wetland can modify the natural hydrological regime. The aim of this work is to asses the effects of intensive aquifer exploitation in coastal wetlands using hydrogeological models. Such models allow to evaluate changes in the environmental conditions of wetland at regional level. The hydrogeological model exposed in this work shows how the intensive groundwater exploitation affects the wetland area, generating important variations both in the groundwater flows and in the salinity of the groundwater. Identification of these modifications to the environment is important to generate guidelines leading to minimize these affectations.     

Dawn; the Vesta–HED connection; and the geologic context for eucrites,diogenites, and howardites

The Dawn mission has provided new evidence strengthening the identification of asteroid Vesta as the parent body of the howardite, eucrite, and diogenite (HED) meteorites. The evidence includes Vesta's petrologic complexity, detailed spectroscopic characteristics, unique space weathering, diagnostic geochemical abundances and neutron absorption characteristics, chronology of surface units and impact history, occurrence of exogenous carbonaceous chondritic materials in the regolith, and dimensions of the core, all of which are consistent with HED observations and constraints. Global mapping of the distributions of HED lithologies by Dawn cameras and spectrometers provides the missing geologic context for these meteorites, thereby allowing tests of petrogenetic models and increasing their scientific value.     

Iron site geometry in orthopyroxene: Multiple scattering calculations and XANES study

The iron site geometry in orthopyroxenes (OPX) and synthetic FeO, has been investigated by X-ray Absorption Near Edge Structure (XANES) spectroscopy. Multiple scattering calculations have been used to determine how the iron polyhedral geometry affects the absorption spectra. The results reported here demonstrate that this approach is effective in determining the site geometry around the absorbing atom, allowing the assignment of features in the XANES spectrum to specific structural aspects of the coordination environment. In the case of the orthopyroxenes this method allows discrimination between the multiple scattering contributions to the absorption spectrum due to the two octahedral sites M1 and M2 of the OPX structure. The results obtained with the MS calculation were used to evaluate the effects of polyhedral distortion, symmetry changes and iron site occupancies on the experimental spectra. The results indicate a more quantitative way to interpret XANES experimental spectra and give insights into the interpretation of site geometries of more complex or unknown structures and amorphous materials.     

Granulite-amphibolite facies metasediments from the Serre (Calabria,Southern Italy): their protoliths and the processes controlling their chemistry

In the northwestern Serre, a near continuous section through the Palaeozoic lower continental crust crops out. This paper deals with granulite facies metasedimentary rocks of this section. Fifty-five chemical analyses (major elements, Sc, V, Cr, Co, Ni, Rb, Sr, Y, Nb and Ba) are given. Chemical data indicate that the original sedimentary sequence was made up of arenites in the lower part and mainly Fe and Mg rich pelites in the upper part. The metapelites experienced anatexis and removal of some melt, whereas the meta-arenites suffered only incipient anatexis and became dehydration granulites. The various rock types display an overall relatively low K/Rb ratio due mainly to the stability of K- and Rb-retaining phases. A weighted mean composition of the fragment of the lower continental crust outcropping in the Serre has been established by integrating the chemical data for metasediments (55 analyses), metabasites (92 analyses) and dioritic and tonalitic gneisses (10 analyses) with the field data. This composition compared to the compositions of the bulk continental crust and of other sections considered as belonging to the lower crust, confirms the hypothesis that (1) the lower crust is heterogeneous, and (2) it is more basic than the continental crust.     

Integrating airborne and multi‐temporal long‐range terrestrial laser scanning with total station measurements for mapping and monitoring a compound slow moving rock slide

A slow moving compound rock slide located in the northern Apennines of Italy was mapped and monitored through the integration of Airborne Laser Scanning (ALS), multi‐temporal long‐range Terrestrial Laser Scanning (TLS), and Automated Total Station (ATS) measurements. Landslide features were mapped using a High Resolution Digital Terrain Model (HR‐DTM) obtained by merging ALS and TLS data in an Iterative Closest Point (ICP) procedure. Slope movements in the order of centimeters to a few decimeters were quantified with Differential TLS (D‐TLS) based on a Surface Matching approach and supported by ATS data to define stable reference surfaces. The integrated approach allowed mapping of the composite geomorphic features of the rock slide under examination, revealing its complex dynamic nature and further proving that laser scanning is a versatile and widely applicable tool for slope process analysis. Copyright © 2013 John Wiley & Sons, Ltd.     

Consequences of a freshwater canal discharge on the benthic community and its habitat on an exposed sandy beach

This paper analyses the spatial and temporal effects of a freshwater discharge (Canal Andreoni) on the macroinfauna community and its habitat in a sandy beach of Uruguay. Bimonthly, we examined 17 environmental variables plus macroinfauna abundance, biomass, richness, evenness and diversity of three sites: Andreoni, at the canal mouth, Coronilla, at 1 km, and Barra, at 13 km from the mouth. Both univariate and multivariate techniques showed an increasing degree of perturbation towards the canal. This was reflected by abiotic and biotic differences between sites and by a consistent two-dimensional ordination of the samples. A clear seasonal pattern was found, specially accentuated at Coronilla, where the effects of the canal were stronger in winter and weaker in summer. Multivariate linking between macroinfauna and its habitat highlighted the role of salinity as explanatory variable of the observed trends.