Triassic Nb-enriched basalts, magnesian andesites, and adakites of the Qiangtang terrane (Central Tibet): evidence for metasomatism by slab-derived melts in the mantle wedge

New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized by high Sr/Y (25–45), La/Yb (14–42) and Na₂O/K₂O (12–49) ratios, high Al₂O₃ (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and ε_ND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive ε_ND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids. A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite. The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series” recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane.     

翅碱蓬(Suaeda heteroptera)根际与非根际沉积物常见重金属总量及化学形态变化

原子吸收光谱法和等离子光谱法分别研究了潮滩盐沼植物翅碱蓬(Suaedaheterop-tera)根际与非根际(根上部和根下部)沉积物中Cu、Zn、Pb和Cd的总量和化学形态。结果表明,从总量来看,不同潮滩沉积物中4种重金属次序均为Zn>Pb>Cu>Cd,但同一元素随潮滩位置变化明显,尤以中潮滩差异最显著,重金属总量明显大于其他两个潮滩(低潮滩和高潮滩),特别是根际沉积物中的重金属总量远高于非根际沉积物总量,其比值分别为Cu3·4—4·2倍,Zn2·2—2·7倍,Pb3·2—3·3倍。同一潮滩均表现为根际沉积物>根上部>根下部。Cd含量相对较低,其变化不明显。从化学形态看,沉积物重金属表现为环境直接影响态(交换态和有机结合态)、环境间接影响态(碳酸盐态和铁锰氧化物态)和稳定态(残渣态)。与非根际沉积物相比,根际沉积物中重金属的化学形态发生了显著的变化,Cu和Pb以稳定态为主,其次为环境间接影响态,环境直接影响态最低;Zn与上述2种金属不同,以环境直接影响态含量最高(可交换态是有机结合态的7倍),其次分别为环境间接影响态(主要是碳酸盐结合态)和稳定态。实验结果表明,由于特异根圈效应,一方面该植物使可迁移形态的Cu和Pb在根际逐步得到矿化,使其生物可利用性降低;另一方面使Zn的生物可利用性提高,促进了植物对Zn的吸收利用。     

冲绳海槽西北侧表层沉积物中微型腹足类的分布及其研究意义

冲绳海槽西北侧大陆架向大陆坡转折处表层沉积物中微型腹足类动物群具有混合的生态特征,这与现代海洋沉积环境并不一致。腹足类动物群中除少数种类为陆坡深海分子,多数种类属内陆架区或近岸浅水分子。因此,动物群主要反映了晚更新世末次冰期低海平面的海洋环境,而少数深海种类的混入应与黑潮暖流在冲绳北端所形成的上升流有关。根据本区腹足类在其他海区的时空分布规律,本文认为在更新世末次冰期,黑潮暖流仍对本区有重要影响，并控制着腹足类的分布。本区腹足类这种混合的生态特征是晚更新世末次冰期以来各种海洋动力环境叠加影响的结果。     

频率域电磁法中视电阻率全区定义

视电阻率定义在电法勘探中得到广泛的应用。目前在频率域电磁法中常常采用远区视电阻率定义。由于在频率域中收发距并非足够大,以致在低频段远区定义视电阻率往往不能反映地下电阻率值。我们定义全区电阻率及引入校正系数K,经二层三层模型及野外实测资料的计算,证明了方法的有效性。     

井中激电地-井方式井旁球体正反演

以激发极化法中的地-井方式中的体极化球形体作为研究对象,采用解析法对地下半空间的电位场进行求解,利用提取出的井中二次场异常电位差进行反演,得出极化球体的球心离井的距离和球心的埋深。通过计算机进行正反演模拟,验证了进行正反演计算的解析式的正确性,并从物理意义上对正反演过程中出现的现象进行分析。最后给出该方法的适用条件以及注意事项。研究对激发极化法地下勘探目标的定量分析具有明确意义。     

GNSS three carrier ambiguity resolution using ionosphere-reduced virtual signals

This paper presents a general modeling strategy for ambiguity resolution (AR) and position estimation (PE) using three or more phase-based ranging signals from a global navigation satellite system (GNSS). The proposed strategy will identify three best “virtual” signals to allow for more reliable AR under certain observational conditions characterized by ionospheric and tropospheric delay variability, level of phase noise and orbit accuracy. The selected virtual signals suffer from minimal or relatively low ionospheric effects, and thus are known as ionosphere-reduced virtual signals. As a result, the ionospheric parameters in the geometry-based observational models can be eliminated for long baselines, typically those of length tens to hundreds of kilometres. The proposed modeling comprises three major steps. Step 1 is the geometry-free determination of the extra-widelane (EWL) formed between the two closest L-band carrier measurements, directly from the two corresponding code measurements. Step 2 forms the second EWL signal and resolves the integer ambiguity with a geometry-based estimator alone or together with the first EWL. This is followed by a procedure to correct for the first-order ionospheric delay using the two ambiguity-fixed widelane (WL) signals derived from the integer-fixed EWL signals. Step 3 finds an independent narrow-lane (NL) signal, which is used together with a refined WL to resolve NL ambiguity with geometry-based integer estimation and search algorithms. As a result, the above two AR processes performed with WL/NL and EWL/WL signals respectively, either in sequence or in parallel, can support real time kinematic (RTK) positioning over baselines of tens to hundreds of kilometres, thus enabling centimetre-to-decimentre positioning at the local, regional and even global scales in the future.     

高精度GPS形变监测网数据处理的理论与方法

分析了高精度GPS形变监测网数据处理中系统误差的影响,给出了顾及系统误差影响的自由网平差模型;针对粗差在GPS观测数据中存在的广泛性,在对平差模型进行整体性检验的基础上,采用检验方法消除粗差对平差结果的影响;结合抗差估计,对中国地壳运动观测网络工程1999～2003年观测数据进行了处理,验证了模型的精度和可靠性.     

饱和软土压缩曲线的“反常”现象

饱和软土压缩试验时,经常出现压缩曲线“反常”、压缩系数“倒大”的现象。它是土的原始结构发生破坏前后的不同压缩性的客观反映。饱和软土的结构力很微弱,唯质量好的原状土才能见到这种“反常”。应从成孔、取样、测试及资料整理等多个环节保证其工程意义。     

黄河影响下开封城市的历史演变

河流对城市的形成和发展起着重要的作用,古人形象地把其比喻为“城市之血脉”。文章从不同的历史时期黄河及其分支对开封城市演变的影响进行分析,得出黄河与开封城市的关系存在着利与害的统一。开封城市的历史发展,即得益于黄河充足的水源,又受害于其频繁的决溢、泛滥、改道。因此,要采用先进的科学技术对黄河进行综合治理开发,使其恢复它应有的美好环境,更好地造福于人民。     

An electrochemical study of pyrite oxidation in the presence of carbon coatings in cyanide medium

The anodic and cathodic behaviour of pyrite with clay and different carbon coatings of activated carbon, graphite and carbonaceous matter in cyanide medium was investigated using the potentiodynamic method. The presence of clay coating did not change the polarisation curve appearance for either the anodic oxidation of pyrite or the cathodic reduction of oxygen or the potential of the current plateau, but only decreased the plateau current especially at a higher coating thickness. The presence of the carbon coatings marginally shifted the rest potential for pyrite to a more anodic position and slightly changed the polarisation curve appearance for pyrite oxidation. The current density for pyrite oxidation largely increased in the presence of the carbon coatings, the potential at the plateau shifted to more cathodic positions, and the plateau width became smaller. These effects became more noticeable at a higher coating thickness. The activated carbon, graphite and carbonaceous matter coatings performed similarly in affecting pyrite oxidation at a similar thickness. The carbon coatings significantly increased the limiting current densities for oxygen reduction on pyrite, and the limiting current plateau became steeper at a higher coating thickness. The carbon coatings increased the limiting current density for oxygen reduction to a similar extent at a low coating thickness, but increased to varied extents at a higher coating thickness. The carbon coatings also greatly increased the cathodic current density for gold reduction on pyrite. The enhancement of pyrite oxidation and oxygen or gold reduction on pyrite by the carbon coatings was likely attributed to the electrochemical interaction between pyrite and the carbon materials with electron-rich surfaces and high conductivity. The presence of the carbon coatings significantly increased the oxidation of pyrite in aerated cyanide solutions and the preg-robbing of pyrite especially at a higher coating thickness.