High pressure experimental calibration of the olivine-orthopyroxene-spinel oxygen geobarometer: implications for the oxidation state of the upper mantle

Synthetic spinel harzburgite and lherzolite assemblages were equilibrated between 1040 and 1300° C and 0.3 to 2.7 GPa, under controlled oxygen fugacity (f _{O 2}). f _{O 2} was buffered with conventional and open double-capsule techniques, using the Fe−FeO, WC-WO₂-C, Ni−NiO, and Fe₃O₄−Fe₂O₃ buffers, and graphite, olivine, and PdAg alloys as sample containers. Experiments were carried out in a piston-cylinder apparatus under fluid-excess conditions. Within the P-T-X range of the experiments, the redox ratio Fe³⁺/ΣFe in spinel is a linear function of f _{O 2} (0.02 at IW, 0.1 at WCO, 0.25 at NNO, and 0.75 at MH). It is independent of temperature at given Δlog(f _{O 2}), but decreases slightly with increasing Cr content in spinel. The Fe³⁺/ΣFe ratio falls with increasing pressure at given Δlog(f _{O 2}), consistent with a pressure correction based on partial molar volume data. At a specific temperature, degree of melting and bulk composition, the Cr/(Cr+Al) ratio of a spinel rises with increasing f _{O 2}. A linear least-squares fit to the experimental data gives the semi-empirical oxygen barometer in terms of divergence from the fayalite-magnetite-quartz (FMQ) buffer:

Diel stream geochemistry,Taylor Valley,Antarctica

Unlike temperate and polythermal proglacial streams, the proglacial streams in Taylor Valley (TV), Antarctica, are derived primarily from glacier surface melt with no subglacial or groundwater additions. Solute responses to flow reflect only the interaction of glacial meltwater with the valley floor surrounding the stream channel. We have investigated the major, minor and trace element 24‐h variations of two proglacial melt streams, Andersen Creek and Canada Stream, originating from the Canada Glacier in TV, Antarctica. Both streams exhibited diel mid‐austral summer diurnal flow variation, with maximum flow being more than 50 times the minimum flow. Dissolved (< 0.4 µm) major, minor and trace solute behaviors through diel periods were strongly controlled by the availability of readily solubilized material on the valley floor and hyporheic‐biological exchanges. Anderson Creek had generally greater solute concentrations than Canada Stream because of its greater receipt of eolian sediment. Andersen Creek also acquired greater solute concentrations in the rising limb of the hydrograph than the falling limb because of dissolution of eolian material at the surface of the stream channel coupled with minimal hyporheic‐biological exchange. Conversely, Canada Stream had less available eolian sediment, but a greater hyporheic‐biological exchange, which preferentially removed trace and major solutes in the rising limb and released them in the falling limb. Given the dynamic nature of discharge, eolian, and hyporheic‐biological processes, solute loads in TV streams are difficult to predict. Copyright © 2012 John Wiley & Sons, Ltd.     

Towards a Digital Earth: using archetypes to enable knowledge interoperability within geo-observational sensor systems design

Earth System Science (ESS) observational data are often inadequately semantically enriched by geo-observational information systems to capture the true meaning of the associated data sets. Data models underpinning these information systems are often too rigid in their data representation to allow for the ever-changing and evolving nature of ESS domain concepts. This impoverished approach to observational data representation reduces the ability of multi-disciplinary practitioners to share information in a computable way. Object oriented techniques that are typically employed to model data in a complex domain (with evolving domain concepts) can unnecessarily exclude domain specialists from the design process, invariably leading to a mismatch between the needs of the domain specialists, and how the concepts are modelled. In many cases, an over simplification of the domain concept is captured by the computer scientist. This paper proposes that two-level modelling methodologies developed by health informaticians to tackle problems of domain specific use-case knowledge modelling can be re-used within ESS informatics. A translational approach to enable a two-level modelling process within geo-observational sensor systems design is described. We show how the Open Geospatial Consortium’s (OGC) Observations & Measurements (O&M) standard can act as a pragmatic solution for a stable reference-model (necessary for two-level modelling), and upon which more volatile domain specific concepts can be defined and managed using archetypes. A rudimentary use-case is presented, followed by a worked example showing the implementation methodology and considerations leading to an O&M based, two-level modelling design approach, to realise semantically rich and interoperable Earth System Science based geo-observational sensor systems.     

Sulfate reduction and the nature of organic matter in estuarine sediments

The reduction of sulfate by sulfate reducing bacteria in the anoxic zone is an extremely important process during early diagenesis of marine sediments. Our data from Great Bay, NH reinforce the proposal that the rate of sulfate reduction is directly proportional to the reactivity of the organic matter or the amount of readily metabolizable organic matter present in the sediment and, hence, the source of the organic material in the anoxic zone. It appears that organic matter rich in marine organic remains is more easily degraded in the anoxic zone and that sulfate reduction rates can vary considerably in an estuarine system where many types of organic material may be deposited.     

Structure of the crust and upper mantle in Canada

The seismic probing of the crust and upper mantle in Canada started in 1938 and since then has involved many government and university groups using a wide variety of techniques. These have included simple profiling with both wide and narrow station spacing, areal time-term surveys, detailed deep reflection experiments, very long-range refraction studies and the analysis of surface wave dispersion between stations of the Canadian Standard Network.

A review of the published interpretation leads to the general conclusion that:

1. (1) P_n-velocities vary from a value possibly as low as 7.7 km/sec under Vancouver Island to 8.6 km/sec and higher in the extreme eastern part of the shield and some parts of the Atlantic coast.

2. (2) Large areas of Canada have a crustal thickness of 30–40 km, with Vancouver Island, the southwestern Prairies, the Lake Superior basin and parts of the eastern shield of Quebec being thicker. No continental area in Canada is known to have a crust thinner than 29 km.

3. (3) The Riel discontinuity — a deep intra-crustal reflector and sometime refractor, is widely reported in the Prairies and Manitoba. It is not seen to the north in the vicinity of Great Slave Lake, nor in the Hudson Bay, Lake Superior and Maritime regions, nor in the interior of British Columbia. It may be present in some areas of the eastern shield.

4. (4) As experiments have become more detailed, crustal structures of greater complexity have been revealed. The concept that crustal structure becomes simpler with increasing depth is apparently unfounded.

Long-range refraction studies suggest that the Gutenberg P-wave low-velocity channel is poorly developed under the Canadian Shield. The analysis of the dispersion of surface waves, however, suggests that the channel is better developed for S-waves, and is present throughout the country. The lid of the channel is deepest under the central shield and shallowest under the Cordillera.     

The Cambrian metamorphic history of Tasmania: The Metapelites

The metamorphic complexes of Tasmania formed during the Cambrian (ca 510 Ma) as a result of rapid compression in a subduction zone setting followed by rapid exhumation, which brought various fault-bounded metamorphic complexes back to the surface in less than 5 Ma. The two highest grade complexes, the Franklin Metamorphic Complex, and the Port Davey Metamorphic Complex, experienced initial growth of metamorphic garnets at ～560°C, ～0.56 GPa. However, their subsequent metamorphic histories diverge, with the FMC displaying a marked increase in pressure (to 1.4 GPa at peak P/T), while the PDMC shows only a slight increase in pressure (to ～0.7 GPa). Both complexes show only a minor increase in temperature (～100°C) between initial garnet growth and peak metamorphic conditions. Rapid exhumation of these complexes can be accounted for by a slab-breakoff model. However, the difference in peak pressure between these complexes requires either continued subduction of the FMC while the PDMC had already begun its return towards the surface or that the subduction zone geometry resulted in significantly different pressures occurring contemporaneously within portions of the channel, which are not far removed from one another.     

The distributions of particulate atmospheric trace metals and mineral aerosols over the Indian Ocean

Data are presented for the concentrations of Al, Fe, Mn, Ni, Co, Cr, V, Cu, Zn, Pb and Cd in aerosols collected over two contrasting regions of the Indian Ocean. These are: (1) the northern Arabian Sea (AS), from which samples were collected in the northeast monsoon, during which the region receives an input of crustal material from the surrounding arid land masses; and (2) the Tropical Southern Indian Ocean (TSIO), a remote region from which samples were collected from air masses for which there were no large-scale up-wind continental aerosol sources. The TSIO samples can be divided into two populations: Population I aerosols, collected from air masses which have probably impinged on Madagascar, and Population II aerosols, which have been confined to open-ocean regions to the south of the area.The data indicate that there are strong latitudinal variations in the chemical signatures of aerosols over the Indian Ocean. The input of crustal material to the Arabian Sea gives rise to an average Al concentration of about 1000 ng m⁻³ of air in the northeast monsoon regime. As a result, the concentrations of all trace metals are relatively high, and the values of crustal enrichment factors are less than 10 for most metals, in the AS aerosols. In contrast, TSIO Population II ‘open-ocean southern air’ sampled during the southwest monsoon season, has an average Al concentration of only about 10 ng m⁻³ of air. Trace metal concentrations in the TSIO ‘open-ocean southern air’ during the southwest monsoon season are representative of ‘clean’ remote marine air and are generally similar to those reported over the central North Pacific.Mineral dust concentrations over the Indian Ocean decrease in a north to south direction, from about 15–20 μg m⁻³ of air in the extreme north to about 0.01–0.25 μg m⁻³ of air in the far south. The deposition of mineral dust over the northern Arabian Sea can account for approximately 75% of the non-carbonate material incorporated into the underlying sediments.In the Arabian Sea the dissolved atmospheric inputs of all the trace metals, with the exception of Cu and Co, exceed those from fluvial run-off by factors which range from 9.6 for Pb to 1.6 for Cr.     

锦州湾沾污沉积物急性毒性的海洋端足类检验

１９９２年９月￣１９９３年１月对锦州湾沾污沉积物的海洋端足类急性毒性效应进行了研究。从锦州湾湾顶到湾口沿西南－－东北方向每２ｋｍ等距离采集２７个表层沉积我校 品,应用海洋端足类Ａ ｍｐｅｌｉｓｃａ ａｂｄｉｔａ对这些样品进行了１０ｄ直流式急性毒性检验,检验指标为死亡率。结果表明,五里河河口处受试生物死亡率最高,为１００％,从湾顶该河口处沿东北方向随着距离增加,死亡率逐渐递减,笔架山处最低,仅为２．     

Thermodynamic controls on element partitioning between titanomagnetite and andesitic–dacitic silicate melts

Titanomagnetite–melt partitioning of Mg, Mn, Al, Ti, Sc, V, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Hf and Ta was investigated experimentally as a function of oxygen fugacity (fO₂) and temperature (T) in an andesitic–dacitic bulk-chemical compositional range. In these bulk systems, at constant T, there are strong increases in the titanomagnetite–melt partitioning of the divalent cations (Mg²⁺, Mn²⁺, Co²⁺, Ni²⁺, Zn²⁺) and Cu²⁺/Cu⁺ with increasing fO₂ between 0.2 and 3.7 log units above the fayalite–magnetite–quartz buffer. This is attributed to a coupling between magnetite crystallisation and melt composition. Although melt structure has been invoked to explain the patterns of mineral–melt partitioning of divalent cations, a more rigorous justification of magnetite–melt partitioning can be derived from thermodynamic principles, which accounts for much of the supposed influence ascribed to melt structure. The presence of magnetite-rich spinel in equilibrium with melt over a range of fO₂ implies a reciprocal relationship between a(Fe²⁺O) and a(Fe³⁺O_1.5) in the melt. We show that this relationship accounts for the observed dependence of titanomagnetite–melt partitioning of divalent cations with fO₂ in magnetite-rich spinel. As a result of this, titanomagnetite–melt partitioning of divalent cations is indirectly sensitive to changes in fO₂ in silicic, but less so in mafic bulk systems.     

Decadal‐Scale Changes of the Ödenwinkelkees,Central Austria,Suggest Increasing Control of Topography and Evolution Towards Steady State

Small mountain glaciers have short mass balance response times to climate change and are consequently very important for short‐term contributions to sea level. However, a distinct research and knowledge gap exists between (1) wider regional studies that produce overview patterns and trends in glacier changes, and (2) in situ local scale studies that emphasise spatial heterogeneity and complexity in glacier responses to climate. This study of a small glacier in central Austria presents a spatiotemporally detailed analysis of changes in glacier geometry and changes in glaciological behaviour. It integrates geomorphological surveys, historical maps, aerial photographs, airborne LiDAR data, ground‐based differential global positioning surveys and Ground Penetrating Radar surveys to produce three‐dimensional glacier geometry at 13 time increments spanning from 1850 to 2013. Glacier length, area and volume parameters all generally showed reductions with time. The glacier equilibrium line altitude increased by 90 m between 1850 and 2008. Calculations of the mean bed shear stress rapidly approaching less than 100 kPA, of the volume–area ratio fast approaching 1.458, and comparison of the geometric reconstructions with a 1D theoretical model could together be interpreted to suggest evolution of the glacier geometry towards steady state. If the present linear trend in declining ice volume continues, then the Ödenwinkelkees will disappear by the year 2040, but we conceptualise that non‐linear effects of bed overdeepenings on ice dynamics, of supraglacial debris cover on the surface energy balance, and of local topographically driven controls, namely wind‐redistributed snow deposition, avalanching and solar shading, will become proportionally more important factors in the glacier net balance.