Luminescence dating of sand–loess sequences and response of Mu Us and Otindag sand fields (north China) to climatic changes

The sand–loess transition zone in north China is sensitive to climate change, and is an ideal place to investigate past environmental changes. However, past climate change at millennial–centennial timescales in this region has not been well reconstructed because of limited numerical dating. Alternations of sandy loam soils with aeolian sand layers in the Mu Us and Otindag sand fields, which lie along the sand–loess transition zone, indicate multiple intervals of dune activity and stability. This change is probably a response to variations of the East Asian monsoon climate during the late Quaternary. The single aliquot regeneration (SAR) optically stimulated luminescence (OSL) dating protocol, which has been successfully applied to aeolian deposits worldwide, is applied to these two sand fields in this study. The OSL ages provide reliable constraints for reconstruction of past climate changes at suborbital timescale. Sections in both sand fields contain aeolian sand beds recording millennial‐scale episodes of dry climate and widespread dune activation, including episodes at about the same time as Heinrich Event 5 and the Younger Dryas in the North Atlantic region. These results demonstrate the potential of aeolian sediments in semi‐arid north China to record millennial‐scale climatic events, and also suggest that dry–wet climate variation at the desert margin in China may be linked to climatic change elsewhere in the Northern Hemisphere, through atmospheric circulation. This article was published online on 27 November 2008. An error was subsequently identified. This notice is included in the online and print versions to indicate that both have been corrected (16 December 2008). Copyright © 2008 John Wiley & Sons, Ltd.     

An ocean-bottom hydrophone recorder for seismic refraction experiments

A new and inexpensive pop-up ocean-bottom hydrophone recorder has been developed for use in seismic refraction experiments. It is capable of operating in water depths of up to 4000 m and in very rugged topography, and uses an acoustic command system built by the U.K. Institute of Oceanographic Sciences for recovery. The instrument is mounted in an inexpensive cylindrical pressure case based on commercially available extruded aluminium alloy tubing, and uses glass spheres and syntactic foam for buoyancy. Hydrophone and clock signals are frequency modulated and recorded on tape cassettes, with a recording duration of three hours allowing up to 18 programmed shot windows. The prototype has made seven free descents on the Mid-Atlantic ridge and in the Gulf of Oman, and successfully recorded shots under operational conditions for the first time in September 1979. The total component cost of the prototype was £2740 (1979 prices).(Department of Earth Sciences, University of Cambridge Contribution No. ES135).     

Surface-layer flow in complex terrain: Comparison of models and full-scale observations

Four models of surface boundary-layer flow in complex terrain are compared with observations made at Blashaval Hill, North Uist, Scotland. The field experiment is described by Mason and King (1985). Three of the models are derived from the two-dimensional theory of Jackson and Hunt (1975) and are described in Mason and King (1985), Walmsley et al. (1986) and Troen and Petersen (1989). The fourth is a mass-consistent code based on Traci et al. (1979). The model results are in good agreement with each other and are generally within the observed range of variation ( ~ ± 16%) in normalized wind speed. For most wind direcions (7 of 11), model results of normalized wind speed at the summit were within 7% of the observed mean values. For some wind directions, calculations using the Guidelines of Walmsley et al. (1989) suggested that variations in surface roughness were important. This led us to apply one of our models incorporating nonuniform surface roughness. The lack of significant improvement for cases when water lay upstream of Blashaval Hill is attributed to compensating changes at summit and reference sites and to very local effects on the wind data. Sensitivity to topography lying to the west and northwest of Blashaval was also investigated. Results suggested an influence from those distant topographic features for some wind directions. When those features were incorporated, maximum errors in normalized wind speed at the summit were reduced from 18 to 13%.     

Holocene climate variability in Sicily from a discontinuous stalagmite record and the Mesolithic to Neolithic transition

Fabric and stable isotopic composition of a Holocene stalagmite (CR1) from a cave in northern Sicily record changes in paleorainfall in the early Holocene. High δ¹³C stable isotope values in the calcite deposited from ca. 8500 to ca. 7500 yr ago are interpreted as reflecting periods of high rainfall. The wet phase was interrupted by two periods of multi-century duration characterized by relatively cool and dry winters centered at ca. 8200 and ca. 7500 yr ago, highlighted by low δ¹³C and δ¹⁸O values. A high variability of δ¹³C values is recorded from ca. 7500 to ca. 6500 yr ago and indicates that the transition from a pluvial early Holocene to the present-day climate conditions was punctuated by decadal-scale periods of relatively dry winters. In northern Sicily, the traditional elements of the Neolithic appear at ca. 7700 yr ago. It is possible that changes in rainfall influenced the passage from hunter-gathering to farming and sheep-herding economies.     

Site Effects Study in the Serravalle Village (NE Italy) by Means of Spectral Ratios Analyses Relatively to Multiple Reference Sites

The area of Serravalle, sited in the northern part of the town of Vittorio Veneto (TV), NE Italy, has been the target of a seismic microzonation campaign. 10 seismic stations have been deployed for a 7 months period to record in continuous mode. Three stations were installed on bedrock outcrops and seven on sedimentary sites with variable cover thickness. Spectral analyses have been performed on the collected data-set using the Generalized Inversion Technique (GIT, e.g. Andrews, 1986). In particular, spectral ratios have been calculated for each station relatively to the average of the three reference, bedrock sites. The spectral ratios provide quantitative estimates of the seismic motion amplifications which occur in each of the monitored sites. Two sites show high values of amplification, 5 times larger than signal amplitude at the reference sites, in correspondence of well discernible peak frequencies of 5 Hz. Results for the other stations show smaller amounts of site amplification spreading over a broad range of frequencies. Sites where the highest amplifications were recorded all lie on the left bank of the Meschio River and in areas farther away from its outlet into the plain correlating with the presence of thick layers of Quaternary deposits.     

Validation of Landslide Susceptibility Maps; Examples and Applications from a Case Study in Northern Spain

A procedure for validating landslide susceptibility maps wasapplied in a study area in northern Spain and the results obtained compared. Validationwas used to carry out sensitivity analysis for individual variables and combinationsof variables. The validity of different map-making methods was tested, as well as theutility of different types of Favourability Functions. The results obtained show thatvalidation is essential to determine the predictive value of susceptibility maps. Italso helps to better select the most suitable function and significant variables, thus improving the efficiency of the mapping process. Validation based on a temporal strategy makes it possible to derive hazard maps from susceptibility maps.     

Global occurrence of tellurium-rich ferromanganese crusts and a model for the enrichment of tellurium

Hydrogenetic ferromanganese oxyhydroxide crusts (Fe-Mn crusts) precipitate out of cold ambient ocean water onto hard-rock surfaces (seamounts, plateaus, ridges) at water depths of about 400 to 4000 m throughout the ocean basins. The slow-growing (mm/Ma) Fe-Mn crusts concentrate most elements above their mean concentration in the Earth’s crust. Tellurium is enriched more than any other element (up to about 50,000 times) relative to its Earth’s crustal mean of about 1 ppb, compared with 250 times for the next most enriched element.We analyzed the Te contents for a suite of 105 bulk hydrogenetic crusts and 140 individual crust layers from the global ocean. For comparison, we analyzed 10 hydrothermal stratabound Mn-oxide samples collected from a variety of tectonic environments in the Pacific. In the Fe-Mn crust samples, Te varies from 3 to 205 ppm, with mean contents for Pacific and Atlantic samples of about 50 ppm and a mean of 39 ppm for Indian crust samples. Hydrothermal Mn samples have Te contents that range from 0.06 to 1 ppm. Continental margin Fe-Mn crusts have lower Te contents than open-ocean crusts, which is the result of dilution by detrital phases and differences in growth rates of the hydrogenetic phases.Correlation coefficient matrices show that for hydrothermal deposits, Te has positive correlations with elements characteristic of detrital minerals. In contrast, Te in open-ocean Fe-Mn crusts usually correlates with elements characteristic of the MnO₂, carbonate fluorapatite, and residual biogenic phases. In continental margin crusts, Te also correlates with FeOOH associated elements. In addition, Te is negatively correlated with water depth of occurrence and positively correlated with crust thickness. Q-mode factor analyses support these relationships. However, sequential leaching results show that most of the Te is associated with FeOOH in Fe-Mn crusts and ≤10% is leached with the MnO₂.Thermodynamic calculations indicate that Te occurs predominantly as H₅TeO₆⁻ in ocean water. The speciation of Te in ocean water and charge balance considerations indicate that Te should be scavenged by FeOOH, which is in agreement with our leaching results. The thermodynamically more stable Te(IV) is less abundant by factors of 2 to 3.5 than Te(VI) in ocean water. This can be explained by preferential (not exclusive) scavenging of Te(IV) by FeOOH at the Fe-Mn crust surface and by Fe-Mn colloids in the water column. We propose a model in which the extreme enrichment of Te in Fe-Mn crusts is likely the result of an oxidation reaction on the surface of FeOOH. A similar oxidation process has been confirmed for Co, Ce, and Tl at the surface of MnO₂ in crusts, but has not been suggested previously to occur in association with FeOOH in Fe-Mn crusts. Mass-balance considerations indicate that ocean floor Fe-Mn deposits are the major sink for Te in the oceans. The concentration and redox chemistry of Te in the global ocean are likely controlled by scavenging on Fe-Mn colloids in the water column and Fe-Mn deposits on the ocean floor, as is also the case for Ce.     

International greenhouse gas inventory systems: A comparison between CORINAIR and IPCC methodologies in the EU

There are several different approaches currently taken by the 15 EU countries in compiling their IPCC inventories for the FCCC. Six countries (France, Ireland, Italy, Luxembourg, Portugal, Spain) use the CORINAIR system and then aggregate and reformat the data into the required IPCC format. Of the remaining countries, two strictly follow the IPCC methodology (Finland and Greece), five (Denmark, Germany, Netherlands, Sweden, United Kingdom) estimate emissions using a combination of national and IPCC methodologies, while the final two (Austria and Belgium) use a combination of national and CORINAIR methodologies (transformed to IPCC). Comparison of the national inventories in both the IPCC and CORINAIR formats shos some revealing discrepancies between the two systems at both sector and gas level that by chance cancel out when aggregated at the EU level.     

Chemical and isotopic equilibrium between CO2 and CH4 in fumarolic gas discharges: Generation of CH4 in arc magmatic-hydrothermal systems

The chemical and isotopic composition of fumarolic gases emitted from Nisyros Volcano, Greece, and of a single gas sample from Vesuvio, Italy, was investigated in order to determine the origin of methane (CH₄) within two subduction-related magmatic-hydrothermal environments.Apparent temperatures derived from carbon isotope partitioning between CH₄ and CO₂ of around 340°C for Nisyros and 470°C for Vesuvio correlate well with aquifer temperatures as measured directly and/or inferred from compositional data using the H₂O-H₂-CO₂-CO-CH₄ geothermometer. Thermodynamic modeling reveals chemical equilibrium between CH₄, CO₂ and H₂O implying that carbon isotope partitioning between CO₂ and CH₄ in both systems is controlled by aquifer temperature.N₂/³He and CH₄/³He ratios of Nisyros fumarolic gases are unusually low for subduction zone gases and correspond to those of midoceanic ridge environments. Accordingly, CH₄ may have been primarily generated through the reduction of CO₂ by H₂ in the absence of any organic matter following a Fischer-Tropsch-type reaction. However, primary occurrence of minor amounts of thermogenic CH₄ and subsequent re-equilibration with co-existing CO₂ cannot be ruled out entirely. CO₂/³He ratios and δ¹³C_CO2 values imply that the evolved CO₂ either derives from a metasomatized mantle or is a mixture between two components, one outgassing from an unaltered mantle and the other released by thermal breakdown of marine carbonates. The latter may contain traces of organic matter possibly decomposing to CH₄ during thermometamorphism.