Presolar spinel grains from the Murray and Murchison carbonaceous chondrites

With a new type of ion microprobe, the NanoSIMS, we determined the oxygen isotopic compositions of small (<1μm) oxide grains in chemical separates from two CM2 carbonaceous meteorites, Murray and Murchison. Among 628 grains from Murray separate CF (mean diameter 0.15 μm) we discovered 15 presolar spinel and 3 presolar corundum grains, among 753 grains from Murray separate CG (mean diameter 0.45 μm) 9 presolar spinel grains, and among 473 grains from Murchison separate KIE (mean diameter 0.5 μm) 2 presolar spinel and 4 presolar corundum grains. The abundance of presolar spinel is highest (2.4%) in the smallest size fraction. The total abundance in the whole meteorite is at least 1 ppm, which makes spinel the third-most abundant presolar grain species after nanodiamonds (if indeed a significant fraction of them are presolar) and silicon carbide. The O-isotopic distribution of the spinel grains is very similar to that of presolar corundum, the only statistically significant difference being that there is a larger fraction of corundum grains with large ¹⁷O excesses (¹⁷O/¹⁶O > 1.5 × 10⁻³), which indicates parent stars with masses between 1.8 and 4.5 M_⊙.     

Image processing of 2D resistivity data for imaging faults

A methodology to locate automatically limits or boundaries between different geological bodies in 2D electrical tomography is proposed, using a crest line extraction process in gradient images. This method is applied on several synthetic models and on field data set acquired on three experimental sites during the European project PALEOSIS where trenches were dug. The results presented in this work are valid for electrical tomographies data collected with a Wenner-alpha array and computed with an l₁ norm (blocky inversion) as optimization method. For the synthetic cases, three geometric contexts are modelled: a vertical and a dipping fault juxtaposing two different geological formations and a step-like structure. A superficial layer can cover each geological structure. In these three situations, the method locates the synthetic faults and layer boundaries, and determines fault displacement but with several limitations. The estimated fault positions correlate exactly with the synthetic ones if a conductive (or no superficial) layer overlies the studied structure. When a resistive layer with a thickness of 6 m covers the model, faults are positioned with a maximum error of 1 m. Moreover, when a resistive and/or a thick top layer is present, the resolution significantly decreases for the fault displacement estimation (error up to 150%). The tests with the synthetic models for surveys using the Wenner-alpha array indicate that the proposed methodology is best suited to vertical and horizontal contacts. Application of the methodology to real data sets shows that a lateral resistivity contrast of 1:5–1:10 leads to exact faults location. A fault contact with a resistivity contrast of 1:0.75 and overlaid by a resistive layer with a thickness of 1 m gives an error location ranging from 1 to 3 m. Moreover, no result is obtained for a contact with very low contrasts (1:0.85) overlaid by a resistive soil. The method shows poor results when vertical gradients are greater than horizontal ones. This kind of image processing technique should be systematically used for improving the objectiveness of tomography interpretation when looking for limits between geological objects.     

Pumpellyite in Low-grade Metamorphism

The regional metamorphism of the Kant? Mountains in Japan producedrocks of the following facies, with rising temperature: chloritefacies, pumpellyite-chlorite facies, glauco-phane-schist facies,and greenschist facies. This relationship is compared with theprogressive metamorphic zones in other regions where pumpellyitehas been found. Almost similar relations appear to hold in manymetamorphic terrains. Pumpellyites in glaucophanitic metamorphicterrains have, generally, low Fe'/R'R ratios. Physical andchemical conditions responsible for the formation of pumpellyiteare also discussed.     

Fluid inclusion studies of the Abawso gold prospect,near the Ashanti Belt,Ghana

The major Ghanaian lode gold deposits are preferentially aligned along the western and eastern contacts of the Kumasi Basin with the Ashanti and Sefwi Belts, respectively. The investigated area of the Abawso small-scale concession, covering the workings of the old Ettadom mine, is situated 3 km west of the lithological contact of the Birimian metavolcanic rocks of the Akropong Belt in the east with the Birimian metasedimentary rocks of the Kumasi Basin in the west. The rocks of the Abawso concession represent a steeply NW-dipping limb of a SE-verging anticline with an axis plunging to the SW. Quartz veining occurs predominantly in the form of en échelon dilatational veins along NNE–SSW-striking shear zones of a few metres width and shows evidence of brittle and ductile deformation. Also stockwork-style quartz veining occurs in the vicinity of the main shaft of the old Ettadom mine. Hydrothermal alteration includes sericitisation, sulphidation and locally carbonatisation. The auriferous quartz veins mainly follow the trend of brittle to ductile deformed quartz veins; however, some occur in stockwork. Fluid inclusion studies reveal a large number of H₂O inclusions along intragranular trails in auriferous quartz vein samples, as well as an overall dominance of H₂O and H₂O-CO₂ inclusions over CO₂ inclusions. Textural observations and physico-chemical fluid inclusion properties indicate post-entrapment modifications for all quartz vein samples due to grain boundary migration recrystallisation. This process is interpreted to be responsible for the generation of the CO₂ inclusions from a H₂O-CO₂ parent fluid. In comparison with mineralisation at the Ashanti and Prestea deposits, which are characterised by CO₂±N₂ inclusions, the observed inclusion assemblage may be due to a shallower crustal level of mineralisation, or different degrees and styles of recrystallisation, or a less pronounced development of laminated quartz veins due to comparably restricted pressure fluctuations. Furthermore, the microthermometric observations allow the reconstruction of a possible retrograde P-T path, depicting near-isothermal decompression in the P-T range of the brittle/ductile transition.Editorial handling: E. Frimmel     

Kinetics and Equilibrium Sorption Studies of 4-Nitrophenol on pyrolyzed and activated oil shale residue

Sorption of the organic pollutant 4-nitrophenol (4-NP) by pyrolyzed and activated Jordanian oil-shale was studied. Pyrolyzed oil shale was prepared using a fluidized bed reactor at 520 °C in the presence of nitrogen. Physical activation was carried out by treating the pyrolyzed oil shale with CO₂ at 830 °C, while chemical activation was achieved by using KOH and ZnCl₂ as impregnating agents. Batch kinetics and isotherm studies were conducted to evaluate the sorption process. Effects of contact time, initial sorbate concentration, sorbent concentration, temperature, pH and inorganic salts (NaCl and KCl) on the sorption process by the different sorbents were considered. Chemically activated oil shale, pretreated with ZnCl₂, gave the highest uptake of 4-NP. The isotherm experimental data fit reasonably well to Langmuir, Freundlich and Redlich-Paterson models. Three kinetic models, namely the Morris-Weber, Lagergren, and Pseudo-Second-Order model (PSOM), were applied to represent the experimental results for both pyrolyzed and ZnCl₂-oil shale sorbents.     

Investigations and assessment of the landslide hazards of Fengdu county in the reservoir region of the Three Gorges project on the Yangtze River

The spatial database of landslides in Fengdu County of the reservoir region of the Three Gorges project (TGP) on the Yangtze River was compiled from a variety of different sources including field investigations on landslides, existing catalogues and archives on landslides, reports of meteorological events and human engineering activities that triggered slope failures. The major factors that are found to have affected the slope stabilities are outlined, and an assessment and zonation of landslide hazards of the region is made using an integrated information model, which is divided into destructive, disastrous, likely disastrous and essentially non-disastrous areas from the assessment of landslide hazards. The destructive and disastrous areas are respectively 1.9 and 13.8% of the total region, mostly being nearby townships, highways along the south bank of the Yangtze River and residential quarters along two flanks of the Yangtze River and its distributaries, that will impose direct impact to highway transportation and residential lives, and may effect to some degree the navigation of the Yangtze River, reservoir banks, and building of cities and towns.     

Trends in the frequency of synoptic types in central-southern Chile in the period 1961–2012 using the Jenkinson and Collison synoptic classification

Atmospheric circulation patterns in southern Chile (42° 30′ S) were studied in order to determine and analyse the most characteristic synoptic types and their recent trends, as well as to gain an understanding of how they are associated with low-frequency variability patterns. According to the Jenkinson and Collison (J&C) classification method, a 16-point grid of sea-level pressure data was employed. The findings reveal that some synoptic types show statistically significant trends with a 95% confidence level, positively for anticyclonic westerly hybrids (AW) and advective types for third and fourth quadrant wind flows (W, NW, and N) and negatively for SW and cyclonic hybrids (CS and CSW). A model has been constructed of the linear regression of some weather types with teleconnections that most affect Chile: the undetermined types (U), AW were associated with El Niño or the warm phase of the Pacific Decadal Oscillation (PDO), whereas the cyclonic northerly and cyclonic northeasterly types (CN and CNE) were associated with La Niña or cool phase of the PDO. The weather types associated with Antarctic Oscillation (AAO) in its positive phase are anticyclonic northerly and northeasterly and northerly advection types, while in its negative phase are cyclonic southwesterly and advection types.