L波段海水介电模型构建与误差分析

基于实验室测量数据,构建了盐度和温度多项式形式的L波段海水介电模型,并采用最小二乘法和奇异值分解技术求解模型系数。将新模型与目前广泛使用的Klein-Swift(KS)模型、Meissner-Wentz(MW)模型以及George Washington University(GWU)模型进行比较。结果表明：新模型计算的海水介电常数与实验室测量数据的RMSE误差为0.09（实部）和0.25（虚部）,均优于KS、MW、GWU模型。     

太湖表层沉积物多环芳烃的空间分布、来源及其风险

随着太湖流域社会与经济的发展,多环芳烃(PAHs)在各种环境介质中逐渐累积,污染日益严重,可能对太湖生态环境及周边人体健康构成威胁。为探究太湖沉积物PAHs的来源及生态风险,于2021年12月在太湖采集30个表层沉积物样品,利用气相色谱-质谱联用仪(GC-MS)检测样品中16种PAHs含量;利用受体模型和苯并[a]芘(BaP)毒性当量法进行来源解析及生态风险评估,并将各来源贡献与毒性当量浓度相结合,量化源风险。结果表明,太湖表层沉积物中16种PAHs总含量介于124~592 ng/g之间,平均值为294 ng/g,中值为279 ng/g;高环多环芳烃(HMW PAHs)为主要组分,占∑PAHs的67%。高含量区域位于竺山湾、梅梁湾、贡湖湾和西太湖,与国内外其他湖泊沉积物相比,太湖沉积物PAHs含量处于较低水平。源解析的结果表明,太湖表层沉积物中PAHs交通排放源贡献率为29.1%、煤炭燃烧源贡献率为26.7%、生物质燃烧源贡献率为28.7%、石油源贡献率为15.6%。生态风险评价结果表明,交通排放源、生物质燃烧源、煤炭燃烧源和石油源的BaP毒性当量含量(TEQ_BaP)均值分别为19.34、17.81、16.33和9.1 ng/g,均小于70 ng/g,几乎处于无风险水平。西太湖、贡湖湾和梅梁湾的部分区域ΣTEQ_BaP大于70 ng/g属于潜在风险区,具有一定潜在毒性。在后续的污染治理中应重点关注太湖西北部地区污染物的排放。本研究可为沉积物中PAHs污染的研究提供数据支撑,为地方政府精准、高效地管控PAHs污染提供理论依据。     

ANFIS在土地利用变化模拟中的应用

土地利用变化在空间维和时间维上是一个渐进的、不确定的复杂过程,而模糊理论正是解决不确定性现象的一种合适的方法,所以尝试运用模糊推理理论对土地利用变化进行深入的探讨.以江苏省南通市崇川区为研究区,建立了基于自适应神经模糊推理系统(ANFIS)的土地利用变化模糊推理模型.通过利用ANFIS训练获得模型的隶属函数及参数.并运用该模型对研究区进行土地利用变化的模拟和预测.研究结果表明,通过利用ANFIS建立的模型,基本上可以模拟研究区复杂而不确定的土地利用变化过程,同时ANFIS可以有效地简化模糊推理模型结构,使得模型更具灵活性.因此,为土地利用变化模拟提供了另一种可行的解决思路.     

NaCl—H_2O溶液包裹体的密度式和等容式及其应用

由于含盐类包裹体不能应用现有的状态方程求解,作者根据实验数值,采用最小二乘法等,得到含盐度(wt%)≤25的NaCl-H_2O溶液包裹体的密度式和等容式。只要测定出包裹体的均一温度和含盐度,代入密度式,即可计算包裹体中的流体密度。再由此密度、含盐度的等容式,进一步可求得包裹体的形成温度和压力。最后,作者列举了三个实例。     

Antioxidant system responses in two co-occurring green-tide algae under stress conditions

Green tides have occurred every year from 2007 to 2014 in the Yellow Sea. Ulva prolifera(Müller) J. Agardh has been identified as the bloom-forming alga,co-occurring with U. intestinalis. We observed distinct strategies for both algal species during green tides. U. prolifera exhibited a high abundance initially and then decreased dramatically,while U. intestinalis persisted throughout. The antioxidant system responses of these two macroalgae were compared in the late phase of a green tide(in-situ) and after laboratory acclimation. Lipid peroxidation and antioxidant system responses differed significantly between the two. Malondialdehyde and hydrogen peroxide contents increased significantly in-situ in U. prolifera,but not in U. intestinalis. In U. prolifera,we observed a significant decrease in total antioxidant ability(T-AOC),antioxidant enzymes(SOD and Apx),and non-enzyme antioxidants(GSH and As A) in-situ. U. intestinalis showed the same pattern of T-AOC and SOD,but its Gpx,Apx,and GSH responses did not differ significantly. The results suggest that U. prolifera was more susceptible than U. intestinalis to the harsh environmental changes during the late phase of a Yellow Sea green tide. The boom and bust strategy exhibited by U. prolifera and the persistence of U. intestinalis can be explained by differences in enzyme activity and antioxidant systems.     

Objective Analysis on Large-scale Circulation Type and Its Links to Precipitation over China

Atmospheric circulation anomaly is a direct cause of weather and climate change. In the past, most researches for the relationship between Weather Type (WT) and precipitation have mainly focused on the subjective classification and diagnosis. Compared to the subjective analysis, objective classification uses more consistent index and standard unification, thus, we can get more WTs, and it has been widely used in many areas. By using daily 12UTC Sea Level Pressure (SLP), Precipitable Water (PW), and 700 hPa wind speed (UV700) data from ECMWF’s Interim Reanalysis, the classification of WTs over China was performed with the method of obliquely rotated T-mode principle component analysis. WT and its link to precipitation over China were further analyzed. The results show that the influence of different WTs on precipitation is not uniform over China, and also show distinctly difference in different seasons. A common feature is that WTs great impact on the regions and months with large precipitation, while less impact on regions and months have with less precipitation. In addition, precipitation trends originating from WT intensity changes are much more deterministic, significant, and predictable than trends from WT frequency changes.     

漠河盆地西部二十二站组碎屑锆石U-Pb年龄、地球化学特征及其物源意义

大兴安岭北部漠河盆地内广泛发育二十二站组,其形成时代及物质来源一直以来备受争议.本文在野外地质调查及岩相学的基础上,利用碎屑锆石LA-ICP-MS U-Pb法测年,并结合岩石地球化学等方法,探讨了二十二站组形成时代、物源区大地构造环境及沉积物来源.测年结果显示132个测点年龄主要分布在4个群落,分别为508.3～492.3 Ma;486.9～435.5 Ma;278.3～254.2 Ma;209.5～178.1 Ma.本次获得二十二站组最小碎屑锆石年龄为178.1 Ma,并结合漠河盆地东西部碎屑锆石的年龄,综合认为二十二站组形成时代应为中晚侏罗世.地球化学分析结果显示,二十二站组砂岩的稀土元素与活动大陆边缘的稀土元素曲线吻合较好,且相对亏损高场强元素(Nb和Ta)和大离子亲石元素(Ba和Sr),相对富集高场强元素(La、Th、Zr、Hf),地球化学特征与活动大陆边缘相似.综合古流向、源区母岩分析、碎屑锆石测年分析、微量元素特征等诸多因素,本次研究认为本区二十二站组砂岩的母岩主要来源于盆地南缘广泛分布的前中生代沉积-变质基底(兴华渡口岩群、佳疙瘩组、额尔古纳河组等)及各期中酸性火成岩.     

不同发展模式下资源环境承载力评价——以海南省为例

文章关注于产业、人口与资源环境要素的作用关系,建构了资源环境承载力综合评价框架,并以海南省为案例区开展应用研究。该框架首先对区域产业重要性进行评价并分级,为产业结构调整提供依据;其次解析了区域产业、人口资源消耗与污染排放强度,最后,基于产业评价结果设定不同的产业结构调整情景,结合产业和人口的资源消耗与污染排放强度评价不同产业结构下的资源环境承载力,即产业和人口的规模上限。结果表明：2016年海南省的经济规模并未超载,产业有进一步发展空间。其中土地资源成为海南省发展的首要限制因素,其次是水环境;海南经济效益较高的支柱产业和基础性产业多为高耗水、高污染的产业,亟需加强水资源的集约利用,并降低污染排放强度。为提升经济发展规模上限,需要培育低能耗、低排放的产业。文章建构的资源环境承载力评价方法将产业、人口与资源环境相联系,其评价结果政策意义更为明确,可为优化产业结构调整、控制产业及人口发展规模提供决策参考。