Triassic Nb-enriched basalts, magnesian andesites, and adakites of the Qiangtang terrane (Central Tibet): evidence for metasomatism by slab-derived melts in the mantle wedge

New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized by high Sr/Y (25–45), La/Yb (14–42) and Na₂O/K₂O (12–49) ratios, high Al₂O₃ (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and ε_ND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive ε_ND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids. A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite. The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series” recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane.     

鲁苏榴辉岩的地球化学

以微量元素、稀土元素、Ｓｒ和Ｎｄ同位素变异特征为依据，确定鲁苏榴辉岩为多成因、多来源和多阶段，指出主要是在印支期扬子陆块与华北陆块碰撞造山作用过程中，挤入的上地幔碎片以及不同原岩类型的壳内高压变质岩碎块。燕山晚期的区域构造热事件使得某些榴辉岩的同位素体系再平衡。     

冲绳海槽西北侧表层沉积物中微型腹足类的分布及其研究意义

冲绳海槽西北侧大陆架向大陆坡转折处表层沉积物中微型腹足类动物群具有混合的生态特征,这与现代海洋沉积环境并不一致。腹足类动物群中除少数种类为陆坡深海分子,多数种类属内陆架区或近岸浅水分子。因此,动物群主要反映了晚更新世末次冰期低海平面的海洋环境,而少数深海种类的混入应与黑潮暖流在冲绳北端所形成的上升流有关。根据本区腹足类在其他海区的时空分布规律,本文认为在更新世末次冰期,黑潮暖流仍对本区有重要影响，并控制着腹足类的分布。本区腹足类这种混合的生态特征是晚更新世末次冰期以来各种海洋动力环境叠加影响的结果。     

频率域电磁法中视电阻率全区定义

视电阻率定义在电法勘探中得到广泛的应用。目前在频率域电磁法中常常采用远区视电阻率定义。由于在频率域中收发距并非足够大,以致在低频段远区定义视电阻率往往不能反映地下电阻率值。我们定义全区电阻率及引入校正系数K,经二层三层模型及野外实测资料的计算,证明了方法的有效性。     

井中激电地-井方式井旁球体正反演

以激发极化法中的地-井方式中的体极化球形体作为研究对象,采用解析法对地下半空间的电位场进行求解,利用提取出的井中二次场异常电位差进行反演,得出极化球体的球心离井的距离和球心的埋深。通过计算机进行正反演模拟,验证了进行正反演计算的解析式的正确性,并从物理意义上对正反演过程中出现的现象进行分析。最后给出该方法的适用条件以及注意事项。研究对激发极化法地下勘探目标的定量分析具有明确意义。     

GNSS three carrier ambiguity resolution using ionosphere-reduced virtual signals

This paper presents a general modeling strategy for ambiguity resolution (AR) and position estimation (PE) using three or more phase-based ranging signals from a global navigation satellite system (GNSS). The proposed strategy will identify three best “virtual” signals to allow for more reliable AR under certain observational conditions characterized by ionospheric and tropospheric delay variability, level of phase noise and orbit accuracy. The selected virtual signals suffer from minimal or relatively low ionospheric effects, and thus are known as ionosphere-reduced virtual signals. As a result, the ionospheric parameters in the geometry-based observational models can be eliminated for long baselines, typically those of length tens to hundreds of kilometres. The proposed modeling comprises three major steps. Step 1 is the geometry-free determination of the extra-widelane (EWL) formed between the two closest L-band carrier measurements, directly from the two corresponding code measurements. Step 2 forms the second EWL signal and resolves the integer ambiguity with a geometry-based estimator alone or together with the first EWL. This is followed by a procedure to correct for the first-order ionospheric delay using the two ambiguity-fixed widelane (WL) signals derived from the integer-fixed EWL signals. Step 3 finds an independent narrow-lane (NL) signal, which is used together with a refined WL to resolve NL ambiguity with geometry-based integer estimation and search algorithms. As a result, the above two AR processes performed with WL/NL and EWL/WL signals respectively, either in sequence or in parallel, can support real time kinematic (RTK) positioning over baselines of tens to hundreds of kilometres, thus enabling centimetre-to-decimentre positioning at the local, regional and even global scales in the future.     

Geochemistry of the Mian-Lue ophiolites in the Qinling Mountains, central China: Constraints on the evolution of the Qinling orogenic belt and collision of the North and South China Cratons

The Anzishan ophiolite, a typical ophiolitic block of early Carboniferous age in the Mian-Lue suture zone of the Qinling Mountains, central China, consists of amphibolites/metabasalts, gabbros and gabbroic cumulates. All of these rocks, as well as those in the Hunshuiguan-Zhuangke (HZ) block, have compositions similar to normal MORB and back-arc basin basalts (BABB) with high ε_Nd(t) values, indicating that they were derived from a depleted mantle source. The Mian-Lue suture zone also contains blocks of other lithologies, e.g., rift volcanic rocks in the Heigouxia block and arc volcanic rocks in the Sanchazi block. Although they are in fault contact with each other, the presence of these different blocks in the Mian-Lue suture zone may represent a complete Wilson cycle, from initial rifting to open ocean basin to final subduction and continent-continent collision, during the late Paleozoic-early Triassic. In this region, the North and South China Cratons were separated by Paleo-Tethys at least until the early Carboniferous, and final amalgamation of both cratons along the Qinling orogenic belt took place in the Triassic.     

高精度GPS形变监测网数据处理的理论与方法

分析了高精度GPS形变监测网数据处理中系统误差的影响,给出了顾及系统误差影响的自由网平差模型;针对粗差在GPS观测数据中存在的广泛性,在对平差模型进行整体性检验的基础上,采用检验方法消除粗差对平差结果的影响;结合抗差估计,对中国地壳运动观测网络工程1999～2003年观测数据进行了处理,验证了模型的精度和可靠性.     

生物炭对磷石膏中磷的固化作用

磷石膏中的磷在雨水淋滤作用下浸出,将污染堆场附近水体。本研究采用生物炭固化磷石膏中的磷,以减少其对周遭水体的污染。主要通过模拟固化实验和对照浸出实验,分析生物炭用量、反应时间和温度、初始pH值对固化效果的影响,通过XRD、SEM-EDS分析固化后的生成物。实验结果显示,在生物炭用量为25 mg时,单位固化量达到最大值13.20 mg/g;在反应温度T=293 K、初始pH=7条件下,反应平衡时间72 h时浸出液的磷平衡浓度C_e= 1.40 mg/L;温度提升有助于提高生物炭的固化效果,当T=308 K时,浸出液的磷平衡浓度C_e=0.167 mg/L;碱性条件有利于固化反应持续进行,在pH=11条件下,浸出液的磷平衡浓度C_e=0.153 mg/L。实验结果表明生物炭对磷石膏中的磷具有明显的固化效果。磷石膏中的二水硫酸钙溶解后,Ca²⁺与表面带负电的生物炭结合,在生物炭显微结构的凹陷处,化学吸附溶液中的磷酸根生成了絮状、团簇状的羟基磷灰石(HAP)沉淀,从而使浸出磷得到有效控制。     

饱和软土压缩曲线的“反常”现象

饱和软土压缩试验时,经常出现压缩曲线“反常”、压缩系数“倒大”的现象。它是土的原始结构发生破坏前后的不同压缩性的客观反映。饱和软土的结构力很微弱,唯质量好的原状土才能见到这种“反常”。应从成孔、取样、测试及资料整理等多个环节保证其工程意义。