Relationship between footwall composition,crustal contamination,and fluid–rock interaction in the Platreef,Bushveld Complex,South Africa

In the northern limb of the 2.06-Ga Bushveld Complex, the Platreef is a platinum group elements (PGE)-, Cu-, and Ni-mineralized zone of pyroxenite that developed at the intrusion margin. From north to south, the footwall rocks of the Platreef change from Archaean granite to dolomite, hornfels, and quartzite. Where the footwall is granite, the Sr-isotope system is more strongly perturbed than where the footwall is Sr-poor dolomite, in which samples show an approximate isochron relationship. The Nd-isotope system for samples of pyroxenite and hanging wall norite shows an approximate isochron relationship with an implied age of 2.17 ± 0.2 Ga and initial Nd-isotope ratio of 0.5095. Assuming an age of 2.06 Ga, the ɛNd values range from −6.2 to −9.6 (ave. −7.8, n = 17) and on average are slightly more negative than the Main Zone of the Bushveld. These data are consistent with local contamination of an already contaminated magma of Main Zone composition. The similarity in isotope composition between the Platreef pyroxenites and the hanging wall norites suggests a common origin. Where the country rock is dolomite, the Platreef has generally higher plagioclase and pyroxene δ ¹⁸O values, and this indicates assimilation of the immediate footwall. Throughout the Platreef, there is considerable petrographic evidence for sub-solidus interaction with fluids, and the Δ _{plagioclase–pyroxene} values range from −2 to +6, which indicates interaction at both high and low temperatures. Whole-rock and mineral δD values suggest that the Platreef interacted with both magmatic and meteoric water, and the lack of disturbance to the Sr-isotope system suggests that fluid–rock interaction took place soon after emplacement. Where the footwall is granite, less negative δD values suggest a greater involvement of meteoric water. Consistently higher values of Δ _{plagioclase–pyroxene} in the Platreef pyroxenites and hanging wall norites in contact with dolomite suggest prolonged interaction with CO₂-rich fluid derived from decarbonation of the footwall rocks. The overprint of post crystallization fluid–rock interaction is the probable cause of the previously documented lack of correlation between PGE and sulfide content on the small scale. The Platreef in contact with dolomite is the focus of the highest PGE grades, and this suggests that dolomite contamination played a role in PGE concentration and deposition, but the exact link remains obscure. It is a possibility that the CO₂ produced by decarbonation of assimilated dolomite enhanced the process of PGE scavenging by sulfide precipitation.     

A model for the viscosity of rhyolite as a function of H2O-content and pressure: A calibration based on centrifuge piston cylinder experiments

The Newtonian viscosity of synthetic rhyolitic liquids with 0.15-5.24 wt% dissolved water was determined in the interval between 580 and 1640 °C and pressures of 1 atm and 5-25 kbar. Measurements were performed by combining static and accelerated (up to 1000g) falling sphere experiments on water-bearing samples, with high temperature concentric cylinder experiments on 0.15 wt% H₂O melts. These methods allowed viscosity determinations between 10² and 10⁷ Pa s, and cover the complete range of naturally occurring magmatic temperatures, pressures, and H₂O-contents for rhyolites.Our viscosity data, combined with those from previous studies, were modeled by an expression based on the empirical Vogel-Fulcher-Tammann equation, which describes viscosities and derivative properties (glass transition temperature T_g, fragility m, and activation volume of viscous flow Va) of silicic liquids as a function of P-T-X_(H2O). The fitted expressions do not account for composition-dependent parameters other than X_(H2O) and reproduce the entire viscosity database for silicic liquids to within 3.0% average relative error on log η (i.e. std. error of estimate of 0.26 log units).The results yield the expected strong decrease of viscosity with temperature and water content, but show variable pressure dependencies. Viscosity results to be strongly affected by pressure at low pressures; an effect amplified at low temperatures and water contents. Fragility, as a measure for the deviation from Arrhenian behavior, decreases with H₂O-content but is insensitive to pressure. Activation volumes are always largely negative (e.g., less than −10 cm³/mol) and increase strongly with H₂O-content. Variations in melt structure that may account for the observed property variations are discussed.     

Cambridge deep Ocean geophone

We describe recent mechanical andeelectronic modifications to the Cambridge Ocean Bottom Hydrophone system, enabling it to record in addition three geophone channels from a deployed, disposable geophone package. Examples of data from seismic refraction experiments show good correspondence between records of ground motion detected by the hydrophone and the vertical geophone. Seismic signals are undistorted by noise from instrument related sources. Clear examples of P to S conversions just below the receiver are observed. Improved recording conditions are achieved by deploying the geophones in a small pressure vessel as far away as possible from the main instrument package.     

Aspects of Deep Ocean Mixing

The turbulent motions responsible for ocean mixing occur on scales much smaller than those resolved in numerical simulations of oceanic flows. Great progress has been made in understanding the sources of energy for mixing, the mechanisms, and the rates. On the other hand, we still do not have adequate answers to first order questions such as the extent to which the thermohaline circulation of the ocean, and hence the earth's climate, is sensitive to the present mixing rates in the ocean interior. Internal waves, generated by either wind or flow over topography, appear to be the principle cause of mixing. Mean and eddy flows over topography generate internal lee waves, while tidal flows over topography generate internal tides. The relative importance of these different internal wave sources is unknown. There are also great uncertainties about the spatial and temporal variation of mixing. Calculations of internal tide generation are becoming increasingly robust, but we do not know enough about the subsequent behavior of internal tides and their eventual breakdown into turbulence. It does seem, however, that most internal tide energy flux is radiated away from generation sites as low modes that propagate over basin scales. The mechanisms of wave-wave interaction and topographic scattering both act to transfer wave energy from low modes to smaller dissipative scales. This revised version was published online in August 2006 with corrections to the Cover Date.     

Geomechanical model for fracture deformation under hydraulic, mechanical and thermal loads

Hydraulic flow and transport (heat and solute) within crystalline rocks is dominated by the fracture systems found within them. In situ stress conditions have a significant impact on the hydraulic, mechanical and thermal coupled processes, and quantification of these processes provides a key to understanding the often transient time-dependent behaviour of crystalline rocks. In this paper, a geomechanical model is presented which describes fracture closure as a function of effective stress and the changes in parameters such as storage, permeability, porosity and aperture. Allowing the fracture closure to be defined by the change in normal effective stress provides a link to the numerical consideration of parametrical changes due to rock stress alterations caused for example by changes in fracture fluid pressure, stress release, tectonic stress, thermal stress, orientation of the natural fracture in the pervasive stress system and local changes in a rock mass due to stress alteration. The model uses geometrical considerations based on a fractal distribution of apertures on the fracture surface, and applies well-established analytical elastic deformation solutions to calculate the deformation response to changes in effective stress. Analysis of the fractal generation method allows a standard normal distribution of fracture apertures to be predicted for all common fractal dimensions relating to a 2D surface. Changes in the fracture aperture are related to hydraulic functions such as permeability, storage and porosity of the fracture. The geomechanical model is experimentally validated against laboratory scale experimental data gained from the closure of a fractured sample recovered at a depth of 3,800 m from the KTB pilot borehole. Parameters for matching the experimental data were established externally, the only fitting parameters applied were the minimum and maximum contact area between the surfaces and the number of allowable contacts. The model provides an insight into the key processes determining the closure of a fracture, and can act as a material input function for numerical models linking the effects of changes in the stress field, hydraulic or thermal conditions, to the flow and transport parameters of a fractured system.

---

Résumé L’écoulement et le transport (chaleur et soluté) dans les roches cristallines sont dominés par les systèmes de fracture. Les conditions de stress in-situ ont un impact significatif sur l’hydraulique, les processus couplés de mécanique et thermique et la quantification de ces processus apportent une clé pour comprendre le comportement transitoire des roches cristallines. Dans cet article un modèle géomécanique est présenté, modèle qui décrit la fermeture des fractures comme une fonction de la contrainte effective et des changements de paramètres tels le coefficient d’emmagasinement, la perméabilité, la porosité et l’ouverture. En s’accordant que la fermeture des fractures est définit par les changements de la contrainte effective normale, on apporte le lien avec la considération numérique des changements paramétriques dus aux altérations de la contrainte des roches, causés par exemple par des variations de la pression des fluides dans les fractures, du dégagement de la contrainte, des contraintes tectoniques et thermiques, des orientations des fractures naturelles dans le système de contraintes pénétrantes, et des changements locaux dans un massif de roches dus à l’altération des contraintes. Le modèle utilise des considérations géométriques basées sur une distribution fractale des ouvertures à la surface des fractures, et permet d’établir des solutions analytiques de la déformation élastique pour calculer la réponse de la déformation à la contrainte effective. L’analyse de la méthode par génération fractale permet de prédire une distribution normale standard de l’ouverture des fractures, pour toutes les dimensions fractales en relation avec les surfaces 2D. Les changements dans l’ouverture des fractures sont mis en relation avec les fonctions hydrauliques tels la perméabilité, l’emmagasinement et la porosité de la fracture. Le modèle géoméchanique est expérimentalement validé à l’échelle du laboratoire sur un échantillon fracturé récupéré à une profondeur de 3,800 mètres sur le puits du site pilote KTB. Les paramètres du calibrage des données expérimentales ont été établies extérieurement, les seuls paramètres utilisés étant les surfaces de contact minimum et maximum, et le nombre de contacts permis. Le modèle apporte une connaissance perspicace sur le processus clé déterminant la fermeture des fractures, et peut servir de fonction input dans les modèles numériques reliant les effets des variations de la contrainte du terrain, les conditions hydrauliques ou thermales, les paramètres de l’écoulement et du transport et les systèmes de fracture.

---

Resumen El flujo hidráulico y transporte (de calor y solutos) dentro de rocas cristalinas está dominado por los sistemas de fracturas que se encuentran en ellas. Las condiciones de esfuerzos in-situ tienen un impacto significativo en los procesos aparejados termales, mecánicos e hidráulicos y la cuantificación de estos procesos aporta una clave para entender el frecuente comportamiento transitorio dependiente de las rocas cristalinas. En este artículo se presenta un modelo geomecánico que describe el cierre de fracturas en función del esfuerzo efectivo y los cambios en parámetros tal como almacenamiento, permeabilidad, porosidad y apertura. El definir el cierre de fractura mediante el cambio en esfuerzo normal efectivo aporta un vínculo con la consideración numérica de cambios paramétricos ocasionados por alteraciones de esfuerzos en la roca causadas, por ejemplo, por cambios en presión de fluidos en fractura, liberación de esfuerzo, esfuerzo tectónico, esfuerzo termal, orientación de fracturas naturales en el sistema de esfuerzos penetrante, y cambios locales en una masa rocosa ocasionados por alteración de esfuerzos. El modelo utiliza consideraciones geométricas basadas en la distribución fractal de aperturas en la superficie de fractura y aplica soluciones analíticas bien establecidas de deformación elástica para calcular la respuesta de deformación a cambios en el esfuerzo efectivo. Los análisis del método de generación fractal permiten predecir una distribución normal standard para la distribución de aperturas de fracturas para todas las dimensiones fractales comunes que se relacionan con una superficie 2D. Los cambios en la apertura de fractura se relacionan con funciones hidráulicas tal como permeabilidad, almacenamiento y porosidad de la fractura. El modelo geomecánico se ha validado experimentalmente en contra de datos experimentales a escala de laboratorio obtenidos a partir del cierre de una muestra fracturada recuperada a una profundidad de 3,800 m en el pozo piloto KTB. Se establecieron externamente parámetros que se ajustan a los datos experimentales, con los parámetros de ajuste aplicados que fueron el área máxima y mínima de contacto entre las superficies y el número de contactos permisibles. El modelo arroja luz sobre los procesos clave que determinan el cierre de una fractura y puede actuar como un material de función de entrada para modelos numéricos que vinculan los efectos de cambios en el campo de esfuerzos, condiciones termales o hidráulicas, con los parámetros de flujo y transporte de un sistema fracturado.

     

Validation of a fish farm waste resuspension model by use of a particulate tracer discharged from a point source in a coastal environment

To validate a resuspension model of particulate material (salmonid farm wastes), a UV fluorescent particle tracer was selected with similar settling characteristics. Tracer was introduced to the seabed (water depth ≈30 m) and sediment samples taken on days 0, 3, 10, 17 and 30 to measure the horizontal and vertical distribution of tracer in sediments. A concentric sampling grid was established at radii of 25, 50, 100, 150, 200, 400, 700 and 1, 000 m from the source on transects 30° apart. The bulk of the deployed tracer was initially concentrated in an area 25 m radius from the release point; tracer was observed to steadily decrease to zero over a period of 30 days. In a 200 m region measured from the release point in the direction of the residual current, the redeposition of tracer was low. A Lagrangian particle tracking model was validated using these observed data by varying resuspension model parameters within limits to obtain the best agreement between spatial and temporal distributions. The validated model generally gave good predictions of total mass budgets (±7% of total tracer released), particulary where tracer concentrations were high near the release point. Best fit model parameters (critical erosion shear stress=0.018 N m⁻², erodibility constan=60 g m⁻² d⁻¹) are at the low end of reported parameters for coastal resuspension models. Such a low critical erosion shear stress indicates that the frequency of resuspension and deposition events for freshly deposited material is high.     

δO of carbonate, quartz and phosphate from belemnite guards: implications for the isotopic record of old fossils and the isotopic composition of ancient seawater

Belemnite guards of Cretaceous and Jurassic age were found to contain varying amounts of quartz deposited both on the external surface and inside the rostrum. The oxygen isotopic composition of coexisting carbonate, quartz and phosphate from the same rostrum was measured according to well-established techniques. None of these compounds showed isotopic values in equilibrium with one another. Assuming δ¹⁸O values of the diagenetic water within the range of meteoric waters, the δ¹⁸O(SiO₂) yield temperatures in agreement with the apparent secondary origin of this phase. The δ¹⁸O(CO₃²⁻) range, with a certain continuity, between −10.8 and +0.97 PDB-1 with most of the intermediate values being within the range of the carbonate isotopic values of Mesozoic fossils. The most positive isotopic results obtained from phosphate are close to +23/+24‰ (V-SMOW). They can hardly be related to a secondary origin of the phosphate, or to the presence of diagenetic effects, since these results are among the most positive ever measured on phosphate. As far as we know there is no widespread diagenetic process determining an ¹⁸O enrichment of phosphate. The very low concentration of phosphate did not allow the determination of its mineralogical composition. All the available δ¹⁸O(PO₄³⁻) values from belemnite and non-belemnite fossils of marine origin of Tertiary and Mesozoic age are reported along with the newly measured belemnites. The following conclusions may be drawn from the data reported: (1) the pristine oxygen isotope composition of fossil marine organisms (either carbonate or phosphate) may easily undergo fairly large changes because of oxygen isotope exchange processes with diagenetic water; this process is apparent even in the case of geologically recent fossils; (2) the δ¹⁸O(PO₄³⁻) of belemnite rostra seems to be, at least in the case of the most positive results, in isotopic equilibrium with environmental water because of the similarity between the results from Cretaceous belemnites and the results from Cretaceous and Lower Tertiary pelecypods and fish teeth; 3) if so, the only feasible interpretation that can be suggested for the ¹⁸O enriched data is the possibility of a relatively large variation of the oxygen isotopic composition of ocean paleowater from Jurassic to recent time.