Synthesis and characterization of poly(ethylene aspartate)-metal complexes

Poly(ethylene aspartate) [PEA] was synthesized by the melt condensation of D,L-aspartic acid and ethylene glycol. PEA containing pendent amino and carbonyl groups in its repeating chain was used as the polymeric ligand for complexation with transition metal ions, viz. Co(II), Ni(II), Cu(II), Mn(II), Zn(II), Cd(II), Ca(II), Mg(II), Pb(II) and Hg(II). Complexation was found to be most effective in DMSO. The resulting polyester-metal complexes were solid coloured materials which have been characterized by IR spectroscopy, elemental analysis and magnetic susceptibility measurements. The thermal stability of the polyester-metal complexes was investigated by thermogravimetric analysis (TGA). On the basis of the physico-chemical studies, an oxygen and nitrogen coordinated structure for the polyester-metal complexes is proposed.     

Stepwise-Graded Si3N4–SiC Ceramics with Improved Wear Properties

The processing of stepwise graded Si₃N₄/SiC ceramics by pressureless co-sintering is described. Here, SiC (high elastic modulus, high thermal expansion coefficient) forms the substrate and Si₃N₄ (low elastic modulus, low thermal expansion coefficient) forms the top contact surface, with a stepwise gradient in composition existing between the two over a depth of ∼1.7 mm. The resulting Si₃N₄ contact surface is fine-grained and dense, and it contains only 2 vol% yttrium aluminum garnet (YAG) additive. This graded ceramic shows resistance to cone-crack formation under Hertzian indentation, which is attributed to a combined effect of the elastic-modulus gradient and the compressive thermal-expansion-mismatch residual stress present at the contact surface. The presence of the residual stress is corroborated and quantified using Vickers indentation tests. The graded ceramic also possesses wear properties that are significantly improved compared with dense, monolithic Si₃N₄ containing 2 vol% YAG additive. The improved wear resistance is attributed solely to the large compressive stress present at the contact surface. A modification of the simple wear model by Lawn and co-workers is used to rationalize the wear results. Results from this work clearly show that the introduction of surface compressive residual stresses can significantly improve the wear resistance of polycrystalline ceramics, which may have important implications for the design of contact-damage-resistant ceramics.     

Studies on lymphocyte subpopulations and the effect of age on immune competence in turkeys

We characterized the lymphocyte subpopulations and investigated the effect of age on cellular and humoral immunity, development of lymphoid organs, and the relative proportions of CD4+ and CD8+ cells in turkeys. The mitogenic responses of peripheral T cells were poorly developed at hatch but developed rapidly after hatch and reached adult levels by 2 weeks-of-age. The average percentage of CD4+ cells was 45, 29.8, and 26.3 in the thymi, peripheral blood, and spleens, respectively, in turkeys. The mean percentage of CD8+ cells in the thymi, peripheral blood, and spleens of turkeys was 53.8, 13.6, and 15.5, respectively. Age did not influence the relative proportions of CD4+ and CD8+ T cells in the spleens and peripheral blood of turkeys. The mean percentages of IgM+ cells in the bursae and spleens were 78.5 and 26.8, respectively. Day-old turkeys did not develop detectable antibodies to either thymus dependent or independent antigens. However, 2 week or older turkeys showed good humoral responses. Inoculation of BSA at hatch induced tolerance, whereas injection of SRBC did not. Analysis of relative organ weights of turkey lymphoid organs showed that spleens and thymi developed rapidly during the first week-of-age.     

Countercurrent water-heating system with a heat exchanger in a solar energy collector loop

The counter current heat exchanger theory with periodic inlet temperatures has been applied to analyze the thermal performance of a water heating system. The theoretical results obtained are in agreement with the experimental data reported in the literature.     

A scheduling decision aid in glass fiber manufacturing

A decision aid for scheduling production in glass fiber manufacturing industry is described. The methodology combines a linear programming (LP) optimization model with a heuristic model. The LP model determines production goals; the heuristic model then uses the LP output to incorporate system-specific constraints in developing processing sequences.     

Crack growth in transforming ceramics under cyclic tensile loads

The mechanisms of stable growth of short fatigue cracks (crack length up to 1 mm) at room temperature in magnesia-partially stabilized zirconia subjected to cyclic tensile loads were investigated. Single edge-notched specimens were fractured in the four-point bend configuration under cyclic and quasi-static tensile loads. At a load ratio of 0.1, the threshold stress intensity factor range, K, for fracture initiation in cyclic tension is as low as 3.4 M Pam^1/2, and catastrophic failure occurs at K=6.6 M Pam^1/2. For crack length less than 1 mm and for plane strain conditions, growth rates are highly discontinuous, and periodic crack arrest is observed after growth over distances of the order of tens of micrometres. Crack advance could only be resumed with an increase in the far-field stress intensity range. The mechanisms of short crack advance in cyclic tension are similar to those observed under quasi-static loads, and the tensile fatigue effect appears to be a manifestation of static failure modes. A model is presented to provide an overall framework for the tensile fatigue crack growth characteristics of partially stabilized zirconia. Experimental results are also described to demonstrate the possibility of stable room temperature crack growth under cyclic tension in fine-grained tetragonal zirconia polycrystals, partially stabilized with Y₂O₃. The growth of cracks in transformation-toughened ceramics is found to be strongly influenced by the crack size and shape, stress state and specimen geometry.