Study of the effective parameters on mechanical and electrical properties of carbon black filled PP/PA6 microfibrillar composites

In this study the electrical and mechanical properties of microfibrillar polypropylene (PP)/polyamide6 (PA6) blend filled with super conductive carbon black (CB) have been investigated. In situ microfibrillar PP/PA6 composites filled with CB are produced using a single screw extruder equipped with a spinneret. Glycidyl methacrylate (GMA) grafted polypropylene (PP-g-GMA) is used as the compatibilizer. To investigate the effects of extensional flow on the microstructure, electrical and mechanical properties, three adaptors with various convergence angles were designed, prepared and applied between the extruder and the spinneret. To optimize the effects of processing and material parameters on the electrical and mechanical properties, the Taguchi method of experimental design is used. Material and processing factors which are studied include: concentration of PA6, compatibilizer level, CB concentration, drawing speed of melt spinning line, adaptor angle, order of mixing and temperature profile along the extruder. The results show an increase in DC conductivity of up to 10¹¹ times in comparison with pure PA6, by increasing the concentration of CB, drawing speed, adaptor angle and optimizing other parameters. By optimizing processing and material factors studied here, strength of microfibrillar structured composites is increased of up to 80% in comparison to pure PP.     

Practical scalable image analysis and indexing using Hadoop

The ability to handle very large amounts of image data is important for image analysis, indexing and retrieval applications. Sadly, in the literature, scalability aspects are often ignored or glanced over, especially with respect to the intricacies of actual implementation details. In this paper we present a case-study showing how a standard bag-of-visual-words image indexing pipeline can be scaled across a distributed cluster of machines. In order to achieve scalability, we investigate the optimal combination of hybridisations of the MapReduce distributed computational framework which allows the components of the analysis and indexing pipeline to be effectively mapped and run on modern server hardware. We then demonstrate the scalability of the approach practically with a set of image analysis and indexing tools built on top of the Apache Hadoop MapReduce framework. The tools used for our experiments are freely available as open-source software, and the paper fully describes the nuances of their implementation.     

Transforming Vulnerability Indexing for Saltwater Intrusion into Risk Indexing through a Fuzzy Catastrophe Scheme

Mapping vulnerability to Saltwater Intrusion (SWI) in coastal aquifers is studied in this paper using the GALDIT framework but with a novelty of transforming the concept of vulnerability indexing to risk indexing. GALDIT is the acronym of 6 data layers, which are put consensually together to invoke a sense of vulnerability to the intrusion of saltwater against aquifers with freshwater. It is a scoring system of prescribed rates to account for local variations; and prescribed weights to account for relative importance of each data layer but these suffer from subjectivity. Another novelty of the paper is to use fuzzy logic to learn rate values and catastrophe theory to learn weight values and these together are implemented as a scheme and hence Fuzzy-Catastrophe Scheme (FCS). The GALDIT data layers are divided into two groups of Passive Vulnerability Indices (PVI) and Active Vulnerability Indices (AVI), where their sum is Total Vulnerability Index (TVI) and equivalent to GALDIT. Two additional data layers (Pumping and Water table decline) are also introduced to serve as Risk Actuation Index (RAI). The product of TVI and RAI yields Risk Indices. The paper applies these new concepts to a study area, subject to groundwater decline and a possible saltwater intrusion problem. The results provide a proof-of-concept for PVI, AVI, RAI and RI by studying their correlation with groundwater quality samples using the fraction of saltwater (f_sea), Groundwater Quality Indices (GQI) and Piper diagram. Significant correlations between the appropriate values are found and these provide a new insight for the study area.

     

A model to predict the solubility and permeability of gaseous penetrant in the glassy polymeric membrane at high pressure

In this work, the transport properties of gaseous penetrant through several dense glassy polymeric membranes are studied. The nonequilibrium lattice fluid (NELF) in conjunction with the modified Fick's law and dual mode sorption model was used to simulate the gas transport in glassy polymeric membranes. The approach is based on the sorption, diffusion, in which solubility is calculated based on the NELF model, and diffusion coefficient is obtained from the product thermodynamic coefficient and molecular mobility. The governing equation is solved by the finite element method using COMSOL multi-physics software. The developed model for gas permeability of glassy polymeric membrane can be applied in a wide range of pressure and temperature. The comparison of the calculated permeability and solubility of gasses with the experimental data represented the ability of the developed model. Increasing feed gas temperature increases the gas permeability, while this variation leads to lower gas solubility in the glassy polymeric membranes. The effect of feed temperature and pressure on permeability and solubility is investigated, and the experimental data from literature are described by the developed model. A good prediction of the experimental data can be observed over the considered condition.     

Preparative scale synthesis ofO-glycosides and of a disaccharide by electrochemical oxidation of phenylS-glycosides

Summary O-glycosides were synthesized by electrochemical oxidation of phenylS-glycosides in the presence of primary alcohols in acetonitrile. Similarly, a -linked disaccharide was obtained selectively by oxidation of phenylS-glycoside in the presence of a sugar alcohol. Electrosyntheses were performed under controlled potential or at constant current, in an undivided cell, on a large scale. 1 to 60 g of phenylS-glycosides in 0.5 to 1 dm³ of acetonitrile were converted with chemical yields in the range of 65–75%.     

Additive Manufacturing of Hard Magnetic Passive Shims to Increase Field Homogeneity of a Halbach Magnet

Obtaining a highly homogeneous magnetic field is desired for field-controlled applications. For example, the resolution of magnetic analysis methods can be improved by generating a stronger and more homogeneous field over the region of interest (ROI). A set of 3D-printed passive shims is fabricated using additive manufacturing to improve the magnetic field homogeneity of a Halbach magnet assembly. The feedstock is a custom acrylonitrile butadiene styrene (ABS)-hard magnet composite filament filled with 60% wt. isotropic NdFeB. Additionally, a method for investigating the remanence is developed and validated. The result reveals a good agreement between the new method and existing measurement techniques for the remanence of permanent magnets. It is also shown that the additive manufacturing procedure has negligible effects on the magnetic properties. Performing a parametric study over a rectangular ROI, an optimized shim configuration is achieved. In the optimized and 3D-printed configuration, the average norm of the magnetic flux density, B_norm, is increased by 13% and, more importantly, a 43% increase in the magnetic uniformity is obtained. These results highlight the great potential of freeform manufacturing, namely, additive manufacturing, to tailor the properties of magnet structures.     

Personalisierte Medizin als Orphanisierung: rechtliche und ethische Fragen

Definition of the problem The development of personalized medicine is currently a popular topic. Particularly the personalized pharmacotherapy is a matter of relative importance due to pharmacological and molecular–genetic developments. For this reason it is required to examine the implications of personalized pharmacotherapy to statutory health insurance and health care of patients. Arguments In this context the question of orphanization arises: If medical drugs of personalized medicine could be regularly indicated as orphan drugs, i.e., as drugs to medicate orphan diseases, it would not be necessary according to the “Arzneimittelneuordnungsgesetz” (AMNOG) to prove an auxiliary value within the assessment of the “Gemeinsamer Bundesausschuss” (GBA). Crucial to the drug’s indication as an orphan drug is among other things the rate of prevalence of the patient group, whose disease should be medicated with the drug. In this connection, there is importance attached to the stratification of patient groups within personalized medicine. Conclusion An orphanization causes consequences in terms of prices to the statutory health insurance due to the lack of knowledge about an auxiliary value. For patients, the implications must be considered in a more differentiated manner.     

Nanostructure array of coupled RTDs as cellular neural networks

The processing capabilities of a proposed nanoelectronic device are investigated. The device is considered as a global dynamical system with local circuit model components. The system equations and the corresponding network model are presented. The characteristics of this network model are compared with the cellular neural networks. Certain characteristics of the network are analysed theoretically and demonstrated with circuit‐system level simulations. As a novel property, it is shown that the single layer nanodevice network structure is a basic reaction–diffusion system and it is capable of autowave propagation. Furthermore, the same network structure exhibits several image processing capabilities like image smoothing, edge enhancement, and horizontal or vertical line detection using simple arrangements of the device parameters. Copyright ©2003 John Wiley & Sons, Ltd.     

Passive Three Dimensional Face Recognition Using Iso-Geodesic Contours and Procrustes Analysis

We introduce a new model for personal recognition based on the 3-D geometry of the face. The model is designed for application scenarios where the acquisition conditions constrain the facial position. The 3-D structure of a facial surface is compactly represented by sets of contours (facial contours) extracted around automatically pinpointed nose tip and inner eye corners. The metric used to decide whether a point on the face belongs to a facial contour is its geodesic distance from a given landmark. Iso-geodesic contours are inherently robust to head pose variations, including in-depth rotations of the face. Since these contours are extracted from rigid parts of the face, the resulting recognition algorithms are insensitive to changes in facial expressions. The facial contours are encoded using innovative pose invariant features, including Procrustean distances defined on pose-invariant curves. The extracted features are combined in a hierarchical manner to create three parallel face recognizers. Inspired by the effectiveness of region ensembles approaches, the three recognizers constructed around the nose tip and inner corners of the eyes are fused both at the feature-level and the match score-level to create a unified face recognition algorithm with boosted performance. The performances of the proposed algorithms are evaluated and compared with other algorithms from the literature on a large public database appropriate for the assumed constrained application scenario.     

Influence of edge velocity on flame front position and displacement speed in turbulent premixed combustion

Using a novel concept, the present study experimentally investigates underlying physics pertaining to statistics of the flame front position and the flame front velocity in turbulent premixed V-shaped flames. The concept is associated with characteristics of the reactants velocity at the vicinity of the flame front, referred to as the edge velocity. The experiments are performed using simultaneous Mie scattering and Particle Image Velocimetry techniques. Three mean streamwise exit velocities of: 4.0, 6.2, and 8.6 m/s along with three fuel–air equivalence ratios of: 0.7, 0.8, and 0.9 are examined. The results show that fluctuations of the flame front position and the flame front velocity are induced by the fluctuations of the component of the edge velocity transverse to the mean flow direction. Analysis of the results show that the mean of the flame front velocity in the normal direction to the flame front is significantly dependent on the vertical distance from the flame-holder. Relatively close to the flame-holder, the mean of the flame front velocity in the direction normal to the flame front is about zero; however, it increases to values several times larger than the laminar flame speed by increasing the vertical distance from the flame-holder.