Selectivity Enhancement to the Exclusive Formation of Ethyltoluenes and Hydrogen During Dehydroalkylation of Toluene with Ethane

The dehydroalkylation of toluene with ethane to the isomeric ethyltoluenes was studied on 0.4Pt/H-ZSM-5 at varying contact times (1/WHSV). At a high contact time of 1.0 h, toluene disproportionation and hydrogenolysis reactions dominate, resulting in low selectivity to the desired ethyltoluenes via the alkylation reaction. However, at a low contact time of 0.12 h side reactions are eliminated, resulting in maximum selectivities to the kinetically favored ethyltoluenes and hydrogen. Results at high selectivities to ethyltoluenes provide significant insight into reaction pathways.     

Cit-CSP及其应用

介绍了Cit-CSP--Cit/E-commerce信息安全保障平台子系统，并阐述了它所提供的消息摘要、块加密、加密(公钥)、签名和MAC等功能和服务。     

Reconstruction of reflectance spectra using weighted principal component analysis

The weighted principal component analysis technique is employed for reconstruction of reflectance spectra of surface colors from the related tristimulus values. A dynamic eigenvector subspace based on applying certain weights to reflectance data of Munsell color chips has been formed for each particular sample and the color difference value between the target, and Munsell dataset is chosen as a criterion for determination of weighting factors. Implementation of this method enables one to increase the influence of samples which are closer to target on extracted principal eigenvectors and subsequently diminish the effect of those samples which benefit from higher amount of color difference. The performance of the suggested method is evaluated in spectral reflectance reconstruction of three different collections of colored samples by the use of the first three Munsell bases. The resulting spectra show considerable improvements in terms of root mean square error between the actual and reconstructed reflectance curves as well as CIELAB color difference under illuminant A in comparison to those obtained from the standard PCA method. © 2008 Wiley Periodicals, Inc. Col Res Appl, 33, 360–371, 2008     

Simulation of Natural Depletion and Miscible Gas Injection Effects on Asphaltene Stability in Petroleum Reservoir Fluids

Natural depletion of petroleum reservoirs as well as gas injection for enhance oil recovery, are unavoidable processes in the oil industry. Foremost, prediction of the problems due to these two processes is very necessary and important. So many field and experimental experiences have shown that heavy organic depositions, especially asphaltene deposition, are principal results during these processes. Results of laboratory simulation of asphaltene deposition during the natural depletion of petroleum reservoirs and also during gas injection and enhanced oil recovery (EOR) processes are reported here. This is achieved through the design of a new experimental setup for the investigation of pressure and composition effects on asphaltene deposition in petroleum fluids at high pressure and high temperature conditions. In this work, asphaltene deposition during decreasing pressure, from pressures greater than reservoir pressure to pressures below the bubble point pressure (natural depletion) and also asphaltene deposition during natural gas injection in reservoir conditions, are studied for three samples—one recombined sample and two bottomhole samples. All of the obtained results from this work conform to theoretical and other experimental works.     

A novel approach to predict shear strength of tilted angle connectors using artificial intelligence techniques

Shear connectors play a prominent role in the design of steel-concrete composite systems. The behavior of shear connectors is generally determined through conducting push-out tests. However, these tests are costly and require plenty of time. As an alternative approach, soft computing (SC) can be used to eliminate the need for conducting push-out tests. This study aims to investigate the application of artificial intelligence (AI) techniques, as sub-branches of SC methods, in the behavior prediction of an innovative type of C-shaped shear connectors, called Tilted Angle Connectors. For this purpose, several push-out tests are conducted on these connectors and the required data for the AI models are collected. Then, an adaptive neuro-fuzzy inference system (ANFIS) is developed to identify the most influencing parameters on the shear strength of the tilted angle connectors. Totally, six different models are created based on the ANFIS results. Finally, AI techniques such as an artificial neural network (ANN), an extreme learning machine (ELM), and another ANFIS are employed to predict the shear strength of the connectors in each of the six models. The results of the paper show that slip is the most influential factor in the shear strength of tilted connectors and after that, the inclination angle is the most effective one. Moreover, it is deducted that considering only four parameters in the predictive models is enough to have a very accurate prediction. It is also demonstrated that ELM needs less time and it can reach slightly better performance indices than those of ANN and ANFIS.

     

Query processing optimization in broadcasting XML data in mobile communications

Todays, XML as a de facto standard is used to broadcast data over mobile wireless networks. In these networks, mobile clients send their XML queries over a wireless broadcast channel and recieve their desired XML data from the channel. However, downloading the whole XML data by a mobile device is a challenge since the mobile devices used by clients are small battery powered devices with limited resources. To meet this challenge, the XML data should be indexed in such a way that the desired XML data can be found easily and only such data can be downloaded instead of the whole XML data by the mobile clients. Several indexing methods are proposed to selectively access the XML data over an XML stream. However, the existing indexing methods cause an increase in the size of XML stream by including some extra information over the XML stream. In this paper, a new XML stream structure is proposed to disseminate the XML data over a broadcast channel by grouping and summarizing the structural information of XML nodes. By summarizing such information, the size of XML stream can be reduced and therefore, the latency of retrieving the desired XML data over a wirless broadcast channel can be reduced. The proposed XML stream structure also contains indexes in order to skip from the irrelevant parts over the XML stream. It therefore can reduce the energy consumption of mobile devices in downloading the results of XML queries. In addition, our proposed XML stream structure can process different types of XML queries and experimental results showed that it improves the performace of XML query processing over the XML data stream compared to the existing research works in terms of access and tuning times.

     

Ultra-low power MEMS micro-heater device

Microsystem Technologies - In this paper, we propose a simple design for the heating device with ultra-low power consumption. The device is composed of a micro heater made of Nichrome (20/80)...     

Incorporation of a Regularization Term to Control Negative Correlation in Mixture of Experts

Combining accurate neural networks (NN) in the ensemble with negative error correlation greatly improves the generalization ability. Mixture of experts (ME) is a popular combining method which employs special error function for the simultaneous training of NN experts to produce negatively correlated NN experts. Although ME can produce negatively correlated experts, it does not include a control parameter like negative correlation learning (NCL) method to adjust this parameter explicitly. In this study, an approach is proposed to introduce this advantage of NCL into the training algorithm of ME, i.e., mixture of negatively correlated experts (MNCE). In this proposed method, the capability of a control parameter for NCL is incorporated in the error function of ME, which enables its training algorithm to establish better balance in bias-variance-covariance trade-off and thus improves the generalization ability. The proposed hybrid ensemble method, MNCE, is compared with their constituent methods, ME and NCL, in solving several benchmark problems. The experimental results show that our proposed ensemble method significantly improves the performance over the original ensemble methods.     

A robust critical path in an environment with hybrid uncertainty

In this article, we consider the project critical path problem in an environment with hybrid uncertainty. In this environment, the duration of activities are considered as random fuzzy variables that have probability and fuzzy natures, simultaneously. To obtain a robust critical path with this kind of uncertainty a chance constraints programming model is used. This model is converted to a deterministic model in two stages. In the first stage, the uncertain model is converted to a model with interval parameters by alpha-cut method and distribution function concepts. In the second stage, the interval model is converted to a deterministic model by robust optimization and min-max regret criterion and ultimately a genetic algorithm with a proposed exact algorithm are applied to solve the final model. Finally, some numerical examples are given to show the efficiency of the solution procedure.     

Sustainable Basin-Scale Water Allocation with Hydrologic State-Dependent Multi-Reservoir Operation Rules

This study extends the PSO-MODSIM model, integrating particle swarm optimization (PSO) algorithm and MODISM river basin decision support system (DSS) to determine optimal basin-scale water allocation, in two aspects. The first is deriving hydrologic state-dependent (conditional) operating rules to better account for drought and high-flow periods, and the second is direct, explicit consideration of sustainability criteria in the model’s formulation to have a better efficiency in basin-scale water allocation. Under conditional operating rules, the operational parameters of reservoir target storage levels and their priority rankings were conditioned on the hydrologic state of the system in a priority-based water allocation scheme. The role of conditional operating rules and policies were evaluated by comparing water shortages associated with objective function values under unconditional and conditional operating rules. Optimal basin-scale water allocation was then evaluated by incorporating reliability, vulnerability, reversibility and equity sustainability indices into the PSO objective function. The extended model was applied for water allocation in the Atrak River Basin, Iran. Results indicated improved distribution of water shortages by about 7.5% using conditional operating rules distinguishing dry, normal and wet hydrologic states. Alternative solutions with nearly identical objective function values were found with sustainability indices included in the model.