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1.
Joel Kuula Heino Kuuluvainen Jarkko V. Niemi Erkka Saukko Harri Portin Anu Kousa 《Aerosol science and technology》2020,54(2):190-202
AbstractLung deposited surface area (LDSA) is a relatively new metric that has been argued to be more accurate at predicting health effects from aerosol exposure. For typical atmospheric aerosol, the LDSA concentration depends mainly on the concentration of ultrafine particles (e.g. vehicular exhaust emissions and residential wood combustion) and therefore optical methods cannot be used to measure and quantify it. The objective of this study was to investigate and describe typical characteristics of LDSA under different urban environments and evaluate how a diffusion charging-based Pegasor AQ Urban sensor (Pegasor Ltd., Finland) can be used as an alternative to optical sensors when assessing local combustion emissions and respective LDSA concentrations. Long-term (12?months) sensor measurements of LDSA were carried out at three distinctly different measurement sites (four sensor nodes) in the Helsinki metropolitan area, Finland. The sites were affected mainly by vehicular exhaust emission (street canyon and urban background stations) and by residential wood combustion (two detached housing area stations). The results showed that the accuracy of the AQ Urban was good (R2 = 0.90) for the measurement of LDSA when compared to differential mobility particle sizer. The mean concentrations of LDSA were more than twice as high at the street canyon (mean 22 µm2 cm?3) site when compared to the urban background site (mean 9.4 µm2 cm?3). In the detached housing area, the mean concentrations were 12 µm2 cm?3, and wood combustion typically caused high LDSA peaks in the evenings. High correlations and similar diurnal cycles were observed for the LDSA and black carbon at street canyon and urban background stations. The utilization of a small-scale sensor network (four nodes) showed that the cross-station variability in hourly LDSA concentrations was significant in every site, even within the same detached housing area (distance between the two sites ~670?m). 相似文献
2.
A mathematical model of evaporation process from a laminar falling liquid film on a vertical plate of constant temperature is presented. The model is developed with and without interfacial shear stress due to the vapor flow at the liquid film surface. The vapor pressure drop, vapor exit velocity and cooling rate are calculated for different liquid mass flow values. It is shown that lower liquid mass flow produces higher cooling rate. The results also show that the interfacial shear stress has a considerable negative effect on the cooling rate. It is proved that there exists an optimum distance between the plates, which gives the maximum volumetric cooling rate. 相似文献
3.
An expenmental and theoretical study of heat and mass transfer analogy and a comparison of that to a binary liquid mixture evaporation is presented. Common organic solvents, ethanol and n-heptane, were used to form an alcohol - hydrocarbon mixture. Studies were carried out in a horizontal rectangular channel having air flow velocities of 0.2 - 0.9 m/s. Heat transfer coefficients were measured with a copper plate resistor and mass transfer coefficients with a square pool. The heat and mass transfer analogy is presented for a system having two evaporating compounds with a fixed value of air flow and verified by measuring and comparing mass transfer coefficients for distilled water with air flow velocities of 0.2 - 0.9 mls. An illustrative example of the use of the theory for industrial ventilation is presented. 相似文献
4.
Markku Eskelinen 《Digital Creativity》2013,24(3):175-183
It is relatively stress-free to write about computer games as nothing too much has been said yet, and almost anything goes. The situation is pretty much the same when it comes to writing about games and gaming in general. The sad fact with alarming cumulative consequences is that they are under-theorized; there are Huizinga, Caillois and Ehrmann of course, and libraries full of board game studies,in addition to game theory and bits and pieces of philosophy – most notably those of Wittgenstein – but they won't get us very far with computer games. So if there already is or soon will be a legitimate field for computer game studies, this field is also very open to intrusions and colonisations from the already organized scholarly tribes. Resisting and beating them is the goal of our first survival game in this paper, as what these emerging studies need is independence, or at least relative independence. 相似文献
5.
Hoffren Anna-Marja; Saloheimo Markku; Thomas Pamela; Overington John P.; Johnson Mark S.; Knowles Jonathan K.C.; Blundell Tom L. 《Protein engineering, design & selection : PEDS》1993,6(2):177-182
A model of the lignin peroxidase LIII of Phlebia radiata wasconstructed on the basis of the structure of cytochrome c peroxidase(CCP). Because of the low percentage of amino acid identitybetween the CCP and the lignin peroxidase LIII of Phlebia radiata,alignment of the sequences was based on the generation of atemplate from a knowledge of the 3-D structure of CCP and consensussequences of lignin peroxidases. This approach gave an alignmentin which all the insertions in the lignin peroxidase were placedat loop regions of CCP, with a 21.1% identity for these twoproteins. The model was constructed using this alignment andthe computer program COMPOSER, which assembles the model asa series of rigid fragments derived from CCP and other proteins.Manual intervention was required for some of the longer loopregions. The -helices forming the structural framework, andespecially the haem environment of CCP, are conserved in theLIII model and the core is close packed without holes. A possiblesite of the substrate oxidation at the haem edge of LIII isdiscussed. 相似文献
6.
Robustness and convergence properties of exponentially weighted least-squares identification are studied. It is shown that exponential convergence in the noiseless case can be obtained for a class of increasing or decreasing regression vectors. The rate of change of the limits in the regressors affect the convergence rates, which are explicitly given. It is demonstrated that for a sub-class of regressors decreasing-in-the-norm exponential convergence without the noise does not guarantee robustness subject to a bounded noise. Instead, exponential divergence of the estimate is shown in a specific case. 相似文献
7.
Thermotropic liquid crystalline polymers, LCPs, are frequently blended with thermoplastics to achieve an in situ composite structure. Significant mechanical reinforcement is obtained for the matrix polymer in the direction of the LCP fibers, but the transversal properties are often inferior because of the incompatibility of the components. Blends of LCP with polypropylene, and with three related matrix polymers, and PP/LCP blends with added potential compatibilizers were prepared and studied for their mechanical properties and morphology. A notable improvement in impact strength was achieved when a small amount of ethylene-based terpolymer was added as compatibilizer. © 1993 John Wiley & Sons, Inc. 相似文献
8.
Ming Yang Suvi Kuittinen Markku Keinänen Jouko Vepsäläinen Henrik Romar Pekka Tynjälä Ulla Lassi Ari Pappinen 《Chemical Engineering Research and Design》2014
In this study, pretreatment liquor of acid-stored green and yellowish barley silage was used for fermentative acetone–butanol–ethanol (ABE) production. Further, the catalytic oxidation of biobutanol over Pt catalysts was studied to investigate the behaviour of butanol as a fuel in the combustion engine. After the hydrothermal treatment of green and yellowish barley silage followed by enzymatic hydrolysis, approximately 88% and 100% of the available sugars were recovered, respectively. Batch fermentations of pretreatment barley silage liquor, supplemented with gelatinised barley grain, showed good fermentability with total ABE concentrations of 9.0 g/L and 10.9 g/L. Butanol yields of 0.20, 0.17 and ABE yields of 0.28, 0.26 (g/g monosaccharide) were obtained, respectively. In catalytic activity measurements, the conversion of biobutanol became appreciable in the 120–140 °C range, whereas conversions greater than 95% were obtained over 200 °C. Selectivities were also high, although formation of by-products, such as butyraldehyde, was observed. 相似文献
9.
10.
Helmi Keskinen Jyrki M. Mäkelä Mikko Aromaa Jorma Keskinen Sami Areva Cilâine V. Teixeira Jarl B. Rosenholm Viljami Pore Mikko Ritala Markku Leskelä Mari Raulio Mirja S. Salkinoja-Salonen Erkki Levänen Tapio Mäntylä 《Catalysis Letters》2006,111(3-4):127-132
Titania and titania-silver nanoparticle deposits were made by Liquid Flame Spray technique, in which the liquid precursor
is injected into a high temperature flame, where it will evaporate and nucleate to nanosize particles. One-step and two-step
methods were used for preparation of titania-silver deposits. The amount of silver added was 1 wt%. The deposits were collected
in the flame zone on steel and glass surfaces and were analyzed by TEM, EDS, XPS and SAXS. The titania deposits consisted
of porous nanosized titania agglomerates of primary particles (~10 nm). With silver addition, small spherical silver metal
particles (~2 nm) were detected on the agglomerates. An increase in the photocatalytic activity was verified by stearic acid
decomposition and biofilm removal using Deinococcus geothermalis as the model organism. 相似文献