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1.
The behavior of two series of concrete slabs exposed to sulfate-bearing soils was investigated by a numerical model called
STADIUM. In addition to the diffusion of ions and moisture, the model also accounts for the effects of dissolution/precipitation
reactions on the transport mechanisms. The simulations yielded by the model were compared to the actual degradation of the
slabs after 8 years of exposure. The microstructural alterations of concrete resulting from the penetration of magnesium,
chloride and sulfate ions were studied by backscatter mode scanning electron microscope observations and energy-dispersive
X-ray analyses. The comparison of both series of data indicates that the model can reliably predict the various features of
the microstructural alterations of concrete.
Editorial Note Laval University (Canada) is a RILEM Titular Member. Prof. J. Marchand was awarded the 2000 Robert L'Hermite Medal. He is Editor in Chief for Concrete Science and Engineering and Associate Editor for Materials and Structures. He participates in RILEM TC 186-ISA ‘Internal Sulfate attack’. 相似文献
Résumé Le comportement de deux séries de dalles sur sol en béton exposées à des sols chimiquement agressifs a été étudié à l'aide d'un code de calcul numérique appelé STADIUM. Ce modèle permet de décrire le transport couplé de l'eau et des ions dans des matériaux poreux non-saturés en prenant en considération l'influence des réactions chimiques. Les résultats des simultations de la dégradation du béton après huit ans d'exposition à des ions chlore, sulfate et magnésium. Les observations ont été réalisées par microscopie électronique à balayage. Des analyses par dispersion des rayons X ont également été effectuées. Les données démontrent clairement que le modèle perment de prédire avec précision le comportement du béton soumis à différents types d'agression chimique.
Editorial Note Laval University (Canada) is a RILEM Titular Member. Prof. J. Marchand was awarded the 2000 Robert L'Hermite Medal. He is Editor in Chief for Concrete Science and Engineering and Associate Editor for Materials and Structures. He participates in RILEM TC 186-ISA ‘Internal Sulfate attack’. 相似文献
2.
This paper presents the trajectory tracking control of an autonomous underwater vehicle(AUV). To cope with parametric uncertainties owing to the hydrodynamic effect, an adaptive control law is developed for the AUV to track the desired trajectory. This desired state-dependent regressor matrix-based controller provides consistent results under hydrodynamic parametric uncertainties.Stability of the developed controller is verified using the Lyapunov s direct method. Numerical simulations are carried out to study the efficacy of the proposed adaptive controller. 相似文献
3.
A. K. Sahu G. Selvarani S. Pitchumani P. Sridhar A. K. Shukla 《Journal of Applied Electrochemistry》2007,37(8):913-919
Incorporation of silica particles through a sol-gel process into the anode-catalyst layer with a sol-gel modified Nafion-silica
composite membrane renders easy retention of back-diffused water from the cathode to anode through the composite membrane
electrolyte, increases the catalyst-layer wettability and improves the performance of the Polymer Electrolyte Fuel Cell (PEFC)
while operating under relative humidity (RH) values ranging between 18% and 100% with gaseous hydrogen and oxygen reactants
at atmospheric pressure. A peak power density of 300 mW cm−2 is achieved at a load current-density value of 1200 mA cm−2 for the PEFC employing a sol-gel modified Nafion-silica composite membrane and operating at 18% RH. Under similar operating
conditions, the PEFC with a Membrane Electrode Assembly (MEA) comprising Nafion-silica composite membrane with silica in the
anode-catalyst layer delivers a peak power density of 375 mW cm−2. By comparison, the PEFC employing commercial Nafion membrane fails to deliver satisfactory performance at 18% RH due to
the limited availability of water at its anode, acerbated electro-osmotic drag of water from anode to cathode and insufficient
water back diffusion from cathode to anode causing the MEA to dehydrate. 相似文献
4.
Betal Atanu Bera Jayanta Alam Mahfooz Gandi Appala Naidu Sahu Satyajit 《Journal of Computational Electronics》2022,21(1):227-234
Journal of Computational Electronics - The strain- and electric field-dependent electronic and optical properties of monolayer GaInS2 have been calculated using density functional... 相似文献
5.
Modulated Triple‐Material Nano‐Heterostructures: Where Gold Influenced the Chemical Activity of Silver in Nanocrystals 下载免费PDF全文
Puspanjali Sahu Gyanaranjan Prusty Amit K. Guria Narayan Pradhan 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(33)
For efficient charge separations, multimaterial hetero‐nanostructures are being extensively studied as photocatalysts. While materials with one heterojunction are widely established, the chemistry of formation of multijunction heterostructures is not explored. This needs a more sophisticated approach and modulations. To achieve these, a generic multistep seed mediated growth following controlled ion diffusion and ion exchange is reported which successfully leads to triple‐material hetero‐nanostructures with bimetallic‐binary alloy‐binary/ternary semiconductors arrangements. Ag2S nanocrystals are used as primary seeds for obtaining AuAg‐AuAgS bimetallic‐binary alloyed metal–semiconductor heterostructures via partial reduction of Ag(I) using Au(III) ions. These are again explored as secondary seeds for obtaining a series of triple‐materials heterostructures, AuAg‐AuAgS‐CdS (or ZnS or AgInS2), with introduction of different divalent and trivalent ions. Chemistry of each step of the gold ion–induced changes in the rate of diffusion and/or ion exchanges are investigated and the formation mechanism for these nearly monodisperse triple material heterostructures are proposed. Reactions without gold are also performed, and the change in the reaction chemistry and growth mechanism in presence of Au is also discussed. 相似文献
6.
Coarse frequency offset estimate and tracking of residual frequency offset are two crucial stages for frequency synchronization in OFDM based WLAN systems. An improved frequency offset estimation scheme is proposed for tracking residual offset. The estimation scheme is dependent on the position of an OFDM symbol in a frame. 相似文献
7.
Sahu Anshuman Kumar Mahapatra Siba Sankar 《The International Journal of Advanced Manufacturing Technology》2020,107(3):1017-1023
The International Journal of Advanced Manufacturing Technology - It is of great significance for intelligent manufacturing to study condition monitoring and diagnosis methods to realize early... 相似文献
8.
P. Dupriez A. Piper A. Malinowski J.K. Sahu M. Ibsen B.C. Thomsen Y. Jeong L.M.B. Hickey M.N. Zervas J. Nilsson D.J. Richardson 《Photonics Technology Letters, IEEE》2006,18(9):1013-1015
We demonstrate a pulsed ytterbium-doped fiber master-oscillator power amplifier source at 1060 nm producing over 300 W of average power in 20-ps pulses at 1-GHz repetition rate. The pulses generated by a gain-switched diode were compressed by a chirped fiber Bragg grating and amplified without any distortion with excellent spectral quality. This fiber master oscillator power amplifier system offers versatility and potential for further power scaling. 相似文献
9.
10.
Quaternized poly(phenylene oxide) anion exchange membrane for alkaline direct methanol fuel cells in KOH‐free media 下载免费PDF全文
A series of anion exchange membrane (AEM) electrolytes with quaternary ammonium moiety are fabricated from poly (phenylene oxide) for its application in alkaline direct methanol fuel cells (ADMFCs). In the first step, poly(phenylene oxide) (PPO) is successfully chloromethylated by substituting chloromethyl groups in the aryl position of polymer. In the second step, the chloromethylated PPO (CPPO) is further homogeneously quaternized and ion‐exchanged to form an AEM. From the second step, series of AEMs are prepared by changing the mole ratio of amine in relation to CPPO. The presence of quaternary ammonium group in the membrane was confirmed by elemental analysis. The fabricated membranes are subjected to cell polarization studies in ADMFCs, wherein quaternized poly(2,6‐dimethyl‐1,4‐phenylene oxide) (CPPO:amine of 1:8) membrane exhibits higher peak power density of 3.5 mW cm?2 when compared with the other ratios of CPPO:amine in the absence of KOH solution. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43693. 相似文献