Steam reforming of simulated pre-reformed naphtha in a PdAu membrane reactor

Process intensification in a membrane reactor is an efficient and compact way to produce hydrogen. A methane-rich gas mixture that simulated the composition of pre-reformed naphtha (PRN; with a steam-to-carbon ratio of 2.7) was reformed at temperatures of 550 °C–625 °C and pressures up to 40 barg. The reactor contained commercial steam reforming catalyst and a 14.8 cm long, 2.6 μm thick Pd-1.8Au (wt. %) membrane on a porous alumina support. Methane conversions approaching 90% were obtained in the membrane reactor at a gas-hourly space velocity of 676 h^?1, compared to ≤30% conversion at the same conditions in conventional reactor mode (CM) without withdrawing hydrogen through the membrane. The results were compared to steam methane reforming (SMR) in the membrane reactor at similar conditions. The nitrogen leak through the membrane increased slowly during the testing, because of both pinhole formation and some leakage through the end seals.     

Deployment of real-time systems in the cloud environment

Interest in real-time systems has grown considerably over recent years, primarily due to significant increase in the use of smart technologies and latency-sensitive applications such as cloud gaming, audio/video streaming, and smart homes. Significant work has been done on resource mapping in the cloud environment, and a number of promising results have been established accordingly where the focus is mainly on resource provisioning. However, the applicability of cloud computing services for real-time systems generated from smart systems is still in its infancy and remains unexplored, relatively. To address this gap, we propose a model for the smart systems that periodically offload computational workload to the cloud environment where virtual machines are allocated according to rate-monotonic scheduling policy to ensure requests are processed within the associated deadlines. Deadlines of tasks have been relaxed to improve server utilization as well as maintain a level of confidence in the timing constrains. Experimental results are discussed to highlight the applicability of static priority assignment for the workload in the context of virtual machines allocation.

     

Reducing power consumption of non-preemptive real-time systems

With introduction of dynamic voltage scaling techniques, promising results have been obtained for minimizing overall power consumptions of the real-time systems by exploiting the hardware characteristics of latest processors. Traditionally, preemptive systems have been investigated in depth and interesting results are established accordingly. The non-preemptive counterpart, though equally important, has received very little attention. Due to its simple implementation and lesser number of context switching, non-preemptive systems offer even more opportunities to be exploited for reducing power consumption of the system. In this paper, we establish mathematical foundations for determining the system speed appropriate to non-preemptive nature of tasks such that the timing constraints remain intact and overall power consumption is reduced. We compare our results with closely related techniques, and our analysis shows that the reduction in power consumptions is significant with proposed technique.     

Investigation of turbulent heat transfer and nanofluid flow in a double pipe heat exchanger

In present study, heat transfer and turbulent flow of water/alumina nanofluid in a parallel as well as counter flow double pipe heat exchanger have been investigated. The governing equations have been solved using an in-house FORTRAN code, based on finite volume method. Single-phase and standard k-ε models have been used for nanofluid and turbulent modeling, respectively. The internal fluid has been considered as hot fluid (nanofluid) and the external fluid, cold fluid (base fluid). The effects of nanoparticles volume fraction, flow direction and Reynolds number on base fluid, nanofluid and wall temperatures, thermal efficiency, Nusselt number and convection heat transfer coefficient have been studied. The results indicated that increasing the nanoparticles volume fraction or Reynolds number causes enhancement of Nusselt number and convection heat transfer coefficient. Maximum rate of average Nusselt number and thermal efficiency enhancement are 32.7% and 30%, respectively. Also, by nanoparticles volume fraction increment, the outlet temperature of fluid and wall temperature increase. Study the minimum temperature in the solid wall of heat exchangers, it can be observed that the minimum temperature in counter flow has significantly reduced, compared to parallel flow. However, by increasing Reynolds number, the slope of thermal efficiency enhancement of heat exchanger gradually tends to a constant amount. This behavior is more obvious in parallel flow heat exchangers. Therefore, using of counter flow heat exchangers is recommended in higher Reynolds numbers.     

A Patent Review on the Therapeutic Application of Monoclonal Antibodies in COVID-19

Severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) contains spike proteins that assist the virus in entering host cells. In the absence of a specific intervention, efforts are afoot throughout the world to find an effective treatment for SARS-CoV-2. Through innovative techniques, monoclonal antibodies (MAbs) are being designed and developed to block a particular pathway of SARS-CoV-2 infection. More than 100 patent applications describing the development of MAbs and their application against SARS-CoV-2 have been registered. Most of them target the receptor binding protein so that the interaction between virus and host cell can be prevented. A few monoclonal antibodies are also being patented for the diagnosis of SARS-CoV-2. Some of them, like Regeneron^® have already received emergency use authorization. These protein molecules are currently preferred for high-risk patients such as those over 65 years old with compromised immunity and those with metabolic disorders such as obesity. Being highly specific in action, monoclonal antibodies offer one of the most appropriate interventions for both the prevention and treatment of SARS-CoV-2. Technological advancement has helped in producing highly efficacious MAbs. However, these agents are known to induce immunogenic and non-immunogenic reactions. More research and testing are required to establish the suitability of administering MAbs to all patients at risk of developing a severe illness. This patent study is focused on MAbs as a therapeutic option for treating COVID-19, as well as their invention, patenting information, and key characteristics.     

Influence of Sn content on the electrocatalytic activity of NiSn alloy nanoparticles-incorporated carbon nanofibers toward methanol oxidation

Improvement of the electrocatalytic activity of nickel toward methanol oxidation can be conducted by exploiting the synergetic influence of a co-catalyst and/or utilizing a proper support. In this study, utilizing tin as a co-catalyst and supporting on carbon nanofibers are proposed to enhance methanol oxidation in the alkaline media. Typically, NiSn nanoparticles alloy-incorporated carbon nanofibers could be prepared by calcination of electrospun nanofibers composed of poly (vinyl alcohol), nickel acetate tetrahydrate and tin chloride under argon atmosphere at a high temperature. The influence of the co-catalyst content and the calcination temperature on the morphology, composition and electrocatalytic activity of the proposed nanofibers was investigated. Smooth electrospun nanofibers can be prepared regardless the tin chloride content up to 35 wt%, and the calcination process did not distinctly affect the nanofibrous morphology. Mostly, Ni₃Sn and Ni₃Sn₂ nanoparticles-incorporated amorphous carbon nanofibers were obtained at all the utilized calcination temperatures (700, 850 and 1000 °C) and examined SnCl₂ contents. However, at 10 wt% SnCl₂ content and 850 °C calcination temperature, single metallic compound (Ni₃Sn₂)-incorporated carbon nanofibers were synthesized. Electrochemical measurements indicated that the electrocatalytic activity depends strongly on the tin content as well as the calcination temperature. The nanofibers obtained from electrospun solution containing 10 wt% SnCl₂ and calcined at 850 °C showed very good performance compared to the other formulations. Typically, the corresponding onset potential of the methanol oxidation reaction using these nanofibers catalyst is 315 mV (vs. Ag/AgCl) while it was 405 mV for the nanofibers obtained from electrospun solution containing 0, 5, 15, 25 and 35 wt% SnCl₂. Moreover, the best nanofibers reveal the highest current density. Kinetic study indicated that the corresponding activation energy is 15.6 kJ/mol.