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1.
M. Ganschow C. Hellriegel E. Kneuper M. Wark C. Thiel G. Schulz‐Ekloff C. Bruchle D. Whrle 《Advanced functional materials》2004,14(3):269-276
Dye‐loaded AlPO4‐5 single crystals were prepared by microwave‐assisted hydrothermal synthesis from a batch, containing a mixture of three chromophores (Coumarin 40, Rhodamine BE50, and Oxazine 1) differing in their absorption range, molecular dimensions, and solubilities. Confocal fluorescence images reveal a spatial separation effect of the dye molecules, where the slimmer, more‐soluble dye molecule (Coumarin 40) is uniformly distributed in the body of the single crystal, and the bulky and/or less‐soluble ones (Rhodamine BE50, Oxazine 1) are situated in distinct domains. Visible spectra show good panchromatic absorption of visible light. Fluorescence lifetime measurements indicate the presence of an energy transfer cascade of the entirely fixed dye molecules from Coumarin 40 to Oxazine 1. The transfer mechanism is predominantly radiative. 相似文献
2.
Larissa Canilha Walter Carvalho Marco Giulietti Maria Das Graças Almeida Felipe João Batista Almeida E Silva 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(5):715-721
BACKGROUND: Xylitol bioproduction from lignocellulosic residues comprises hydrolysis of the hemicellulose, detoxification of the hydrolysate, bioconversion of the xylose, and recovery of xylitol from the fermented hydrolysate. There are relatively few reports on xylitol recovery from fermented media. In the present study, ion‐exchange resins were used to clarify a fermented wheat straw hemicellulosic hydrolysate, which was then vacuum‐concentrated and submitted to cooling in the presence of ethanol for xylitol crystallization. RESULTS: Sequential adsorption into two anion‐exchange resins (A‐860S and A‐500PS) promoted considerable reductions in the content of soluble by‐products (up to 97.5%) and in medium coloration (99.5%). Vacuum concentration led to a dark‐colored viscous solution that inhibited xylitol crystallization. This inhibition could be overcome by mixing the concentrated medium with a commercial xylitol solution. Such a strategy led to xylitol crystals with up to 95.9% purity. The crystallization yield (43.5%) was close to that observed when using commercial xylitol solution (51.4%). CONCLUSION: The experimental data demonstrate the feasibility of using ion‐exchange resins followed by cooling in the presence of ethanol as a strategy to promote the fast recovery and purification of xylitol from hemicellulose‐derived fermentation media. Copyright © 2008 Society of Chemical Industry 相似文献
3.
Hans-Dirk Walter 《Informatik-Spektrum》2008,31(4):333-343
Zusammenfassung ,,Rich Internet Applications“ (RIA) sind Webapplikationen, die mit einer wesentlich interaktiveren Benutzerschnittstelle ausgestattet
sind, als wir das bisher von den auf HTML basierten ,,poor ugly web applications“ (PUWA) gewohnt waren. 相似文献
4.
Prof. Dipl.-Ing. Dr.techn. Walter Gretler Prof. Dr. Si-min Zeng 《Forschung im Ingenieurwesen》1996,62(5):105-115
A numerical simulation of unsteady compressible flow induced by two high-speed trains in oncoming traffic within a tunnel
is presented. The computations were carried out by means of a second-order accurate Harten-Yee type upwind TVD scheme. In
order to take the effect of friction into account, a source term is included in the governing flow equations. In the computation,
moving boundary configurations were used to simulate the two trains passing through the tunnel. As geometrical configuration,
the Einmalberg tunnel, where experimental data are available, was selected. The computational results agree reasonably well
with their experimental counter-part. The waves interaction and the waves propagation process at the tunnel entrance and exit
as well as within the tunnel are addressed. Finally, the influence on the transmitted waves at the tunnel exit portal and
the variation of the negative pressure drop during the passage of the two trains are discussed. 相似文献
5.
Systemised serendipity for producing computer art 总被引:4,自引:0,他引:4
David Walter 《Computers & Graphics》1993,17(6):699-700
Serendipity applied to Newton's method, and its derivative the Secant Method, produces unusual and beautiful fractal patterns. Serendipity may be systemised, for example, by the introduction of a perturbation parameter P1, [1] to facilitate searches for interesting pattern variations. 相似文献
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Samuel L. Manzello Richard G. Gann Scott R. Kukuck Kuldeep Prasad Walter W. Jones 《火与材料》2007,31(5):297-310
A gypsum wall assembly was exposed to an intense real‐scale compartment fire. For the wall assembly, temperatures were measured at the exposed face, within the stud cavity, and at the unexposed face during the fire exposure. Total heat flux gauges were used to measure the temporal variation of the energy incident on the walls, and cameras, both visual and infrared, were used to image the unexposed face of the wall assembly during the fire exposure. The behaviour of the wall assembly under the fire load is discussed as are current model results for a simulation of the fire test. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献